Abstract
In the present scenario, ferrites are widely used for humidity sensor applications. Aiming this, we have prepared Dy3+-doped Mn–Zn ferrites by solution combustion method combining urea and glucose as burning agent. And obtained powder was characterized by several physicochemical techniques. The phase purity was confirmed by using the techniques such as X-ray powder diffraction and infrared spectroscopy. FTIR spectra show 2 prominent absorption bands under 1000 cm−1 which confirms the formation of spinel ferrite. The dielectric studies with change in frequency exhibited remarkable changes with Dy3+ content in samples. All electrical responses were investigated as a function of frequency and Dy3+ content at room temperature. The dielectric constant and loss on the frequency of the alternating applied electric field is consistent with Maxwell–Wagner style interfacial polarization. Further Humidity sensing response were recorded for pellet samples. It is noteworthy that, as the composition of the Dysprosium (Dy3+) increases the resistance is enhanced and is maximum for the Mn0.5Zn0.5Dy0.03Fe2−0.03O4 composite. Hence our results are good enough for sensor applications.
Similar content being viewed by others
References
H. Waqas, A.H. Qureshi, K. Subhan, M. Shahzad, Nanograin Mn–Zn ferrite smart cores to miniaturize electronic devices. Ceram. Int. 38, 1235–1240 (2012)
K. Praveena, K. Sadhana, S. Bharadwaj, S. Murthy, Development of nanocrystalline Mn–Zn ferrites for high frequency transformer applications. J. Magn. Magn. Mater. 321, 2433–2437 (2009)
K. Pubby, S.B. Narang, Influence of grain size and porosity on X-band properties of Mn-Zr substituted Ni-Co ferrites. Mater. Lett. 244, 186–191 (2019)
K. Pubby, S.B. Narang, Ka band absorption properties of substituted nickel spinel ferrites: comparison of open-circuit approach and short-circuit approach. Ceram. Int. 45, 23673–23680 (2019)
K. Praveena, K. Sadhana, S. Bharadwaj, S.R. Murthy, Development of nanocrystalline Mn–Zn ferrites for forward type DC–DC converter for switching mode power supplies. Mater. Res. Innov. 14, 56–61 (2010)
K. Praveena, K. Sadhana, S. Bharadwaj, S.R. Murthy, Fabrication of dc–dc converter using nanocrystalline Mn–Zn ferrites. Mater. Res. Innov. 14, 102–106 (2010)
R. Huang, D. Zhang, K.-J. Tseng, Determination of dimension-independent magnetic and dielectric properties for Mn–Zn ferrite cores and its EMI applications. IEEE Trans. Electromagn. Compat. 50, 597–602 (2008)
Z. Beji, M. Sun, L. Smiri, F. Herbst, C. Mangeney, S. Ammar, Polyol synthesis of non-stoichiometric Mn–Zn ferrite nanocrystals: structural/microstructural characterization and catalytic application. RSC Adv. 5, 65010–65022 (2015)
T. Xie, H. Li, C. Liu, J. Yang, T. Xiao, L. Xu, Magnetic photocatalyst BiVO4/Mn-Zn ferrite/reduced graphene oxide: synthesis strategy and its highly photocatalytic activity. Nanomaterials 8, 380 (2018)
C.Q. Shen, H.N. Ji, J. Wu, N. Zhu, J.Q. Niu, H.D. Li, X.B. Niu, Synthesis and characterization of MnZn ferrite nanoparticles for biomedical applications, in: 2018 IEEE International Conference on Applied Superconductivity and Electromagnetic Devices (ASEMD) (IEEE, 2018) pp. 1–2
A. Anwar, S. Zulfiqar, M.A. Yousuf, S.A. Ragab, M.A. Khan, I. Shakir, M.F. Warsi, Impact of rare earth Dy+3 cations on the various parameters of nanocrystalline nickel spinel ferrite. J. Mater. Res. Technol. 9, 5313–5325 (2020)
V.J. Angadi, K. Manjunatha, K. Praveena, V.K. Pattar, B.J. Fernandes, S.O. Manjunatha, J. Husain, S.V. Angadi, L.D. Horakeri, K.P. Ramesh, Magnetic properties of larger ionic radii samarium and gadalonium doped manganese zinc ferrite nanoparticles prepared by solution combustion method. J. Magn. Magn. Mater. 529, 167899 (2021)
V.J. Angadi, K. Manjunatha, N.H. Ayachit, Correlation of internal strain and size with electrical and magnetic properties of Ce3+-doped manganese ferrimagnetic nanoparticles. J. Mater. Sci.: Mater. Electron. 32, 9275–9293 (2021)
N. Rezlescu, E. Rezlescu, The influence of Fe substitutions by R ions in a Ni-Zn Ferrite. Solid State Commun. 88, 139 (1993)
A. D’souzaa, M.D. Kumara, M. Chatima, V. Naika, P.P. Naika, R.B. Tangsali, Effect of rare-earth doping on magnetic and electrical transport properties of nanoparticle Mn–Zn ferrite. Adv. Sci. Lett. 22, 773–779 (2016)
M.A. Almessiere, Y. Slimani, A.D. Korkmaz, S. Güner, A. Baykal, S.E. Shirsath, I. Ercan, P. Kögerler, Sonochemical synthesis of Dy3+ substituted Mn0.5Zn0.5Fe2−xO4 nanoparticles: structural, magnetic and optical characterizations. Ultrason. Sonochem. 61, 104836 (2020)
K.V. Zipare, S.S. Bandgar, G.S. Shahane, Effect of Dy-substitution on structural and magnetic properties of Mnsingle bondZn ferrite nanoparticles. J. Rare Earths 36, 86–94 (2018)
S.I. El-Dek, M.A. Ahmed, A.A. Eltawil, M.S. Afify, Laser induced adjustment of the conductivity of rare earth doped Mn-Zn nanoferrite. Mater. Sci.-Poland 35(3), 519–527 (2017)
E. Ateia, M.A. Ahmed, A.K. El-Aziz, Effect of rare earth radius and concentration on the structural and transport properties of doped Mn–Zn ferrit. Magn. Magn. Mater. 311, 545–554 (2007)
J. Shah, R.K. Kotnala, B. Singh, H. Kishan, Microstructure-dependent humidity sensitivity of porous MgFe2O4–CeO2 ceramic. Sens. Actuators B Chem. 128, 306–311 (2007)
D.I. Khomskii, Multiferroics: different ways to combine magnetism and ferroelectricity. J. Magn. Magn. Mater. 306, 1–8 (2006)
L. Yin, W. Mi, Progress in BiFeO3-based heterostructures: materials, properties and applications. Nanoscale 12, 477 (2020)
X. Hou, X. Wang, W. Mi, Progress in Fe3O4-based multiferroic heterostructures. J. Alloys Compd. 765, 1127–1138 (2018)
M. Back, E. Trave, R. Marin, N. Mazzucco, D. Cristofori, P. Riello, Energy transfer in Bi- and Er-codoped Y2O3 nanocrystals: an effective system for rare earth fluorescence enhancement. J. Phys. Chem. A 118, 30071–30078 (2014)
M. Pal, P. Brahrma, D. Chakravorty, Magnetic and electrical properties of nickel-zinc ferrites doped with bismuth oxide. J. Magn. Magn. Mater. 152, 370–374 (1996)
M. Pal, P. Brahrma, D. Chakravorty, AC conductivity in bismuth oxide doped nickel-zinc ferrites. J. Phys. Soc. Jpn. 67, 2847–2851 (1998)
V.J. Angadi, K. Manjunatha, S.P. Kubrin, A.T. Kozakov, A.G. Kochur, A.V. Nikolskii, I.D. Petrov, S.I. Shevtsova, N.H. Ayachit, Crystal structure, valence state of ions and magnetic properties of HoFeO3 and HoFe0.8Sc0.2O3 nanoparticles from X-ray diffraction, X-ray photoelectron, and Mössbauer spectroscopy data. J. Alloys Compds. 842, 155805 (2020)
I.C. Sathisha, K. Manjunatha, V.J. Angadi, R.K. Reddy, Structural, microstructural, electrical, and magnetic properties of CuFe2-(x+ y)EuxScyO4 (where x and y vary from 0 to 0.03) nanoparticles. J. Supercond. Nov. Magn. 33, 3963–3973 (2020)
K. Manjunatha, V.J. Angadi, R. Rajaramakrishna, U.M. Pasha, Role of 5 mol% Mg-Ni on the structural and magnetic properties of cobalt chromates crystallites prepared by solution combustion technique. J. Supercond. Nov. Magn. 33, 2861–2866 (2020)
F. Ding, J. Lin, T. Wu, H. Zhong, Scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy and nuclear radiation shielding properties of [α-Fe3+O(OH)]-doped lithium borate glasses. Appl. Phys. A 126, 221 (2020)
P. Thakur, D. Chahar, S. Taneja, N. Bhalla, A. Thakur, A review on MnZn ferrites: synthesis, characterization and applications. Ceram. Int. 46(10), 15740–15763 (2020)
K. Manjunatha, K.M. Srininivasamurthy, C.S. Naveen, Y.T. Ravikiran, E.I. Sitalo, S.P. Kubrin, S. Matteppanavar, N.S. Reddy, V.J. Angadi, Observation of enhanced humidity sensing performance and structure, dielectric, optical and DC conductivity studies of scandium doped cobalt chromate. J. Mater. Sci.: Mater. Electron. 30, 17202–17217 (2019)
H.R. Lakshmiprasanna, K. Manjunatha, V.J. Angadi, U.M. Pasha, J. Husain, Effect of cerium on structural, microstructural, magnetic and humidity sensing properties of Mn–Bi ferrites. Nano-Struct. Nano-Objects 24, 100608 (2020)
A. Sunilkumar, S. Manjunatha, T. Machappa, B. Chethan, Y.T. Ravikiran, A tungsten disulphide–polypyrrole composite-based humidity sensor at room temperature. Bull. Mater. Sci. 42, 271 (2019)
S. Pratibha, B. Chethan, Y.T. Ravikiran, N. Dhananjaya, V.J. Angadi, Enhanced humidity sensing performance of Samarium doped Lanthanum Aluminate at room temperature. Sens. Actuators A Phys. 304, 111903 (2020)
A.T. Ramaprasad, V. Rao, Chitin-polyaniline blend as humidity sensor. Sens. Actuators B Chem. 148, 117–125 (2010)
I.C. Athisha, K. Manjunatha, A. Bajorek, B.R. Babu, B. Chethan, T.R. Reddy, Y.T. Ravikiran, V.J. Angadi, Enhanced humidity sensing and magnetic properties of bismuth doped copper ferrites for humidity sensor applications. J. Alloys Compd. 848, 156577 (2020)
J. Shah, M. Arora, L.P. Purohit, R.K. Kotnala, Significant increase in humidity sensing characteristics of praseodymium doped magnesium ferrite. Sens. Actuators A Phys. 167, 332–337 (2011)
K. Manjunatha, V.J. Angadi, M.C. Oliveira, S.R. de Lazaro, E. Longo, R.A.P. Ribeiro, S.O. Manjunatha, N.H. Ayachit, Towards shape-oriented Bi-doped CoCr2O4 nanoparticles from theoretical and experimental perspective: structural, morphological, optical, electrical and magnetic properties. J. Mater. Chem. C 9, 6452–6469 (2021)
K. Manjunatha, V.J. Angadi, R.A.P. Ribeiro, M.C. Oliveira, S.R. de Lázaro, M.R.D. Bomio, S. Matteppanavar, S. Rayaprol, P.D. Babu, U.M. Pasha, Structural, electronic and magnetic properties of Sc3+ doped CoCr2O4 nanoparticles. New J. Chem. 44, 14246–14255 (2020)
Y. Li, K. Fan, H. Ban, M. Yang, Detection of very low humidity using polyelectrolyte/graphene bilayer humidity sensors. Sens. Actuators B Chem. 222, 151–158 (2016)
K. Manjunatha, V.J. Angadi, K.M. Srinivasamurthy, S. Matteppanavar, V.K. Pattar, U.M. Pasha, Exploring the structural, dielectric and magnetic properties of 5 Mol% Bi3+-substituted CoCr2O4 nanoparticles. J. Supercond. Nov. Magn. 33, 1747–1757 (2020)
A. Sunilkumar, S. Manjunatha, B. Chethan, Y.T. Ravikiran, T. Machappa, M. Masuelli, Polypyrrole-Tantalum disulfide composite: an efficient material for fabrication of room temperature operable humidity sensor. Sens. Actuators A Phys. 298, 111593 (2019)
D. Zhang, D. Wang, P. Li, X. Zhou, X. Zong, G. Dong, Facile fabrication of high-performance QCM humidity sensor based on layer-by-layer self-assembled polyaniline/graphene oxide nanocomposite film. Sens. Actuators B Chem. 255, 1869–1877 (2018)
D. Ravinder, K.V. Kumar, Dielectric behaviour of erbium substituted Mn-Zn ferrites. Bull. Mater. Sci. 24, 505–509 (2001)
Acknowledgements
Taif University Researchers Supporting Project Number (TURSP-2020/45), Taif University. Taif, Saudi Arabia.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
El-Denglawey, A., Angadi, V.J., Manjunatha, K. et al. Role of dysprosium in enhancing the humidity sensing performance in manganese zinc ferrites for sensor applications. J Mater Sci: Mater Electron 32, 23554–23565 (2021). https://doi.org/10.1007/s10854-021-06842-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-021-06842-1