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Double-perovskite Ca3TeO6:Sm3+, Na+ orange–red-emitting phosphors for UV-based white light-emitting diodes

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Abstract

A series of double-perovskite orange–red-emitting Ca(3−2x)SmxNaxTeO6 (x = 0.01–0.25) phosphors have been synthesized via high-temperature method. The single-phase and orthorhombic structure of Ca3TeO6:Sm3+, Na+ phosphors was confirmed by X-ray powder diffraction. Under 405 nm excitation, Ca3TeO6:Sm3+, Na+ phosphors emitted a series of orange–red emission due to the transition of Sm3+ from 4G5/2 to 6HJ/2 (J = 5, 7, 9, and 11). The optimal Sm3+-doping concentration of Ca(3−2x)SmxNaxTeO6 (x = 0.01–0.25) was x = 0.10. The thermal-quenching temperature of Ca3TeO6:0.10Sm3+, 0.10Na+ phosphor was above 480 K. A white light-emitting diode (w-LED) based on 410 nm UV chip was successfully fabricated, and it presented a good correlated color temperature and a high color-rendering index (Ra). Therefore, orange–red-emitting Ca3TeO6:Sm3+, Na+ phosphors have potential applications in UV-based w-LEDs.

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References

  1. D. Xu, F. Xie, L. Yao, Y. Li, H. Lin, A. Li, S. Yang, S. Zhong, Y. Zhang, J. Alloys Compd. 815, 152622 (2020)

    Article  CAS  Google Scholar 

  2. J. Xue, M. Song, H.M. Noh, S.H. Park, B.R. Lee, J.H. Kim, J.H. Jeong, J. Alloys Compd. 817, 152705 (2020)

    Article  CAS  Google Scholar 

  3. F. Feiyue, Z. Lei, S. Yifan, L. Jing, C. Wenbo, L. Yanyan, J. Lumin. 211, 14 (2019)

    Article  Google Scholar 

  4. L. Tang, J. Xia, K. Zhong, Y. Tang, X. Gao, J. Li, Dyes Pigments 178, 108379 (2020)

    Article  CAS  Google Scholar 

  5. L. Tang, L. Zhou, X. Yan, K. Zhong, X. Gao, X. Liu, J. Li, Dyes Pigments 182, 108644 (2020)

    Article  CAS  Google Scholar 

  6. X. Jiang, C. Zheng, C. Mo, X. Wang, J. Zhang, Z. Quan, J. Liu, F. Jiang, Superlattices Microstruct. 126, 120 (2019)

    Article  CAS  Google Scholar 

  7. L. Xinwei, X. Hualan, X. Xianming, X. Feiyan, Z. Shengliang, X. Dekang, Ceram. Int. 45, 10461 (2019)

    Article  Google Scholar 

  8. L. Tang, L. Zhou, A. Liu, X. Yan, K. Zhong, X. Liu, X. Gao, J. Li, Dyes Pigments 186, 109034 (2021)

    Article  CAS  Google Scholar 

  9. L. Junhao, Y. Jing, W. Dawei, K. Wasim Ullah, S. Jianxin, W. Mingmei, S. Qiang, A.T. Peter, J. Mater. Chem. C 4, 8611 (2016)

    Article  Google Scholar 

  10. W. Yu, D. Bin, K. Yuee, S. Shuang, L. Rixin, Y. Ruijin, Arab. J. Chem. 53, 11 (2020)

    Google Scholar 

  11. T. Xubo, H. Jin, C. Zhe, W. Pianpian, Z. Xinmin, J. Lumin. 215, 116670 (2019)

    Article  Google Scholar 

  12. N. Miniajluk, R. Boulesteix, P.J. Deren, Ceram. Int. 46, 7602 (2020)

    Article  CAS  Google Scholar 

  13. Y. Yuan, W. Yelong, C. Guangde, Y. Wan-Jian, J. Appl. Phys. 127, 175703 (2020)

    Article  Google Scholar 

  14. M. Song, W. Zhao, W. Ran, J. Xue, D. Kim, J.H. Jeong, Mater. Res. Bull. 122, 110677 (2020)

    Article  CAS  Google Scholar 

  15. Y.V. Baklanova, L.G. Maksimova, O.A. Lipina, A.P. Tyutyunnik, A.Y. Chufarov, V.G. Zubkov, Mater. Res. Express 6, 066201 (2019)

    Article  CAS  Google Scholar 

  16. J. Guangxiang, Y. Bobo, Z. Guoying, L. Yufeng, Z. Jun, S. Hongtao, O. Haiyan, F. Yongzheng, H. Jingshan, Opt. Mater. 83, 93 (2018)

    Article  Google Scholar 

  17. B. Han, B. Liu, Y. Dai, J. Zhang, Mater. Res. Bull. 121, 110612 (2020)

    Article  CAS  Google Scholar 

  18. Q. Sun, S. Wang, B. Devakumar, L. Sun, J. Liang, T. Sakthivel, S.J. Dhoble, X. Huang, J. Alloys Compd. 804, 230 (2019)

    Article  CAS  Google Scholar 

  19. K. Korzeniowski, M. Sobczyk, J. Alloys Compd. 753, 717 (2018)

    Article  CAS  Google Scholar 

  20. J. Lin, Z. Zhou, Q. Wang, Mater. Res. Bull. 48, 2771 (2013)

    Article  CAS  Google Scholar 

  21. R. Yu, D.S. Shin, K. Jang, Y. Guo, H.M. Noh, B.K. Moon, B.C. Choi, J.H. Jeong, S.S. Yi, Spectrochim. Acta A 125, 458 (2014)

    Article  CAS  Google Scholar 

  22. F. Fan, L. Zhao, Y. Shang, J. Liu, W. Chen, Y. Li, J. Lumin. 211, 14 (2019)

    Article  CAS  Google Scholar 

  23. L. Lakshmi Devi, C.K. Jayasankar, J. Lumin. 45, 116996 (2019)

    Google Scholar 

  24. Y. Li, J. Li, D. Yang, Y. Li, H. Liu, J. Li, L. Zhao, J. Mater. Sci. Mater. Electron. 29, 6412 (2018)

    Article  CAS  Google Scholar 

  25. G. Zhu, Z. Li, F. Zhou, C. Wang, S. Xin, J. Lumin. 196, 32 (2018)

    Article  CAS  Google Scholar 

  26. B.H. Toby, J. Appl. Crystallogr. 34, 210 (2001)

    Article  CAS  Google Scholar 

  27. G. Zhu, Y. Huang, C. Wang, L. Lu, T. Sun, M. Wang, Y. Tang, D. Shan, S. Wen, J. Zhu, Spectrochim. Acta A 210, 105 (2019)

    Article  CAS  Google Scholar 

  28. B. Yang, J. Xu, H.-L. Zhu, Free Radic. Biol. Med. 145, 42 (2019)

    Article  CAS  Google Scholar 

  29. W. Yurong, Z. Dandan, W. Yang, Y. Hao, Y. Wei, D. Ying, G. Haiying, F. Xia, L. Ling, D. Hong, Chin. J. Org. Chem. 39, 2053 (2019)

    Article  Google Scholar 

  30. Y. Wang, Y. Cai, L. Cao, M. Cen, Y. Chen, R. Zhang, T. Chen, H. Dai, L. Hu, Y. Yao, Chem. Commun. 55, 10132 (2019)

    Article  CAS  Google Scholar 

  31. J. Zhao, Y.-N. Wang, W.-W. Dong, Y.-P. Wu, D.-S. Li, Q.-C. Zhang, Inorg. Chem. 55, 3265 (2016)

    Article  CAS  Google Scholar 

  32. Y. Tang, Y. Huang, Y. Chen, L. Lu, C. Wang, T. Sun, M. Wang, G. Zhu, Y. Yang, L. Zhang, J. Zhu, Spectrochim. Acta A 218, 359 (2019)

    Article  CAS  Google Scholar 

  33. L. Han, S. Xie, M. Wang, T. Sun, Q. Liu, G. Jiang, Y. Shi, Y. Tang, Mater. Lett. 234, 241 (2019)

    Article  CAS  Google Scholar 

  34. Y. Chen, X. Li, N. Li, Y. Quan, Y. Cheng, Y. Tang, Mater. Chem. Front. 3, 867 (2019)

    Article  CAS  Google Scholar 

  35. Q. Zhao, G.H. Tao, C.W. Ge, Y. Cai, Q.C. Qiao, X.P. Jia, Spectrosc. Lett. 51, 216 (2018)

    Article  CAS  Google Scholar 

  36. L. Zhang, Y. Xie, X. Geng, B. Deng, H. Geng, R. Yu, J. Lumin. 225, 117365 (2020)

    Article  CAS  Google Scholar 

  37. B. Han, Y. Dai, J. Zhang, B. Liu, H. Shi, Ceram. Int. 44, 3734 (2018)

    Article  CAS  Google Scholar 

  38. Q. Kong, J. Wang, X. Dong, W. Yu, G. Liu, J. Mater. Sci. Mater. Electron. 24, 4745 (2013)

    Article  CAS  Google Scholar 

  39. P. Li, Z. Wang, Z. Yang, Q. Guo, X. Li, Mater. Lett. 63, 751 (2009)

    Article  CAS  Google Scholar 

  40. B.C. Jamalaiah, J. Mol. Struct. 1146, 546 (2017)

    Article  CAS  Google Scholar 

  41. Y. Tamraoui, B. Manoun, F. Mirinioui, I. Saadoune, R. Haloui, A. Elhachmi, E. Saad, P. Lazor, J. Mol. Struct. 1131, 103 (2017)

    Article  CAS  Google Scholar 

  42. A. Dias, G. Subodh, M.T. Sebastian, R.L. Moreira, J. Raman Spectrosc. 41, 702 (2010)

    Article  CAS  Google Scholar 

  43. M. Amores, P.J. Baker, E.J. Cussen, S.A. Corr, Chem. Commun. 54, 10040 (2018)

    Article  CAS  Google Scholar 

  44. X.-J. Wang, D. Jia, W.M. Yen, J. Lumin. 102–103, 34 (2003)

    Article  Google Scholar 

  45. X. Zhang, N. Bao, X. Luo, S.-N. Ding, Biosens. Bioelectron. 114, 44 (2018)

    Article  CAS  Google Scholar 

  46. D. Wang, X. Fan, S. Sun, S. Du, H. Li, J. Zhu, Y. Tang, M. Chang, Y. Xu, Sens. Actuators B 264, 304 (2018)

    Article  CAS  Google Scholar 

  47. Y.F. Tang, Y. Huang, L.X. Lu, C. Wang, T.M. Sun, J.L. Zhu, G.H. Zhu, J.Y. Pan, Y.L. Jin, A.L. Liu, M. Wang, Tetrahedron Lett. 59, 3916 (2018)

    Article  CAS  Google Scholar 

  48. J. Zhu, Y. Zhang, Y. Chen, T. Sun, Y. Tang, Y. Huang, Q. Yang, D. Ma, Y. Wang, M. Wang, Tetrahedron Lett. 58, 365 (2017)

    Article  CAS  Google Scholar 

  49. S. Bhushan, M.V. Chukichev, J. Mater. Sci. Lett. 7, 319 (1988)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The work was supported by Natural Science Foundation of Shaanxi Province (Grant Nos. 2018JM4028, 2019JM545), the Project of the Collaborative Innovation Centre of Shaanxi in China [QBXT-Z(P)-18-2], Natural Science Foundation of Shandong Province (Grant No. ZR2018LB002), Key Research and Development Project of Shandong Province (Grant No. 2019GGX102081), and Key Research and Development Project of Jining (Grant No. 2019ZDGH026).

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Authors and Affiliations

  1. Shaanxi Province Key Laboratory of Catalysis, College of Chemical & Environment Science, Shaanxi University of Technology, Hanzhong, 723001, People’s Republic of China

    Fengmin Song

  2. Department of Chemistry and Chemical Engineering, Jining University, Qufu, 273155, Shandong, People’s Republic of China

    Gongguo Zhang

  3. Collaborative Innovation Centre, Shaanxi University of Technology, Hanzhong, 723001, People’s Republic of China

    Fengmin Song

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  1. Fengmin Song
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Song, F., Zhang, G. Double-perovskite Ca3TeO6:Sm3+, Na+ orange–red-emitting phosphors for UV-based white light-emitting diodes. J Mater Sci: Mater Electron 32, 14128–14136 (2021). https://doi.org/10.1007/s10854-021-05643-w

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  • DOI: https://doi.org/10.1007/s10854-021-05643-w

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