Abstract
Tetragonal distorted spinel of CuMn2−xTixO4 (x = 0, 0.25 and 0.50) was prepared by solid state reaction method followed by neutron diffraction, FTIR spectroscopy, dielectric spectroscopy and magnetic measurements. The confirmation regarding phase formation and identification of additional phase has been carried out by analysing the room temperature neutron diffraction. Besides, FTIR spectroscopy data have also assisted in ascertaining these results. Then, the magnetic susceptibility study of CuMn2O4 shows clearly the ferrimagnetic order below 76 K associated with meta-magnetic state of CuMn2O4 which turns into spin-glass behaviour in CuMn1.50Ti0.50O4. In addition, the room temperature M(H) of all the spinels are described by the Arrot’s plot for weak ferromagnetism. Further, the abrupt change in magnetic susceptibility due to Ti-substitution at room temperature is analysed by electrical property using complex dielectric spectroscopy measurements.
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Acknowledgements
One of the authors (I. Naik) acknowledges UGC-DAE CSR, Mumbai Centre for the experimental facility under the collaborative research project scheme (CRS-M-229). P. Patra would like to acknowledge for the fellowship under this project. All the authors would like to express their gratitude to Dr. S. Mukherjee, UGC-DAECSR Mumbai Centre and Dr. B. S. Mohanta, Lab. Technician, Dept. of Chemistry, NOU for the Dielectric and FTIR measurements, respectively.
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Patra, P., Naik, I., Kaushik, S.D. et al. Crossover from meta-magnetic state to spin-glass behaviour upon Ti-substitution for Mn in CuMn2O4. J Mater Sci: Mater Electron 33, 554–564 (2022). https://doi.org/10.1007/s10854-021-07326-y
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DOI: https://doi.org/10.1007/s10854-021-07326-y