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Three‐dimensional micro–nanorods‐like structure bimetallic oxide fabricated by dealumination strategy for supercap electrodes

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Abstract

Chemical dealloying is an emerging strategy that can be applied to synthesize porous materials. The structure morphologies of the active materials were precisely regulated by designing the various NaOH corrosion solutions. Three-dimensional micro–nanorods-like structure Ni75Cu25O bimetallic oxide with ultra-high electrochemical properties have been obtained, which used Al65Cu15Ni20 precursors through a dealumination strategy. Meanwhile, three-dimensional micro–nanorods-like structure Ni75Cu25O demonstrates an unusual extraordinary specific capacitance (16.96 F cm−2 at 10 mV s−1) and excellent cycling stability (100.8% retention after 5000 cycles at 10 mV s−1). Here, the transition bimetallic oxides by using the dealloying strategy can be applied to develop novel guidances and ideas for the generation of energy storage devices.

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Acknowledgements

This research were supported by the National Natural Science Foundation of China (NSFC), China (Contract Nos. 51871238 and 51671214), Xuzhou Science and Technology Achievement Transformation Project, China (Contract Nos: KC19235), Ningbo Natural Fund Project (Contract Nos. 2018A6100063).

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Correspondence to Yanwei Sui.

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Zhang, M., Xu, S., Sui, Y. et al. Three‐dimensional micro–nanorods‐like structure bimetallic oxide fabricated by dealumination strategy for supercap electrodes. J Mater Sci: Mater Electron 32, 8288–8294 (2021). https://doi.org/10.1007/s10854-021-05307-9

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  • DOI: https://doi.org/10.1007/s10854-021-05307-9

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