Abstract
This work reports the structure and optical properties of Cd-doped NdFeO3 nanoparticles synthesized by the simple co-precipitation method without introduction of surfactants. Structural phase formation of the crystal shows orthorhombic planes of all samples (Nd1−xCdxFeO3; x = 0.1, 0.2 and 0.3). The average crystal size and unit-cell volume increased with the dopant concentration (DXRD = 34.8–54.8 nm; V = 234.96–235.02 Å3). The obtained Cd-doped NdFeO3 nanoparticles have higher absorption in the visible region (λ = 400–800 nm) than in the UV range (λ = 250–400 nm) and the bandgap value (Eg = 2.36–2.28 eV) is much lower than similar rare-earth perovskite series such as HoFe1−xNixO3, LaFe1−xTixO3, NdFe1−xNiyO3 synthesized by different methods. The excellent optical properties of Cd-doped NdFeO3 nanomaterials give a great potential for applications related to optics.
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References
O. Opuchovic, G. Kreiza, J. Senvaitiene, K. Kazlauskas, A. Beganskiene, A. Kareiva, Sol-gel synthesis, characterization and application of selected sub-microsized lanthanide (Ce, Pr, Nd, Tb) ferrites. Dyes Pigments 118, 176–182 (2015)
E. Tugova, S. Yastreboy, O. Karpov, R. Smith, NdFeO3 nanocrystals under glycine nitrate combustion formation. J. Cryst. Growth. 467, 88–92 (2017)
Y. Mostafa, S.Z. Samaneh, K.M. Mozhgan, Synthesis and characterization of nano-structured perovskite type neodymium orthoferrite NdFeO3. Curr. Chem. Lett. 6(1), 23–30 (2017)
K.M. Mozhgan, M. Noroozifar, M. Yousefi, Sh. Jahani, Chemical synthesis and characterization of perovskite NdFeO3 nanocrystals via a co-precipitation method. Int. J. Nanosci. Nanotechnol. 9(1), 7–14 (2013)
P.V. Serna, C.G. Campos, F.S.D. Jesus, A.M.B. Miro, J.A.J. Loran, J. Longwell, Mechanosynthesis, crystal structure and magnetic characterization of neodymium orthoferrite. Mater. Res. 19(2), 0214 (2016)
V. Zharvan, Y.N. Kamaruddin, S. Samnur, E.H. Sujiono, The effect of molar ratio on crystal structure and morphology of Nd1+xFeO3 (x=0.1, 0.2 and 0.3) oxide alloy material synthesized by solid state reaction method. IOP Conf. Ser. Mater. Sci. Eng. 202, 012072 (2017)
S.A. Mir, M. Ikram, K. Asokan, Effect of Ni doping on optical, electrical and magnetic properties of Nd orthoferrite. J. Phys. Conf. Ser. 534, 012017 (2014)
I. Ahmad, M.J. Akhtar, M. Siddique, Effect of Ni doping on the structural properties and collapse of magnetic ordering in NdFe1-xNixO3 (0.1 ≤ x ≤ 0.7) orthoferrites. Chin. Phys. B 25(2), 028101 (2016)
A.T. Nguyen, L.T. Pham, I.Y. Mittova, V.O. Mittova, T.T.L. Nguyen, V.H. Nguyen, X.V. Bui, Co-doped NdFeO3 nanoparticles: synthesis, optical and magnetic properties study. Nanomaterials 11, 937 (2021)
K.O. Ogunniran, G. Murugadoss, R. Thangamuthu, P. Periasamy, Evaluation of nanostructured Nd0.7Co0.3FeO3 perovskite obtained via hydrothermal method as anode materials for Li-ion battery. Mater. Chem. Phys. 248, 122944 (2020)
A.J. Deotale, R.V. Nandedkar, Correlation between particle size, strain and band gap of iron oxide nanoparticles. Mater. Today: Proc. 3(6), 2069–2076 (2016)
A. Somvanshi, S. Husain, S. Manzoor, N. Zarrin, W. Khan, Structure of nanocrystalline Nd0.5R0.5FeO3 (R = La, Pr, and Sm) intercorrelated with optical, magnetic and properties. J. Alloys Compd. 806, 1250–1259 (2019)
P.S.J. Bharadwaj, S. Kundu, V.S. Kollipara, Structural, optical and magnetic properties of Sm3+ doped yttrium orthoferrite (YFeO3) obtained by sol-gel synthesis route. J. Phys. Condens. Matter. 32, 035810 (2020)
A.T. Nguyen, T.L.T. Nguyen, V.X. Bui, Influence of the synthitic conditions on the crystal structure, magnetic and optical properties of holmium orthoferrite nanoparticles. J. Mater. Sci.: Mater. Electron. 32, 19010–19019 (2021)
I. Ahmad, M.J. Akhtar, M. Siddque, M. Iqbal, M.M. Hasan, Origin of anomalous octahedral distortions and collapse of magnetic ordering in Nd1-xSrxFeO3 (0 ≤ x ≤ 0.5). Ceram. Int. 39, 8901–8909 (2013)
Zh. Zhou, L. Guo, H. Yang, Q. Liu, F. Ye, Hydrothermal synthesis and magnetic properties of multiferroic rare-earth orthoferrites. J. Alloys Compd. 583, 21–31 (2014)
Y. Wang, X. Yan, J. Chen, J. Deng, R. Yu, X. Xing, Shape controllable synthesis of NdFeO3 micro single crystals by a hydrothermal route. CrystEngComm 16(5), 858–862 (2014)
T.G. Ho, T.D. Ha, Q.N. Pham, H.T. Giang, T.A.T. Do, T.T. Do, N.T. Nguyen, Hydrocarbon gas sensing of nano-crystalline perovskite oxide LnFeO3 (Ln = La, Nd and Sm). Sens. Actuators B Chem. 158(1), 246–251 (2011)
T.A. Nguyen, V. Pham, T.L. Pham, T.L.T. Nguyen, I.Y. Mittova, V.O. Mittova, L.N. Vo, B.T.T. Nguyen, V.X. Bui, L. Viryutina, Simple synthesis of NdFeO3 nanoparticles by the co-precipitation method based on a study of thermal behaviors of Fe (III) and Nd (III) hydroxides. Curr. Comput.-Aided Drug Des. 10, 219 (2020)
T.A. Nguyen, M.V. Berezhnaya, T.L. Pham, V.O. Mittova, M.Q. Vo, L.T.T. Nguyen, H.T. Do, I.Y. Mittova, E.L. Viryutina, Synthesis and magnetic characteristics of neodymium ferrite powders with perovskite structure. Russ. J. Appl. Chem. 92(4), 498–504 (2019)
Q.M. Vo, V.O. Mittova, V.H. Nguyen, I.Y. Mittova, A.T. Nguyen, Strontium doping as a means of influencing the characteristics of neodymium orthoferrite nanocrystals synthesized by co-precipitation method. J. Mater. Sci.: Mater. Electron. 32, 26944–26954 (2021)
F. Bidrawn, S. Lee, J.M. Vohs, R.J. Gorte, The effect of Ca, Sr, and Ba doping on the ionic conductivity and cathode performance of LaFeO3. J. Electrochem. Soc. 155(7), 660–665 (2008)
M.V. Berezhnaya, N.S. Perov, O.V. Almjasheva, V.O. Mittova, A.T. Nguyen, I.Y. Mittova, L.V. Druzhinina, Yu.A. Alechina, Synthesis and magnetic properties of barium-doped nanocrystal lanthanum orthoferrite. Russ. J. Gen. Chem. 89(3), 480–485 (2019)
M.V. Berezhnaya, O.V. Al’myasheva, V.O. Mittova, A.T. Nguyen, I.Y. Mittova, Sol-gel synthesis and properties of Y1-xBaxFeO3 nanocrystals. Russ. J. Gen. Chem. 88(4), 626–663 (2018)
V.V. Kharton, A.V. Kovalevsky, M.V. Patrakeev, E.V. Tsipis, A.P. Viskup, V.A. Kolotygin, A.A. Yaremchenko, A.L. Shaula, E.A. Kiselev, J.C. Waerenborg, Oxygen nonstoichiometry, mixed conductivity, and mössbauer spectra of Ln0.5A0.5FeO3-δ (Ln = La – Sm, A = Sr, Ba): effect of cation size. Chem. Mater. 20(2), 6457–6467 (2008)
H.W. Brinks, H. Fjellvag, A. Kjekshus, B.C. Hauback, Structure and magnetism of Pr1-xSrxFeO3-δ. J. Solid State Chem. 150(2), 233–249 (2000)
M.B. Bellakki, V. Manivannan, J. Das, Synthesis, structural and magnetic properties of La1-xCdxFeO3 (0.0 ≤ x ≤ 0.3) orthoferrites. Mater. Res. Bull. 44, 1522–1527 (2009)
J.E. House, Inorganic Chemistry, 2nd edn. (Academic Press/Elservier, Amsterdam, 2012)
V.T. Dinh, V.O. Mittova, O.V. Almjasheva, I.Y. Mittova, Synthesis and magnetic properties of nanocrystalline Y1-xCdxFeO3-δ (0 ≤ x ≤ 0.2). Inorg. Mater. 47(10), 1141–1146 (2011)
N.A. Tien, I.Y. Mittova, D.O. Solodukhin, O.V. Al’myasheva, V.O. Mittova, SYu. Demidova, Sol-gel formation and properties of nanocrystals of solid solution Y1-xCaxFeO3. Russ. J. Inorg. Chem. 59(2), 40–45 (2014)
M. Wang, T. Wang, Structural, magnetic and optical properties of Gd and Co co-doped YFeO3 nanopowders. Materials 12(15), 2423 (2019)
N. Ghobadi, Band gap determination using absorption spectrum fitting procedure. Int. Nano Lett. 3(2), 1–4 (2013)
S. Phokha, S. Pinitsoontorn, S. Maensiri, S. Rujirawat, Structure, optical and magnetic properties of LaFeO3 nanoparticles prepared by polymerized complex method. J. Sol-Gel Sci. Technol. 71, 333–341 (2014)
C. Sasikala, N. Durairaj, I. Baskaran, B. Sathyaseelan, M. Henini, E. Manikandan, Transition metal titanium (Ti) doped LaFeO3 nanoparticles for enhanced optical structural and magnetic properties. J. Alloys Compd. 712, 870–877 (2017)
Z. Habib, K. Majid, M. Ikram, K. Sultan, S.A. Mir, K. Asokan, Influence of Ni substitution at B-site for Fe3+ ions on morphological, optical, and magnetic properties of HoFeO3 ceramics. Appl. Phys. 122, 550 (2016)
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The authors would like to thank Ho Chi Minh City University of Education for the facility support.
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Conceptualization, methodology, and formal analysis, PTHD and NAT; validation, NAT; writing–original draft preparation, NAT; writing–review and editing, CHD. All authors have read and agreed to the published version of the manuscript.
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Duyen, P.T.H., Diem, C.H. & Tien, N.A. Cd-doped NdFeO3 nanoparticles: synthesis and optical properties study. J Mater Sci: Mater Electron 33, 3546–3555 (2022). https://doi.org/10.1007/s10854-021-07546-2
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DOI: https://doi.org/10.1007/s10854-021-07546-2