Skip to main content
Log in

The microstructure and magnetic properties of FeCo alloys with different OH ¯ /(Co 2+ , Fe 2+ ) ratio and annealing temperature

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

The OH¯/(Co2+, Fe2+) ratio and annealing temperature (Ta) have a great influence on the microstructure and magnetic properties of FeCo alloys. In this work, the OH¯/(Co2+, Fe2+) ratio was first changed from 10:1 to 30:1. When the OH¯/(Co2+, Fe2+) ratio was 20:1, pure FeCo powder samples were obtained. After annealing at 400 °C, the saturation magnetization (Ms), remnant magnetization (Mr), and coercivity (Hc) were 155 emu/g, 15 emu/g, and 210 Oe, respectively. Then the prepared FeCo samples were annealed in the range of 300 °C–600 °C for 5 h. With the increasing of Ta, the better magnetic properties of FeCo powders were observed. When the Ta was 600 °C, the Ms, Mr, and Hc were 202 emu/g, 12 emu/g, and 87 Oe, respectively. When the OH¯/(Co2+, Fe2+) = 20:1 and Ta was 400 °C, the real part of complex permittivity was between 8.2 and 9.5, and the corresponding imaginary part was between − 0.3 and 1.3. Furthermore, the maximum reflection loss (RL) value of FeCo powders (20–30 nm) was − 35.49 dB which showed great potential in corresponding industrial applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. M. Salavati-Niasari, F. Farzaneh, M. Ghandi, J. Mol. Catal. A Chem. 186, 101 (2002)

    Article  CAS  Google Scholar 

  2. D. Ghanbari, M. Salavati-Niasari, J. Ind. Eng. Chem. 24, 284 (2015)

    Article  CAS  Google Scholar 

  3. M. Amiri, M. Salavati-Niasari, A. Akbari, Adv. Colloid Interfac. 265, 29 (2019)

    Article  CAS  Google Scholar 

  4. A. Abbasi, D. Ghanbari, M. Salavati-Niasari, M. Hamadanian, J. Mater. Sci. Mater. El. 27, 4800 (2016)

    Article  CAS  Google Scholar 

  5. S. Mortazavi-Derazkola, M. Salavati-Niasari, O. Amiri, A. Abbasi, J. Energy Chem. 26, 17 (2017)

    Article  Google Scholar 

  6. H.J. Wu, G.L. Wu, Y.Y. Ren, X.H. Li, L.D. Wang, Chem. Eur. J. 22, 8864 (2016)

    Article  CAS  Google Scholar 

  7. N.A. Frey, S. Peng, K. Cheng, S.H. Sun, Chem. Soc. Rev. 38, 2532 (2009)

    Article  CAS  Google Scholar 

  8. T.L. Doane, C. Burda, Chem. Soc. Rev. 41, 2885 (2012)

    Article  CAS  Google Scholar 

  9. L. Liu, N. He, T. Wu, P. Hu, G. Tong, Chem. Eng. J. 355, 103 (2019)

    Article  CAS  Google Scholar 

  10. F. Wang, N. Wang, X. Han, D. Liu, Y. Wang, L. Cui, P. Xu, Y.C. Du, Carbon 145, 701 (2019)

    Article  CAS  Google Scholar 

  11. Y. Cheng, G.B. Ji, Z.Y. Li, H.L. Lv, W. Liu, Y. Zhao, J.M. Cao, Y.W. Du, J. Alloy. Compd. 704, 289 (2017)

    Article  CAS  Google Scholar 

  12. D.W. Liu, Y.C. Du, P. Xu, N. Liu, Y.H. Wang, H.H. Zhao, L.R. Cui, X.J. Han, J. Mater. Chem. C 7, 5037 (2019)

    Article  CAS  Google Scholar 

  13. Z. Wu, K. Pei, L. Xing, X. Yu, W. You, R. Che, Adv. Funct. Mater. 28, 1901448 (2019)

    Article  CAS  Google Scholar 

  14. O. Acher, S. Dubourg, Phys. Rev. B 77, 104440 (2008)

    Article  CAS  Google Scholar 

  15. M. Koiwa, Philos. Mag. 24, 81 (1971)

    Article  CAS  Google Scholar 

  16. D. Kodama, K. Shinoda, K. Sato, Y. Konno, R.J. Joseyphus, K. Motomiya, H. Takahashi, T. Matsumoto, Y. Sato, K. Tohji, B. Jeyadevan, Adv. Mater. 18, 3154 (2006)

    Article  CAS  Google Scholar 

  17. F.J. Yang, J.J. Min, Z.W. Kang, S.Y. Tu, H.B. Chen, D.G. Liu, W.J. Li, X.Q. Chen, C.P. Yang, Chem. Phys. Lett. 670, 1 (2017)

    Article  CAS  Google Scholar 

  18. R.H. Tang, T. Li, Z.B. Wu, W.P. Cai, H. Jiang, Z.G. Yang, W. Liu, Z.J. Zhang, B. Yang, X.F. Liu, Z.Y. Zou, R.H. Yu, IEEE Trans. Magn. 47, 3456 (2011)

    Article  CAS  Google Scholar 

  19. P. Karipoth, A. Thirumurugan, R.J. Joseyphus, J. Colloid. Interf. Sci. 404, 49 (2013)

    Article  CAS  Google Scholar 

  20. Z.J. Huba, K.J. Carroll, E.E. Carpenter, J. Appl. Phys. 109, 07B514 (2011)

    Article  CAS  Google Scholar 

  21. R.J. Joseyphus, K. Shinoda, D. Kodama, B. Jeyadevan, Mater. Chem. Phys. 123, 487 (2010)

    Article  CAS  Google Scholar 

  22. M.R. Wright, An Introduction to Chemical Kinetics (Wiley, Chichester, 2004).

    Book  Google Scholar 

  23. C. Wang, X.J. Han, P. Xu, X.L. Zhang, Y.C. Du, S.R. Hu, J.Y. Wang, X.H. Wang, Appl. Phys. Lett. 98, 072906 (2011)

    Article  CAS  Google Scholar 

  24. T. Wu, Y. Liu, X. Zeng, T.T. Cui, Y.T. Zhao, Y. Li, G.X. Tong, A.C.S. Appl, Mater. Interfaces 8, 7370 (2016)

    Article  CAS  Google Scholar 

  25. L. Tian, J. Xu, S. Xiao, Vacuum 86, 27 (2011)

    Article  CAS  Google Scholar 

  26. C.X. Zhang, J.S. Shi, X.J. Yang, L.L. De, X. Wang, Mater. Chem. Phys. 123, 551 (2010)

    Article  CAS  Google Scholar 

  27. Y.T. Lu, Y.J. Chien, C.F. Liu, T.H. You, C.C. Hu, J. Mater. Chem. 5, 21016 (2017)

    Article  CAS  Google Scholar 

  28. I.B. Bersuker, Electronic Structure and Properties of Transition Metal Compounds, 2nd edn. (Wiely, New York, 2010), pp. 238–323

    Book  Google Scholar 

  29. A. López-Ortega, M. Estrader, G. Salazar-Alvarez, A.G. Roca, J. Nogués, Phys. Rep. 553, 1 (2015)

    Article  CAS  Google Scholar 

  30. X.G. Liu, D.Y. Geng, Z.D. Zhang, Appl. Phys. Lett. 92, 243110 (2008)

    Article  CAS  Google Scholar 

  31. T. Liu, X.B. Xie, Y. Pang, S. Kobayashi, J. Mater. Chem. C 4, 1727 (2016)

    Article  CAS  Google Scholar 

  32. Q.H. Liu, Q. Cao, H. Bi, C.Y. Liang, K.P. Yuan, W. She, Y.J. Yang, R.C. Che, Adv. Mater. 28, 486 (2016)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are grateful for financial support from the National Science Foundation of China (Grant No. 11274101), National Key R&D Program of China (Grant No. 2019YFF01014400), and The Innovation and Enterprise Team Project of Pearl River Talent Plan (Grant No. 2016ZT06G73)

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Tianfa Liao or Fujun Yang.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest. This article does not contain any studies with human participants or animals performed by any of the authors. Informed consent was obtained from all individual participants included in the study.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ke, M., Liao, T., Jia, Y. et al. The microstructure and magnetic properties of FeCo alloys with different OH ¯ /(Co 2+ , Fe 2+ ) ratio and annealing temperature . J Mater Sci: Mater Electron 32, 14156–14163 (2021). https://doi.org/10.1007/s10854-021-05912-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-021-05912-8

Navigation