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A comprehensive study on the optical, mechanical, and radiation shielding properties of the TeO2–Li2O–GeO2 glass system

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Abstract

This paper summarized a comprehensive study on mechanical, optical, and shielding features of the binary lithium-tellurite glasses as a function of doped germanium and lithium oxide content. The Makishima- Makinzie model was applied to compute and estimate the investigated glass samples' mechanical properties. The optical features are studied by determining the optical energy gap (Eg), Urbach energy (Eu) of the TLGe glass system. Both factors vary with the content of dopant germanium and lithium ions in non-linear correlation. Refractive index, molar refraction, electronic polarizability, reflectivity, reflection factor are computed for the studied glasses. The metallization and dielectric constant for the prepared glasses are estimated. The obtained results depict the variation of the optical parameters versus the GeO2 + Li2O content change. The investigated glasses can be suitable for applying in optical devices. The examination showed that the replacement of TeO2 by GeO2 + Li2O enhances the investigated glass samples' shielding properties. The mass attenuation coefficient improved in order 41.79, 42.31, 42.91, and 42.96 cm2/g with substitution

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References

  1. S. Ruengsri, Radiation shielding properties comparison of Pb-based silicate, borate, and phosphate glass matrices. Technol. Nucl. Install, Sci. (2014). https://doi.org/10.1155/2014/218041

    Book  Google Scholar 

  2. S.R. Manohara, S.M. Hanagodimath, L. Gerward, Photon interaction and energy absorption in glass: a transparent gamma ray shield. J. Nucl. Mater. 393–3, 65–472 (2009)

    Google Scholar 

  3. M.I. Sayyed, Y. Al-Hadeethi, M.M. AlShammari, M. Ahmed, S.H. Al-Heniti, Y.S. Rammah, Physical, optical and gamma radiation shielding competence of newly borotellurite based glasses: TeO2–B2O3–ZnO–Li2O3–Bi2O3. Ceram. Int. 47, 611–618 (2021)

    CAS  Google Scholar 

  4. M.Y. Hanfi, I.V. Yarmoshenko, A.A. Seleznev, G. Malinovsky, E. Ilgasheva, M.V. Zhukovsky, Beta radioactivity of urban surface-deposited sediment in three Russian cities. Environ. Sci. Pollut. Res. 27(32), 40309–40315 (2020). https://doi.org/10.1007/s11356-020-10084-9

    Article  CAS  Google Scholar 

  5. H. Akyildirim, E. Kavaz, F.I. El-Agawany, E. Yousef, Y.S. Rammah, Radiation shielding features of zirconolite silicate glasses using XCOM and FLUKA simulation code. J. Non-Cryst. Solids 545, 120245 (2020)

    CAS  Google Scholar 

  6. S. Yasmin, B.S. Barua, M.U. Khandaker, M.A. Rashid, D.A. Bradley, M.A. Olatunji, M. Kamal, Studies of ionizing radiation shielding effectiveness of silica-based commercial glasses used in Bangladeshi dwellings. Results Phys. 9, 541–549 (2018)

    Google Scholar 

  7. M.I. Sayyed, R. El-Mallawany, Shielding properties of (100–x) TeO2-(x)MoO3 glasses. Mater. Chem. Phys. 201, 50–56 (2017)

    CAS  Google Scholar 

  8. M.I. Sayyed, A.H. Almuqrin, R. Kurtulus, A.M.V. Javier-Hila, K. Kaky, T. Kavas, X-ray shielding characteristics of P2O5–Nb2O5 glass doped with Bi2O3 by using EPICS2017 and Phy-X/PSD. Appl. Phys. A 127, 243 (2021)

    CAS  Google Scholar 

  9. S.A.M. Issa, M.I. Sayyed, M.H.M. Zaid, K.A. Matori, Photon parameters for gamma-rays sensing properties of some oxide of lanthanides. Results Phys. 9, 206–210 (2018)

    Google Scholar 

  10. A.S. Abouhaswa, E. Kavaz, A novel B2O3-Na2O-BaO-HgO glass system: synthesis, physical, optical and nuclear shielding features. Ceram. Int. 46, 16166–16177 (2020)

    CAS  Google Scholar 

  11. E. Kavaz, E.H. Ghanim, A.S. Abouhaswa, Optical, structural and nuclear radiation security properties of newly fabricated V2O5-SrO-PbO glass system. J. Non-Cryst. Solids 538, 120045 (2020)

    CAS  Google Scholar 

  12. M.I. Sayyed, K.A. Mahmoud, E. Lacomme, M.M. AlShammari, N. Dwaikat, Y.S.M. Alajerami, M. Alqahtani, B.O. El-bashir, M.H.A. Mhareb, Development of a novel MoO3-doped borate glass network for gamma-ray shielding applications. Eur. Phys. J. Plus 136, 108 (2021)

    CAS  Google Scholar 

  13. M. Kurudirek, Heavy metal borate glasses: potential use for radiation shielding. J. Alloys Compd. 727, 1227–1236 (2017)

    CAS  Google Scholar 

  14. K. Kirdsiri, J. Kaewkhao, A. Pokaipisit, W. Chewpraditkul, P. Limsuwan, Gamma-rays shielding properties of xPbO:(100 x)B2O3 glasses system at 662 keV. Ann. Nucl. Energy 36, 1360–1365 (2009)

    CAS  Google Scholar 

  15. A.H. Almuqrin, M.I. Sayyed, Radiation shielding characterizations and investigation of TeO2–WO3–Bi2O3 and TeO2–WO3–PbO glasses. Appl. Phys. A 127, 190 (2021)

    CAS  Google Scholar 

  16. R. Kurtulus, T. Kavas, I. Akkurt, K. Gunoglu, An experimental study and WinXCom calculations on X-ray photon characteristics of Bi2O3- and Sb2O3-added waste soda-lime-silica glass. Ceram. Int. 46, 21120–21127 (2020)

    CAS  Google Scholar 

  17. K.M. Kaky, M.I. Sayyed, A.A. Ati, M.H.A. Mhareb, K.A. Mahmoud, S.O. Baki, M.A. Mahdi, Germanate oxide impacts on the optical and gamma radiation shielding properties of TeO2-ZnO-Li2O glass system. J. Non-Cryst. Solids 546, 120272 (2020)

    CAS  Google Scholar 

  18. M.I. Sayyed, K.M. Kaky, E. Şakar, U. Akbaba, M.M. Taki, O. Agar, Gamma radiation shielding investigations for selected germanate glasses. J. Non-Cryst. Solids 512, 33–40 (2019)

    CAS  Google Scholar 

  19. M. Kumar, Y.C. Ratnakaram, Role of TeO2 coordination with the BaF2 and Bi2O3 on structural and emission properties in Nd3+ doped fluorophosphate glasses for NIR 1.058 μm laser emission. Opt. Mater. 112, 110738 (2021)

    CAS  Google Scholar 

  20. C.B. Deng, M. Zhang, T. Lan, M.J. Zhou, Y. Wen, J. Zhong, X.Y. Sun, Spectroscopic investigation on Eu3+-doped TeO2-Lu2O3-WO3 optical glasses. J. Non-Cryst. Solids 554, 120565 (2021)

    CAS  Google Scholar 

  21. V.A.G. Rivera, D. Manzani, V.A.G. Rivera, Technological Advances in Tellurite Glasses, Springer International Publishing (2017)

  22. G. Yankov, L. Dimowa, N. Petrova, M. Tarassov, K. Dimitrov, T. Petrov, B.L. Shivachev, Synthesis, structural and non-linear optical properties of TeO2–GeO2–Li2O glasses. Opt. Mater. 35, 248–251 (2012)

    CAS  Google Scholar 

  23. E.S. Yousef, A. El-Adawy, N. El-KheshKhany, Effect of rare earth (Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3 and Er2O3) on the acoustic properties of glass belonging to bismuth-borate system. Solid State Commun. 139, 108–113 (2006)

    CAS  Google Scholar 

  24. A. Makishima, J.D. Mackenzie, Direct calculation of Young’s modulus of glass. J. Non-Cryst. Solids. 12, 35–45 (1973)

    CAS  Google Scholar 

  25. A. Makishima, J.D. Mackenzie, Calculation of bulks modulus, shear modulus and Poisson’s ratio of glass. J. Non-Cryst. Solids. 17, 147–157 (1975)

    CAS  Google Scholar 

  26. X-5 Monte Carlo Team, MCNP-A General Monte Carlo N-Particle Transport Code, Version 5, Los Alamos Controlled Publication. LA-CP-03-0245 (2003)

  27. K.A. Mahmoud, M.I. Sayyed, A.M. Alhuthali, M.Y. Hanfi, The effect of CuO additive on the mechanical and radiation shielding features of Li2B4O7-Pb2O3 glass system. Boletín de la Sociedad Española de Cerámica y Vidrio (2021). https://doi.org/10.1016/j.bsecv.2020.11.005

    Article  Google Scholar 

  28. K.M. Kaky, M.I. Sayyed, M.H.A. Mhareb, A. Abdalsalam, K.A. Mahmoud, S.O. Baki, M.A. Mahdi, Physical, structural, optical and gamma radiation attenuation properties of germanate-tellurite glasses for shielding applications. J. Non-Cryst. Solids 545, 120250 (2020)

    CAS  Google Scholar 

  29. Ö. Eyecioğlu, A.M. El-Khayatt, Y. Karabul, M. Çağlar, O. Toker, O. İçelli, BXCOM: a software for computation of radiation sensing. Radiat. Eff. Defects Solids. 174, 506–518 (2019)

    Google Scholar 

  30. S. Laila, A.K. Suraya, A.K. Yahya, Effect of glass network modification on elastic and structural properties of mixed electronic-ionic 35V2O5-(65-x)TeO2-(x)Li2O glass system. Chalcogenide Lett. 11-2, 91–104 (2014)

  31. D.J. Bergman, Y. Kantor, Phys. Rev. Nature 207, 1238 (1965)

    Google Scholar 

  32. G.A. Saunders, T. Brennan, M. Acet, M. Cankurtaran, H.B. Senin, H.A.A. Sidek, M. Federico, Elastic and non-linear acoustic properties and thermal expansion of cerium metaphosphate glasses. J. Non-Cryst. Solids. 282, 291–305 (2001)

    CAS  Google Scholar 

  33. N.F. Mott, E.A. Davis, conduction in non-crystalline systems V conductivity, optical absorption and photoconductivity in amorphous semiconductors. Philos. Mag. 22, 903–922 (1970)

    Google Scholar 

  34. A. Ramesh Babu, S. Yusub, Ascendancy of iron ions on lithium ion conductivity, optical band gap, Urbach energy and topology of LiF-SrO-B2O3 glasses. J. Non-Cryst. Solids. 533, 119906 (2020)

    CAS  Google Scholar 

  35. F. Urbach, The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids. Phys. Rev. 92, 1324 (1953)

    CAS  Google Scholar 

  36. R.J. Amjad, M.R. Sahar, S.K. Ghoshal, M.R. Dousti, R. Arifin, Synthesis and characterization of Dy3+ doped zinc-lead-phosphate glass. Opt. Mater. 35, 1103–1108 (2013)

    CAS  Google Scholar 

  37. S.F. Khor, Z.A. Talib, W.M. Mat Yunus, Optical properties of ternary zinc magnesium phosphate glasses. Ceram. Int. 38, 935–940 (2012)

    CAS  Google Scholar 

  38. K.M. Kaky, M.I. Sayyed, M.H.A. Mhareb, A.H. Abdalsalam, K.A. Mahmoud, S.O. Baki, M.A. Mahdi, Physical, structural, optical and gamma radiation attenuation properties of germanate-tellurite glasses for shielding applications. J. Non-Cryst. Solids. 545, 120250 (2020)

    CAS  Google Scholar 

  39. Y. Al-Hadeethi, M.I. Sayyed, Y.S. Rammah, Fabrication, optical, structural and gamma radiation shielding characterizations of GeO2-PbO-Al2O3–CaO glasses. Ceram. Int. 46, 2055–2062 (2020)

    CAS  Google Scholar 

  40. F. Nawaz, R. Sahar, S.K. Ghoshal, J. Amjad, Spectral investigation of Sm 3+/Yb 3+ co-doped sodium tellurite glass. Chin. Opt. Lett. 11–6, 061605 (2013)

    Google Scholar 

  41. R. El-Mallawany, The optical properties of tellurite glasses. J. Appl. Phys. 72, 1774–1777 (1992)

    CAS  Google Scholar 

  42. S. Hussain, R.J. Amjad, M. Tanveer, M. Nadeem, H. Mahmood, A. Sattar, A. Iqbal, I. Hussain, Z. Amjad, S.Z. Hussain, S.A. Siddique, M.R. Dousti, Optical investigation of Sm3+ doped in phosphate glass. Glass Phys. Chem. 43, 538–547 (2017)

    CAS  Google Scholar 

  43. M.K. Narayanan, H.D. Shashikala, Optical absorption and TEM studies of silver nanoparticle embedded BaO-CaF2-P2O5 glasses. AIP Conf. Proc. 1731, 1–4 (2016)

    Google Scholar 

  44. R. Mondal, D. Biswas, A.S. Das, R.K.N. Ningthemcha, D. Deb, S. Bhattacharya, S. Kabi, Influence of samarium content on structural, thermal, linear and non-linear optical properties of ZnO–TeO2–P2O5 glasses. Mater. Chem. Phys. (2020). https://doi.org/10.1016/j.matchemphys.2020.123561

    Article  Google Scholar 

  45. W.E. Mahmoud, W. Shirbeeny, A.A. Al-Ghamdi, S. Al-Heniti, Nanoparticles-doped aryl poly ether ether ketone for synthesis and characterization of CdxZn12xO novel application potentials. J. Appl. Polym. Sci. 116, 2658–2667 (2010)

    Google Scholar 

  46. X.Y. Zhang, F.F. Chen, X.H. Zhang, W. Ji, Research progress of third-order optical nonlinearity of chalcogenide glasses. Chin. Phys. B. (2018). https://doi.org/10.1088/1674-1056/27/8/084208

    Article  Google Scholar 

  47. H.N. Desai, J.M. Dhimmar, B.P. Modi, Study of linear and non-linear optical parameters of zinc selenide thin film. IJERA. 5, 117–122 (2015)

    Google Scholar 

  48. S. Stalin, D.K. Gaikwad, M.A. Samee, A. Edukondalu, S.K. Ahmmad, A.A. Joshi, R. Syed, Structural, optical features and gamma ray shielding properties of Bi2O3–TeO2–B2O3-GeO2 glass system. Ceram. Int. 46, 17325–17334 (2020)

    CAS  Google Scholar 

  49. V. Dimitrov, S. Sakka, Electronic oxide polarizability and optical basicity of simple oxides. J. Appl. Phys. 79, 1736–1740 (1996)

    CAS  Google Scholar 

  50. H.M.M. Moawad, H. Jain, R. El-Mallawany, DC conductivity of silver vanadium tellurite glasses. J. Phys. Chem. Solids 70, 224–233 (2009)

    CAS  Google Scholar 

  51. N. Elkhoshkhany, R. Abbas, R. El-Mallawany, A.J. Fraih, Optical properties of quaternary TeO2-ZnO-Nb2O 5-Gd2O3 glasses. Ceram. Int. 40, 14477–14481 (2014)

    CAS  Google Scholar 

  52. M.I. Sayyed, A.A. Ati, M.H.A. Mhareb, K.A. Mahmoud, K.M. Kaky, S.O. Baki, M.A. Mahdi, Novel tellurite glass (60–x)TeO2–10GeO2 -20ZnO–10BaO - xBi2O3 for radiation shielding. J. Alloys Compd. 844, 155668 (2020)

    CAS  Google Scholar 

  53. M.Y. Hanfi, M.I. Sayyed, E. Lacomme, I. Akkurt, K.A. Mahmoud, The influence of MgO on the radiation protection and mechanical properties of tellurite glasses. Nucl. Eng. (2020). https://doi.org/10.1016/j.net.2020.12.012

    Article  Google Scholar 

  54. K.M. Kaky, M.I. Sayyed, M.H.A. Mhareb, A. Abdalsalam, K.A. Mahmoud, S.O. Baki, M.A. Mahdi, Physical, structural, optical and gamma radiation attenuation properties of germanate-tellurite glasses for shielding applications. J. Non-Cryst. Solids 545, 120250 (2020)

    CAS  Google Scholar 

  55. Schott AG, Schott-radiation shielding glass, version May 2013. www.schott.com/advanced_optics

  56. J. Tauc, Amophous and Liquid Semiconductors, 1St edn. (Plenum, London, 1974).

    Google Scholar 

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Acknowledgements

This research was funded by the Deanship of Scientific Research at Princess Nourah bint Abdulrahman University through the Fast-Track Research Funding Program.

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Alsaif, N.A.M., Alotiby, M., Hanfi, M.Y. et al. A comprehensive study on the optical, mechanical, and radiation shielding properties of the TeO2–Li2O–GeO2 glass system. J Mater Sci: Mater Electron 32, 15226–15241 (2021). https://doi.org/10.1007/s10854-021-06074-3

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  • DOI: https://doi.org/10.1007/s10854-021-06074-3

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