Abstract
Repercussion of Swift Heavy Ion (SHI) irradiation on nickel-based nanorods of Metal-Organic Framework (NRs-Ni3HHTP2 MOF) for enhancement in the properties of ChemFET-based gas sensor has been investigated. Nanorods of Ni3HHTP2-MOF were synthesized by chemical method and exposed to C12+ ions irradiation with fluence 1 × 1011 ion/cm2 and 1 × 1012 ion/cm2. The structural, spectroscopic, morphological, and optical characterizations were carried out using x-ray diffraction (XRD), fourier transfer infrared spectroscopy (FTIR), atomic force microscopy (AFM) with scanning electron microscopy (SEM), and UV-visible spectroscopy, respectively, whereas the bandgap was calculated from the Tauc’s plot. The synthesized nanorods of Ni3HHTP2 MOF were drop-casted on gold-coated microelectrodes on silicon/silicon dioxide (Si/SiO2) substrate, where silicon layer serves as a gate and gold microelectrodes on silicon/silicon dioxide (Si/SiO2) substrate as a source and drain. The transmutations in material properties due to SHI irradiations were serviceable for enhancing field-effect transistor (transfer and output) properties and sensing properties. After Swift Heavy Ion (SHI) irradiation (1 × 1011 ion/cm2), it shows excellent response and recovery time i.e., 20 and 23 s, respectively, for 1 ppm SO2 concentration at room temp (RT) with a lower detection limit of 0.625 ppm.
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Acknowledgements
The authors are thankful to the Inter-University Accelerator Center (IUAC), New Delhi (UFR-62320 & UFR-62321) for material science beamline with SEM facilities and financial support and DST-SERB (Sanction No. EEQ/2017/000645), UGC-DAE CSR (RRCAT), Indore (Project No. CSR-IC-BL66/CSR-183/2016-17/847), UGC-SAP programme (F.530/16/DRS-1/2016 (SAP-II), dt. 16-04-2016), DST-FIST (Project No. No. SR/FST/PSI-210/2016(C) dtd. 16/12/2016), Rashtria Uchachatar Shiksha Abhiyan (RUSA), Government of Maharashtra for providing characterization facilities. The authors also thank Dr. Saif A. Khan, IUAC, New Delhi.
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Ingle, N.N., Shirsat, S., Sayyad, P. et al. Influence of swift heavy ion irradiation on sensing properties of nickel-(NRs-Ni3HHTP2) metal-organic framework. J Mater Sci: Mater Electron 32, 18657–18668 (2021). https://doi.org/10.1007/s10854-021-06353-z
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DOI: https://doi.org/10.1007/s10854-021-06353-z