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Tailoring sintering kinetics and dielectric properties of Li2SiO3 ceramics by CaO–B2O3–SiO2 glass dopant for LTCC substrate applications

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Abstract

In this work, a novel material candidate, containing Li2SiO3 (LS) ceramic and CaO–B2O3–SiO2 (CBS) glass for low-temperature co-fired ceramics (LTCC) application was developed via the traditional solid-state reaction process. It is shown that the addition of CBS glass significantly improves the sintering characteristics of LS + CBS glass–ceramic systems at low temperatures by lowering the sintering activation energy. Phase coexistence of the main crystalline phase of Li2SiO3 and minor trace of Li2Si2O5 phase was confirmed. The LS + 6 wt% CBS system presents excellent properties, sintered at 875 °C for 2 h: a εr value of 6.28, a Q × f value about 3527 GHz, a flexural strength 272 MPa, a CTE value of 7.35 × 10–6/°C, and a thermal conductivity λ > 10 W/m/K, denoting its promising future for LTCC substrate application.

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References

  1. F. Wang, Y.-H. Lou, Z.-J. Li et al., Ceram. Int. 47, 9955 (2021). https://doi.org/10.1016/j.ceramint.2020.12.140

    Article  CAS  Google Scholar 

  2. Y. Lv, L. Zhang, S. Yang et al., Ceram. Int. 47, 13035 (2021). https://doi.org/10.1016/j.ceramint.2021.01.167

    Article  CAS  Google Scholar 

  3. M.T. Sebastian, H. Jantunen, Int. Mater. Rev. 53, 57 (2013). https://doi.org/10.1179/174328008x277524

    Article  Google Scholar 

  4. X. Zhou, F. Yang, X. Li, C. Sun, S. Zhang, J. Mater. Sci. 27, 11634 (2016). https://doi.org/10.1007/s10854-016-5296-5

    Article  CAS  Google Scholar 

  5. R. Naveenraj, A.N. Unnimaya, E.K. Suresh, R. Ratheesh, J. Electroceram. 44, 59 (2019). https://doi.org/10.1007/s10832-019-00192-5

    Article  CAS  Google Scholar 

  6. X.-M. Cui, Y. He, Z.-Y. Liang, H. Zhang, J. Zhou, Ceram. Int. 36, 1473 (2010). https://doi.org/10.1016/j.ceramint.2010.01.005

    Article  CAS  Google Scholar 

  7. H. Yang, E. Li, C. Sun, S. Duan, Y. Yuan, B. Tang, J. Electron. Mater. 46, 1048–1054 (2017). https://doi.org/10.1007/s11664-016-5046-8

    Article  CAS  Google Scholar 

  8. R.-L. Jia, H. Su, X.-L. Tang, Y.-L. Jing, Chin. Phys. B (2014). https://doi.org/10.1088/1674-1056/23/4/047801

    Article  Google Scholar 

  9. C.-S. Hsi, Y.-R. Chen, H.-I. Hsiang, J. Mater. Sci. 46, 4695 (2011). https://doi.org/10.1007/s10853-011-5377-z

    Article  CAS  Google Scholar 

  10. X. Zhou, C. Sun, D. Xia et al., J. Mater. Sci. 32, 8716 (2021). https://doi.org/10.1007/s10854-021-05542-0

    Article  CAS  Google Scholar 

  11. S. Knickerbocker, A.H. Kumar, L.W. Herron, Am. Ceram. Soc. Bull. 72, 90–95 (1993)

    CAS  Google Scholar 

  12. Z. Chen, X. Chen, W. Zhang, H. Mao, F. Wang, J. Mater. Sci. 31, 18581 (2020). https://doi.org/10.1007/s10854-020-04401-8

    Article  CAS  Google Scholar 

  13. J. Xi, G. Chen, F. Liu et al., Ceram. Int. 45, 24431 (2019). https://doi.org/10.1016/j.ceramint.2019.08.166

    Article  CAS  Google Scholar 

  14. Kamehara IEEE Trans Ultrason Ferroelectr Freq Control.

  15. H. Zhou, H. Wang, Y. Chen, K. Li, X. Yao, Mater. Chem. Phys. 113, 1 (2009). https://doi.org/10.1016/j.matchemphys.2008.06.037

    Article  CAS  Google Scholar 

  16. J.X. Tong, Q.L. Zhang, H. Yang, J.L. Zou, Mater. Lett. 59, 3252 (2005). https://doi.org/10.1016/j.matlet.2005.05.053

    Article  CAS  Google Scholar 

  17. M. Mattox, Ceram. Eng. Sci. Proc 9, 1567 (1988)

    CAS  Google Scholar 

  18. K. Li, H. Wang, H. Zhou, M. Zhang, X. Yao, Int. J. Appl. Ceram. Technol. 7, E144 (2010). https://doi.org/10.1111/j.1744-7402.2009.02475.x

    Article  Google Scholar 

  19. R.R. Tummala, J. Am. Ceram. Soc 74, 895 (1991)

    Article  CAS  Google Scholar 

  20. Z. Fang, B. Tang, F. Si, S. Zhang, J. Alloys Compd. 693, 843 (2017). https://doi.org/10.1016/j.jallcom.2016.09.292

    Article  CAS  Google Scholar 

  21. R. Xiang, H. Su, Y. Li, Q. Lu, X. Tang, J. Mater. Sci. 31, 13460 (2020). https://doi.org/10.1007/s10854-020-03899-2

    Article  CAS  Google Scholar 

  22. H. Yang, E. Li, C. Sun, S. Duan, Y. Yuan, B. Tang, J. Electron. Mater. 46, 1048 (2016). https://doi.org/10.1007/s11664-016-5046-8

    Article  CAS  Google Scholar 

  23. E. Li, P. Zhang, S. Duan, J. Wang, Y. Yuan, B. Tang, J. Alloys Compd. 647, 866 (2015). https://doi.org/10.1016/j.jallcom.2015.06.172

    Article  CAS  Google Scholar 

  24. F.X. Liang, C.L. Sun, S.R. Zhang et al., J. Mater. Sci. 28, 15405 (2017). https://doi.org/10.1007/s10854-017-7426-0

    Article  CAS  Google Scholar 

  25. M. Valant, D. Suvorov, R.C. Pullar, K. Sarma, N.M. Alford, J. Eur. Ceram. Soc. 26, 2777 (2006). https://doi.org/10.1016/j.jeurceramsoc.2005.06.026

    Article  CAS  Google Scholar 

  26. M.T. Sebastian, H. Jantunen, Int. Mater. Rev. 53, 57–90 (2008). https://doi.org/10.1179/174328008X277524

    Article  CAS  Google Scholar 

  27. M. Liu, H. Zhou, X. Xu et al., J. Mater. Sci. 24, 3985 (2013). https://doi.org/10.1007/s10854-013-1351-7

    Article  CAS  Google Scholar 

  28. X.M. Duan, Z.H. Yang, L. Chen et al., J. Eur. Ceram. Soc. 36, 3725 (2016). https://doi.org/10.1016/j.jeurceramsoc.2016.05.007

    Article  CAS  Google Scholar 

  29. G.M. Dursun, C. Duran, Ceram. Int. 45, 12550 (2019). https://doi.org/10.1016/j.ceramint.2019.03.194

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu, 610054, China

    Chengli Sun, Xing Zhou, Fuxia Liang, Hongyu Yang, Bin Tang, Shuren Zhang & Mengjiang Xing

  2. State Key Laboratory of Electronic Thin Films and Integrated Devices, Chengdu, 610054, China

    Chengli Sun, Bin Tang & Shuren Zhang

  3. National Engineering Research Center of Electromagnetic Radiation Control Materials, Chengdu, 610054, China

    Chengli Sun, Bin Tang & Shuren Zhang

  4. Department of NanoEngineering, University of California San Diego, La Jolla, CA, 92093-0448, USA

    Dawei Xia

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  1. Chengli Sun
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  2. Xing Zhou
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  3. Fuxia Liang
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Correspondence to Chengli Sun or Bin Tang.

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Sun, C., Zhou, X., Liang, F. et al. Tailoring sintering kinetics and dielectric properties of Li2SiO3 ceramics by CaO–B2O3–SiO2 glass dopant for LTCC substrate applications. J Mater Sci: Mater Electron 33, 4043–4050 (2022). https://doi.org/10.1007/s10854-021-07595-7

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  • DOI: https://doi.org/10.1007/s10854-021-07595-7

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