Abstract
Thermally and chemically stable perovskite-like layer structures have attracted extensively in the field of energy and environmental applications. In this study, La2Ti2O7 was synthesized by the solvothermal method at 180 °C. This method provides high pure and homogeneously dispersed nanorods of orthorhombic phase having length of 250 nm and width of 70 nm. Even though this is a low-temperature synthesis method, it yields high crystalline nature after calcination. The novelty of this work is its synthesis methodology by the solvothermal route to achieve lower weight loss of La2Ti2O7. Furthermore, they exhibit narrow absorption in the UV-region from 200 to 350 nm, makes it possible to fabricate it as UV photodetector at ambient condition. In presence of UV illumination at 390 nm, it shows sharp photocurrent response with the decay time of 1.7 s.
Similar content being viewed by others
References
P.A. Fuierer, R.E. Newnham, J. Am. Ceram. Soc. 74, 2876–2881 (1991). https://doi.org/10.1111/j.1151-2916.1991.tb06857.x
J. Brandon, H. Megaw, Philos. Mag. Lett. 21, 189–194 (1970). https://doi.org/10.1080/14786437008238406
M. Subramanian, G. Aravamudan, G.S. Rao, Prog. Solid. State Chem. 15, 55–143 (1983). https://doi.org/10.1016/0079-6786(83)90001-8
R. Turner, P.A. Fuierer, R. Newnham, T.R. Shrout, Appl. Acoust. 41, 299–324 (1994). https://doi.org/10.1016/0003-682X(94)90091-4
P. Soundharraj, M. Jagannathan, D. Dhinasekaran, P. Thiruvarasu, Mater. Today: Proc. (2021). https://doi.org/10.1016/j.matpr.2021.05.512
S. Prabha, D. Durgalakshmi, S. Rajendran, E. Lichtfouse, Environ. Chem. Lett. 19, 1667–1691 (2021). https://doi.org/10.1007/s10311-020-01123-5
G. Li, M. Suja, M. Chen, E. Bekyarova, R.C. Haddon, J. Liu, M.E.J. Itkis, ACS Appl. Mater. Interfaces 9, 37094–37104 (2017). https://doi.org/10.1021/acsami.7b07765
Y. Qin, S. Long, H. Dong, Q. He, G. Jian, Y. Zhang, X. Hou, P. Tan, Z. Zhang, H. Lv, Chin. Phys. B 28, 018501 (2019). https://doi.org/10.1088/1674-1056/28/1/018501
M. Jagannathan, D. Dhinasekaran, P. Soundharraj, S. Rajendran, D.-V.N. Vo, A. Prakasarao, S. Ganesan, J. Hazard. Mater. 416, 125091 (2021). https://doi.org/10.1016/j.jhazmat.2021.125091
S. Prabha, D. Durgalakshmi, K. Subramani, P. Aruna, S. Ganesan, ACS Appl. Mater. Interfaces 12, 19245–19257 (2020). https://doi.org/10.1021/acsami.9b21585
M.M. Mahlambi, A.K. Mishra, S.B. Mishra, R.W. Krause, B.B. Mamba, A.M. Raichur, J. Therm. Anal. Calorim. 110, 847–855 (2012). https://doi.org/10.1007/s10973-011-1852-7
X. Xiong, R. Tian, X. Lin, D. Chu, S. Li, RSC Adv. 5, 14735–14739 (2015). https://doi.org/10.1039/C4RA13945C
Y. Li, L. Jiang, Q. Chen, J. Zhu, J. Mater. Sci.: Mater. Electron. 31, 52–59 (2020). https://doi.org/10.1007/s10854-019-00877-1
A. Nashim, S. Martha, K. Parida, RSC Adv. 4, 14633–14643 (2014). https://doi.org/10.1039/C3RA47037G
R.A. Rakkesh, S. Balakumar, J. Nanosci. Nanotechnol. 13, 370–376 (2013). https://doi.org/10.1166/jnn.2013.6730
R.A. Rakkesh, D. Durgalakshmi, P. Karthe, S. Balakumar, Mater. Chem. Phys 244, 122720 (2020). https://doi.org/10.1016/j.matchemphys.2020.122720
D.W. Hwang, J.S. Lee, W. Li, S.H. Oh, J. Phys. Chem. B 107, 4963–4970 (2003). https://doi.org/10.1021/jp034229n
Z. Shao, S. Saitzek, J.F. Blach, A. Sayede, P. Roussel, R. Desfeux, Wiley Online Libr. (2011). https://doi.org/10.1002/ejic.201100309
M. Butler, D. Girdey, J. Electrochem. Soc. 125, 228–230 (1978). https://doi.org/10.1149/1.2131419
K. Krishnankutty, K. Dayas, Bull. Mater. Sci. 31, 907–918 (2008). https://doi.org/10.1007/s12034-008-0145-7
R. Swami, R. Bokolia, K. Sreenivas, Ceram. Int. 46, 26790–26799 (2020). https://doi.org/10.1016/j.ceramint.2020.07.154
S.W. Lian, W. Wang, A. Lyon, P. Bartolo, M. Dickinson, B. Saunders, Nanoscale Adv. 1, 1–200 (2018). https://doi.org/10.1039/D0NA00581A
G. Li, M. Suja, M. Chen, E. Bekyarova, R.C. Haddon, J. Liu, ACS Appl. Mater. Interfaces 9, 37094–37104 (2017). https://doi.org/10.1021/acsami.7b07765
Acknowledgements
One of the authors D. Durgalakshmi gratefully acknowledges DST-INSPIRE Faculty Fellowship under the sanction DST/INSPIRE/04/2016/000845 for their funding.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
John, J.F., Dhinasekaran, D., Jagannathan, M. et al. Scalable Lanthanum Titanate (La2Ti2O7) nanostructures as UV photodetectors. J Mater Sci: Mater Electron 33, 9126–9133 (2022). https://doi.org/10.1007/s10854-021-07145-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-021-07145-1