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Effect of different anode electrodes with Li(Li0.25Co0.37Mn0.38)O2 as cathode material on Li: ion battery performance

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Abstract

In the present work, Li-rich layered Li(Li0.25Co0.37Mn0.38)O2 (LiCMO) material is prepared using sol–gel technique. The effect of calcination temperature on the structural and morphological characteristics of LiCMO is studied. The electrochemical performance of layered LiCMO/graphite (Cell 1) and LiCMO/Li (Cell 2) has been investigated. The charge transfer resistance (Rct), lithium diffusion coefficients, and discharging capacity are found to be 16,242 Ω, 3.89 × 10–11 S−1 cm2, and 5.26 mAhg−1 and 16 Ω, 20.78 × 10–8 S−1 cm2, and 323 mAhg−1 for Cells 1 and 2, respectively. The presence of efficient lithium-ion transfer tendency and minimal kinetic barrier for lithium diffusion results in enhanced electrochemical properties of Cell 2. Appreciable results for (LiCMO/Li) coin cell make it a unique combination of LiCMO as cathode with Li as anode for the high energy density lithium-ion battery.

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All the findings/data that are presented in this work are based on the original experimental results taken by the authors. The data are not available on the web and not being shared anywhere.

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Acknowledgements

One of authors, Vandana, is thankful to CSIR for financial support, and Department of Physics & Astrophysics, University of Delhi for providing characterization facilities.

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Authors and Affiliations

  1. Department of Physics and Astrophysics, University of Delhi, Delhi, 110007, India

    Vandana, Reema Gupta, Anisha Chaudhary, R. P. Tandon & Vinay Gupta

  2. Department of Physics, Miranda House, University of Delhi, Delhi, 110007, India

    Monika Tomar

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  1. Vandana
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  2. Reema Gupta
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  3. Anisha Chaudhary
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  4. R. P. Tandon
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  5. Vinay Gupta
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Contributions

V involved in conceptualization, methodology, writing—original draft, analysis, and investigation. RG participated in validation, investigation, writing—original draft, and editing. AC took part in validation, investigation, writing—original draft and editing, and analysis. RPT contributed to validation, formal analysis, resources, writing-review, and editing conceptualization. MT participated in conceptualization, methodology, resources, writing-review and editing, supervision, and project administration.

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Correspondence to Monika Tomar.

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One of the authors, Prof. Vinay Gupta unfortunately passed away prior to submission of the manuscript. This is one of his last research works.

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Vandana, Gupta, R., Chaudhary, A. et al. Effect of different anode electrodes with Li(Li0.25Co0.37Mn0.38)O2 as cathode material on Li: ion battery performance. J Mater Sci: Mater Electron 33, 3901–3913 (2022). https://doi.org/10.1007/s10854-021-07584-w

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