Abstract
Magnetoelectric (ME) coupling properties of La0.7Ba0.3MnO3 (LBMO)/P (VDF-TrFE) (0–3) nano-composite films were investigated for device-oriented application like magnetic sensors, actuators, energy harvesting devices etc., The LBMO nanoparticles were prepared by sol–gel auto combustion method. LBMO/P (VDF-TrFE) nanocomposite film was prepared by solution casting method for 0.5% volume fraction of LBMO nanoparticles in P (VDF-TrFE) matrix. This nanocomposite film shows ferromagnetic and ferroelectric properties simultaneously at room temperature. The ME properties of these composite films were studied extensively. The ME coupling coefficient is highly dependent on the angle between ferroelectric polarization and applied magnetic field. The maximum measured in plane ME voltage coefficient \(\left( {\alpha _{{31}}^{V} } \right)\) is found to be 121.5 mV cm−1 Oe−1with application 25 Oe at 10 kHz by lock-in technique. The \(\alpha _{{31}}^{V}\) is maximum at the angles 90° and 270° between ferroelectric polarization and applied magnetic field. The hysteresis of \(\alpha _{{31}}^{V}\) confirms the existence of electric polarized domain formed with the decrease in magnetic field and the process is irreversible.
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Authors appreciating Raja Ramanna Center for Advanced Technology (RRCAT), Indore-452013 and Homi Bhabha National Institute (HBNI), Mumbai-400094 for funds and laboratory facilities.
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SK: Investigation, Data collection, Writing original draft. PD: Data collection, Visualization. AKK: Funding acquisition. SS: Conceptualization, supervision and editing.
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Koner, S., Deshmukh, P., Karnal, A.K. et al. Angular dependent magnetoelectric effect of La0.7Ba0.3MnO3(LBMO) embedded P(VDF-TrFE) particulate multiferroic nanocomposite. J Mater Sci: Mater Electron 33, 8534–8541 (2022). https://doi.org/10.1007/s10854-021-06440-1
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DOI: https://doi.org/10.1007/s10854-021-06440-1