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Synthesis, growth, structural, physicochemical, linear, and nonlinear optical properties of new hybrid [2(C10H20O5) Ba] [Co (SCN)4] single crystal

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Abstract

A novel organometallic single crystal of Bis(15-Crown-5-k5O) barium tetrakis (isothiocynato-kN) cobalt (II) [BCBCTC] was synthesized by slow evaporation solution growth technique at ambient temperature. The grown title compound has been harvested with a dimension of 8 × 5 × 2 mm3 during a period of 10–15 days. The lattice cell parameters, crystal symmetry, and structure were investigated by single-crystal X-ray diffraction technique. Additionally, the different facets of various crystal planes were indexed by powder X-ray diffraction patterns. The result reveals that the title compound belongs to orthorhombic crystal system with a space group of Pnma. The spectroscopic properties of grown crystal were analyzed by FTIR, micro-Raman, and UV–optical spectra. From the UV–optical absorbance spectrum was clearly shown that the cut-off wavelength of the BCBCTC is ~ 369 nm, and optical bandgap is ~ 3.36 eV found to be Tauc’s relation. Moreover, the grown crystal surface morphology, reverse growth rate, and presence of chemical compositions were further verified by FE-SEM, EDAX, and etching studies. The thermal stability and mechanical property were calculated by TG-DSC and Vickers’s hardness tester. The various dielectric properties such as dielectric constant (εr) and dielectric loss (tan δ) of the grown title compound were studied at a function of temperature, and results are discussed. Furthermore, the linear and nonlinear coefficients such as nonlinear refractive index (n2), nonlinear absorption (β), third-order susceptibility (χ3), and then hyper polarizability (γ) were measured by Z-Scan studies.

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Acknowledgements

The authors are grateful thanks to SRM Institute of science and technology (Deemed University), Kattankulathur, Chengalpattu Dist, Tamilnadu, India provided major instrumentation speciality SRM-NRC, and micro-Raman SRM-SCIF.

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Authors and Affiliations

  1. Department of Physics and Nanotechonolgy, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu, 603 203, India

    V. Ravisankar, V. Ramesh & B. Gunasekaran

  2. Nanophotonics Laboratory, School of Physics, Bharathidasan University, Tiruchirappalli, Tamil Nadu, 620 024, India

    T. C. Sabari Girisun

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Ravisankar, V., Ramesh, V., Gunasekaran, B. et al. Synthesis, growth, structural, physicochemical, linear, and nonlinear optical properties of new hybrid [2(C10H20O5) Ba] [Co (SCN)4] single crystal. J Mater Sci: Mater Electron 33, 9380–9394 (2022). https://doi.org/10.1007/s10854-021-07313-3

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