Skip to main content

Advertisement

SpringerLink
Log in

Chemical synthesis and supercapacitive evaluation of polyaniline nanofibers (PANINFs)

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

The aim of the present work is the morphological evaluation of PANINFs synthesized by easy and economical Successive Ionic Layer Adsorption Reaction (SILAR) method by varying deposition cycles for supercapacitor application. The semi-crystalline nature is confirmed by X-ray diffraction (XRD) patterns. From XRD analysis, it is observed that increasing deposition cycles caused decrement in the crystallite size. On the contrary micro-strain, dislocation density, and distortion parameter were increased with deposition cycles. The Fourier infrared spectroscopy (FT-IR) and Raman analysis confirmed the formation of PANI. The surface morphological analysis reveals that the nanofibers appeared with greater interconnectivity and increased porosity with increasing deposition cycles. These observations are supported by an electrochemical analysis which demonstrated that the electrochemical performance of PANINFs is improved. The obtained highest specific capacitance (Cs) of PANINFs is 196 F/g in 1 M H2SO4 electrolyte at 0.5 mA/cm2 current density with 17.46 Wh/kg and 181.81 W/kg energy and power density, respectively. The synthesis of PANINFs via a simple, cost-effective and eco-friendly chemical route, i.e., the SILAR method with enhanced supercapacitive properties promoting its applications in energy storage technology.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. J. Cui, Z. Zhou, M. Jia, X. Chen, C. Shi, N. Zhao, X. Guo, Polymers (Basel) 12, 1324 (2020)

    Article  CAS  Google Scholar 

  2. X. Chen, T. Shi, K. Zhong, G. Wu, Y. Lu, Chem. Eng. J. 379, 122240 (2020)

    Article  CAS  Google Scholar 

  3. F. Zhang, Z. Jia, C. Wang, A. Feng, K. Wang, T. Hou, J. Liu, Y. Zhang, G. Wu, Energy 195, 117047 (2020)

    Article  CAS  Google Scholar 

  4. H. Shirakawa, J. Louis, A.G. Macdiarmid, J.C.S. Chem. Commun. 16, 578 (1977)

  5. P. Liu, J. Yan, Z. Guang, Y. Huang, X. Li, W. Huang, J. Power Sources 424, 108 (2019)

    Article  CAS  Google Scholar 

  6. Q. Meng, K. Cai, Y. Chen, L. Chen, Nano Energy 36, 268 (2017)

    Article  CAS  Google Scholar 

  7. A.G. Macdiarmid, S.-L. Mu, N.L.D. Somasiri, W. Wu, Mol. Cryst. Liq. Cryst. 121, 187 (1985)

    Article  CAS  Google Scholar 

  8. M.M.P. Parel, A.V. Gillado, M.U. Herrera, Surf. Interfaces 10, 74 (2018)

    Article  CAS  Google Scholar 

  9. L. Wang, S. Sun, Y. He, N. He, F. Zhang, Y. Yao, B. Zhang, X. Zhuang, Y. Chen, Eur. Polym. J. 98, 125 (2018)

    Article  CAS  Google Scholar 

  10. Y. He, J. Wang, W. Zhang, J. Song, C. Pei, X. Chen, J Nanosci Nanotechnol. 10, 7254 (2010)

  11. T. Zhang, H. Qi, Z. Liao, Y.D. Horev, L.A. Panes-ruiz, P.S. Petkov, Z. Zhang, R. Shivhare, P. Zhang, K. Liu, V. Bezugly, S. Liu, Z. Zheng, S. Mannsfeld, T. Heine, G. Cuniberti, H. Haick, E. Zschech, U. Kaiser, R. Dong, X. Feng, Nat. Commun. 10, 4225 (2019)

    Article  Google Scholar 

  12. T. Wu, J. Hong, RSC Adv. 6, 96935 (2016)

    Article  CAS  Google Scholar 

  13. T. Hou, Z. Jia, A. Feng, Z. Zhou, X. Liu, H. Lv, G. Wu, J. Mater. Sci. Technol. 68, 61 (2021)

    Article  Google Scholar 

  14. G.A. Al-dainy, F. Watanabe, G.K. Kannarpady, A. Ghosh, B. Berry, A.S. Biris, S.E. Bourdo, ACS Omega 5, 1887–1901 (2012)

    Article  Google Scholar 

  15. J. Banerjee, K. Dutta, M.A. Kader, S.K. Nayak, Polym. Adv. Technol. 30, 1902 (2019)

    Article  CAS  Google Scholar 

  16. T. Han, J.J. Han, H. Ma, Ionics 25, 4739–4749 (2019)

    Article  CAS  Google Scholar 

  17. Y. Zhang, X. Liu, L. Wu, W. Dong, F. Xia, L. Chen, N. Zhou, L. Xia, Z.Y. Hu, J. Liu, H.S.H. Mohamed, Y. Li, Y. Zhao, L. Chen, B.L. Su, J. Mater. Chem. A 8, 2741 (2020)

    Article  CAS  Google Scholar 

  18. H. Yao, Q. Li, M. Zhang, Z. Tao, Y. Yang, Chem. Eng. J. 392, 123653 (2020)

    Article  CAS  Google Scholar 

  19. K.L. Zhou, H. Wang, J.T. Jiu, J.B. Liu, H. Yan, K. Suganuma, Chem. Eng. J. 345, 290 (2018)

    Article  CAS  Google Scholar 

  20. Y. Yang, Y. Xi, J. Li, G. Wei, N.I. Klyui, W. Han, Nanoscale Res. Lett. 12, 394 (2017)

  21. P.R. Deshmukh, S.V. Patil, R.N. Bulakhe, S.N. Pusawale, J.J. Shim, C.D. Lokhande, RSC Adv. 5, 68939 (2015)

    Article  CAS  Google Scholar 

  22. P. Haldar, S. Biswas, V. Sharma, A. Chowdhury, A. Chandra, Appl. Surf. Sci. 491, 171 (2019)

    Article  CAS  Google Scholar 

  23. M. Yanilmaz, M. Dirican, A.M. Asiri, X. Zhang, J. Energy Storage 24, 100766 (2019)

    Article  Google Scholar 

  24. B. Butoi, A. Groza, P. Dinca, A. Balan, V. Barna, Polymers 9, 732 (2017)

    Article  Google Scholar 

  25. M.R. Waikar, A.A. Shaikh, R.G. Sonkawade, Polym. Bull. 76, 4703 (2019)

    Article  CAS  Google Scholar 

  26. S.P. Thokale, R.M. Kore, S.V Kambale, A.V Thakur, B.J. Lokhande, Macromol. Symp. 387, 1800215 (2019)

  27. J. Chu, X. Li, Q. Li, J. Ma, B. Wu, X. Wang, R. Zhang, M. Gong, High Performance Polymers. 32, 258–267 (2019)

  28. Z.K. Ghouri, N.A.M. Barakat, H.Y. Kim, M. Park, A. Khalil, M.H. El-newehy, S.S. Al-deyab, Arab. J. Chem. 9, 219–228 (2015)

    Article  Google Scholar 

  29. Y. Miao, W. Fan, D. Chen, T. Liu, ACS Appl. Mater. Interfaces 5, 4423–4428 (2013)

    Article  CAS  Google Scholar 

  30. U.M. Chougale, J.V Thombare, V.J. Fulari, A.B. Kadam, International Conference on Energy Efficient Technologies for Sustainability, 1078 (2013)

  31. A.A. Shaikh, M.R. Waikar, R.G. Sonkawade, Synth. Met. 247, 1 (2019)

    Article  CAS  Google Scholar 

  32. M. Horn, J. MacLeod, M. Liu, J. Webb, N. Motta, Econ. Anal. Policy 61, 93 (2019)

    Article  Google Scholar 

  33. X. Xiao, P. Conghaile, D. Leech, R. Ludwig, E. Magner, Biosens. Bioelectron. 90, 96 (2017)

    Article  CAS  Google Scholar 

  34. R. Todd, D. Wu, J.A. Dos Santos Girio, M. Poucand, A.J. Forsyth, Conference Proceedings—IEEE Applied Power Electronics Conference and Exposition—APEC 1306 (2010)

  35. Y. Zheng, Y. Yang, S. Chen, Q. Yuan, CrystEngComm 18, 4218 (2016)

    Article  CAS  Google Scholar 

  36. S. Chen, G. Meng, B. Kong, B. Xiao, Z. Wang, Z. Jing, Y. Gao, G. Wu, H. Wang, Y. Cheng, Chem. Eng. J. 387, 123662 (2020)

    Article  CAS  Google Scholar 

  37. S.B. Kulkarni, U.M. Patil, I. Shackery, J.S. Sohn, S. Lee, B. Park, S. Jun, J. Mater. Chem. A 2, 4989 (2014)

    Article  CAS  Google Scholar 

  38. W. Li, F. Gao, X. Wang, N. Zhang, M. Ma, Angew. Chem. Int. Ed. 55, 9196 (2016)

    Article  CAS  Google Scholar 

  39. S.B. Kulkarni, S.S. Joshi, C.D. Lokhande, Chem. Eng. J. 166, 1179 (2011)

    Article  CAS  Google Scholar 

  40. P.R. Deshmukh, S.N. Pusawale, N.M. Shinde, C.D. Lokhande, J. Korean Phys. Soc. 65, 80 (2014)

    Article  CAS  Google Scholar 

  41. N.C. Maile, S.K. Shinde, K.S. Patil, A.V. Fulari, A. Shahzad, D.S. Lee, V.J. Fulari, SN Appl. Sci. 1, 1 (2019)

    Article  Google Scholar 

  42. I. Sapurina, J. Stejskal, Polym. Int. 57, 1295 (2008)

    Article  CAS  Google Scholar 

  43. B. Sydulu Singu, P. Srinivasan, S. Pabba, J. Electrochem. Soc. 159, A6–A13 (2012)

    Article  CAS  Google Scholar 

  44. P. Chakraborty, A. Kothari, R. Nagarajan, Adsorpt. Sci. Technol. 36, 429 (2018)

    Article  CAS  Google Scholar 

  45. E.M. Elnaggar, K.I. Kabel, A.A. Farag, A.G. Al-Gamal, J. Nanostruct. Chem. 7, 75 (2017)

    Article  CAS  Google Scholar 

  46. Y. Ali, V. Kumar, R.G. Sonkawade, A.S. Dhaliwal, H.C. Swart, Vacuum 99, 265 (2014)

    Article  CAS  Google Scholar 

  47. M. Mitra, C. Kulsi, K. Chatterjee, K. Kargupta, S. Ganguly, D. Banerjee, S. Goswami, RSC Adv. 5, 31039 (2015)

    Article  CAS  Google Scholar 

  48. B. Butoi, A. Groza, P. Dinca, A. Balan, V. Barna, Polymers (Basel) 9, 732 (2017)

    Article  Google Scholar 

  49. L.R. de Oliveira, L. Manzato, Y.P. Mascarenhas, E.A. Sanches, J. Mol. Struct. 1128, 707 (2017)

    Article  Google Scholar 

  50. A.S. Hassanien, A.A. Akl, Phys. B 473, 11 (2015)

    Article  CAS  Google Scholar 

  51. J. Chen, H. Wang, J. Deng, C. Xu, Y. Wang, J. Mater. Chem. A 6, 8986–8991 (2018)

    Article  CAS  Google Scholar 

  52. T.N. Ramesh, P.V. Kamath, J. Solid State Electrochem. 13, 763–771 (2009)

    Article  CAS  Google Scholar 

  53. M. Yi, Z. Shen, S. Liang, L. Liu, X. Zhang, S. Ma, Chem. Commun. 49, 11059–11061 (2013)

    Article  CAS  Google Scholar 

  54. H.M. Gayitri, M. Al-Gunaid, Siddaramaiah, A.P.G. Prakash, Indian J. Eng. Mater. Sci. 27, 320 (2020)

    Google Scholar 

  55. H.M. Gayitri, M. Al-Gunaid, B.S. Madhukar, B. Siddaramaiah, A.P. Gnana Prakash, Polym. Technol. Mater. 58, 1110 (2019)

    CAS  Google Scholar 

  56. I. Šeděnková, M. Trchová, J. Stejskal, Polym. Degrad. Stab. 93, 2147 (2008)

    Article  Google Scholar 

  57. D.S. Dhawale, D.P. Dubal, V.S. Jamadade, R.R. Salunkhe, C.D. Lokhande, Synth. Met. 160, 519 (2010)

    Article  CAS  Google Scholar 

  58. J. Stejskal, M. Trchová, P. Bober, P. Humpolíček, V. Kašpárková, I. Sapurina, M.A. Shishov, M. Varga. In Encyclopedia of Polymer Science and Technology, ed. (2015). https://doi.org/10.1002/0471440264.pst640

  59. J. Vivekanandan, V. Ponnusamy, A. Mahudeswaran, P.S. Vijayanand, Appl. Sci. Res. 3, 147 (2011)

    CAS  Google Scholar 

  60. M. Trchová, Z. Morávková, M. Bláha, J. Stejskal, Electrochim. Acta 122, 28 (2014)

    Article  Google Scholar 

  61. M. Tagowska, B. Pałys, K. Jackowska, Synth. Met. 142, 223 (2004)

    Article  CAS  Google Scholar 

  62. M. Zhao, X. Wu, C. Cai, J. Phys. Chem. C 113, 4987 (2009)

    Article  CAS  Google Scholar 

  63. H.M. Gayitri, M. AL-Gunaid, A.P. Gnana Prakash, Polym. Bull. 77, 5005 (2020)

    Article  CAS  Google Scholar 

  64. J. Ding, X. Li, X. Wang, J. Zhang, D. Yu, B. Qiu, Nanoscale Res. Lett. 10, 1 (2015)

    Article  Google Scholar 

  65. X. Zhang, X. Meng, Q. Wang, B. Qin, L. Jin, Q. Cao, Mater. Lett. 217, 312 (2018)

    Article  CAS  Google Scholar 

  66. S. Cho, K.H. Shin, J. Jang, ACS Appl. Mater. Interfaces 5, 9186 (2013)

    Article  CAS  Google Scholar 

  67. P.A. Shinde, A.C. Lokhande, N.R. Chodankar, A.M. Patil, J.H. Kim, C.D. Lokhande, Electrochim. Acta 224, 397 (2017)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are thankful to the PIFC center, Department of Physics, Shivaji University, Kolhapur for providing FE-SEM measurement facility. The financial assistance through DST PURSE-Phase II (2018-2022) & UGC DSA-Phase II (2018-2023) is highly acknowledged. Author SAS thankfully acknowledged the financial support provided by Malhotra Weikfield Foundation, Pune, India (2018-19) and Chhatrapati Shahu Maharaj Research Training and Human Development Institute (SARTHI), Pune (2019).

Author information

Authors and Affiliations

  1. Radiation and Materials Research Laboratory, Department of Physics, Shivaji University, Kolhapur, 416 004, India

    Suman A. Sawant, Maqsood R. Waikar, Gayatri R. Chodankar & Rajendra G. Sonkawade

  2. Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei, 10607, Taiwan, Republic of China

    Akash S. Rasal

  3. Thin Films Nanomaterials Laboratory, Department of Physics, Shivaji University, Kolhapur, 416 004, India

    Suprimkumar D. Dhas & Annasaheb V. Moholkar

  4. RUSA-Centre for Advanced Sensor Technology, Dr. Babasaheb Ambedkar Marathawada University, Aurangabad, Maharashtra, 431 004, India

    Mahendra D. Shirsat

  5. Manav Rachna International Institute of Research & Studies, Faridabad & Ex-National Institute of Technology, Kurukshetra, 136 119, India

    Shiv K. Chakarvarti

  6. Department of Engineering Physics, Padmabhooshan Vasantraodada Patil Institute of Technology (PVPIT), Sangli (Budhgaon), Maharashtra, 416304, India

    Maqsood R. Waikar

Authors
  1. Suman A. Sawant
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Maqsood R. Waikar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Akash S. Rasal
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Gayatri R. Chodankar
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Suprimkumar D. Dhas
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Annasaheb V. Moholkar
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Mahendra D. Shirsat
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Shiv K. Chakarvarti
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Rajendra G. Sonkawade
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Rajendra G. Sonkawade.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sawant, S.A., Waikar, M.R., Rasal, A.S. et al. Chemical synthesis and supercapacitive evaluation of polyaniline nanofibers (PANINFs). J Mater Sci: Mater Electron 32, 11865–11876 (2021). https://doi.org/10.1007/s10854-021-05816-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-021-05816-7

Search

Navigation