Abstract
In this work, a novel memory capacitor structure has been presented with AlOx/Al2O3 bilayer dielectrics on high mobility Epitaxial-GaAs substrate. We have demonstrated the chemical and electrical properties of metal–electrode/AlOx/Al2O3/epi-GaAs-based memory device in detail. Sputter-grown non-stoichiometric AlOx has been used for both the charge trapping layer and blocking layer due to its intrinsic charge trapping capability and high bandgap. Ultra-thin tunneling layer of thicknesses 5 nm and 15 nm were prepared by atomic layer deposition technique and memory properties were compared on promising high mobility Epitaxial-GaAs/Ge heterostructure. The proposed device shows excellent charge trapping properties with a maximum memory window of 3.2 V at sweep voltage of ± 5 V, with good endurance and data retention properties. Oxygen-deficient AlOx layer acted as a charge trapping layer without any additional blocking layer which is impressive for non-volatile memory application on high mobility epi-GaAs substrate. In addition, density Functional Theory (DFT) has been employed to understand the physical origin of the intrinsic charge trapping defects in AlOx dielectric layer.
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A.J. Ritenour, J.W. Boucher, R. Delancey, A.L. Greenaway, S. Aloni, S.W. Boettcher, Energy Environ. Sci. 8, 278 (2015)
T. Ashley, A.B. Dean, C.T. Elliott, G.J. Pryce, A.D. Johnson, H. Willis, Appl. Phys. Lett. 66, 481 (1995)
H.H. Radamson, H. Zhu, Z. Wu, X. He, H. Lin, J. Liu, J. Xiang, Z. Kong, W. Xiong, J. Li, H. Cui, J. Gao, H. Yang, Y. Du, B. Xu, B. Li, X. Zhao, J. Yu, Y. Dong, G. Wang, Nanomaterials 10, 1 (2020)
T. Das, C. Mahata, C.K. Maiti, G.K. Dalapati, C.K. Chia, D.Z. Chi, S.Y. Chiam, H.L. Seng, C.C. Tan, H.K. Hui, G. Sutradhar, P.K. Bose, J. Electrochem. Soc. 159, G15 (2012)
H.J. Oh, J.Q. Lin, S.J. Lee, G.K. Dalapati, A. Sridhara, D.Z. Chi, S.J. Chua, G.Q. Lo, D.L. Kwong, Appl. Phys. Lett. 93, 21 (2008)
C. Mahata, Y. Byun, C.-H. An, S. Choi, Y. An, H. Kim, A.C.S. Appl, Mater. Interfaces 5, 4195 (2013)
S. Takagi, S.H. Kim, M. Yokoyama, R. Zhang, N. Taoka, Y. Urabe, T. Yasuda, H. Yamada, O. Ichikawa, N. Fukuhara, M. Hata, M. Takenaka, Solid. State. Electron. 88, 2 (2013)
M. Yokoyama, S. Kim, R. Zhang, N. Taoka, Y. Urabe, T. Maeda, H. Takagi, T. Yasuda, H. Yamada, O. Ichikawa, N. Fukuhara, M. Hata, M. Sugiyama, Y. Nakano, M. Takenaka, S. Takagi, Appl. Phys. Express 5, 14 (2012)
G.K. Dalapati, S. Guhathakurata, A. Das, C. Mahata, S. Chakraborty, S. Bhunia, H.L. Seng, S. Chattopadhyay, L.K. Bera, S. Tripathy, J. Alloys Compd. 765, 994–1002 (2018)
G.K. Dalapati, M.K. Kumar, C.K. Chia, H. Gao, B.Z. Wang, A.S.W. Wong, A. Kumar, S.Y. Chiam, J.S. Pan, D.Z. Chi, J. Electrochem. Soc. 157, H825 (2010)
H. Ko, K. Takei, R. Kapadia, S. Chuang, H. Fang, P.W. Leu, K. Ganapathi, E. Plis, H.S. Kim, S.-Y. Chen, M. Madsen, A.C. Ford, Y.-L. Chueh, S. Krishna, S. Salahuddin, A. Javey, Nature 468, 286 (2010)
G.K. Dalapati, T.K. Shun Wong, Y. Li, C.K. Chia, A. Das, C. Mahata, H. Gao, S. Chattopadhyay, M.K. Kumar, H.L. Seng, C.K. Maiti, D.Z. Chi, Nanoscale Res. Lett 7, 99 (2012)
G.K. Dalapati, C.K. Chia, C. Mahata, S. Krishnamoorthy, C.C. Tan, H.R. Tan, C.K. Maiti, D. Chi, IEEE Trans. Electron Devices 60, 192 (2013)
G. Kumar Dalapati, S. Chakraborty, C. Mahata, M. Amin Bhuiyan, J. Dong, A. Iskander, S. Masudy-panah, S. Dinda, R. Bin Yang, T. Lee, D. Chi, C. Kean Chia, Mater. Lett. 156, 105 (2015)
Z.-Z. Hou, G.-L. Wang, J.-J. Xiang, J.-X. Yao, Z.-H. Wu, Q.-Z. Zhang, H.-X. Yin, Chinese Phys. Lett. 34, 097304 (2017)
X. Lan, X. Ou, Y. Cao, S. Tang, C. Gong, B. Xu, Y. Xia, J. Yin, A. Li, F. Yan, Z. Liu, J. Appl. Phys. 114, 044104 (2013)
K.-H. Lee, H.-C. Lin, T.-Y. Huang, Jpn. J. Appl. Phys. 53, 014001 (2014)
Y. Shen, Z. Zhang, Q. Zhang, F. Wei, H. Yin, Q. Wei, K. Men, RSC Adv. 10, 7812 (2020)
Y. Zhang, Y.Y. Shao, X.B. Lu, M. Zeng, Z. Zhang, X.S. Gao, X.J. Zhang, J.-M. Liu, J.Y. Dai, Appl. Phys. Lett. 105, 172902 (2014)
X. Lan, X. Ou, Y. Lei, C. Gong, Q. Yin, B. Xu, Y. Xia, J. Yin, Z. Liu, Appl. Phys. Lett. 103, 192905 (2013)
M.M. Rahman, D.-H. Kim, T.-W. Kim, Nanomaterials 10, 527 (2020)
J. Oh, H. Na, K. Lee, H. Sohn, M.Y. Heo, J. Vac. Sci. Technol. B. Nanotechnol. Microelectron. Mater. Process. Meas. Phenom. 31, 041201 (2013)
C.Y. Wei, B. Shen, P. Ding, P. Han, A.D. Li, Y.D. Xia, B. Xu, J. Yin, Z.G. Liu, Sci. Rep. 7, 5988 (2017)
Z. Hou, Z. Wu, H. Yin, ECS J. Solid State Sci. Technol. 7, Q229 (2018)
M. Specht, H. Reisinger, F. Hofmann, T. Schulz, E. Landgraf, R.J. Luyken, W. Rösner, M. Grieb, L. Risch, Solid. State. Electron. 49, 716 (2005)
C. Zhu, Z. Huo, Z. Xu, M. Zhang, Q. Wang, J. Liu, S. Long, M. Liu, Appl. Phys. Lett. 97, 253503 (2010)
S. Nakata, T. Kato, S. Ozaki, T. Kawae, A. Morimoto, Thin Solid Films 542, 242 (2013)
R.C. Jeff, M. Yun, B. Ramalingam, B. Lee, V. Misra, G. Triplett, S. Gangopadhyay, Appl. Phys. Lett. 99, 072104 (2011)
E. Capogreco, A. Subirats, J.G. Lisoni, A. Arreghini, B. Kunert, W. Guo, C.L. Tan, R. Delhougne, G. Van Den Bosch, K. De Meyer, A. Furnemont, J. Van Houdt, IEEE Trans. Electron Devices 64, 130 (2017)
X.-D. Huang, Y. Li, H.-Y. Li, K.-H. Xue, X. Wang, X.-S. Miao, IEEE Electron Device Lett. 41, 549 (2020)
L. Khomenkova, B.S. Sahu, A. Slaoui, F. Gourbilleau, Nanoscale Res. Lett. 6, 172 (2011)
E.K. Evangelou, M.S. Rahman, A. Dimoulas, IEEE Trans. Electron Devices 56, 399 (2009)
W. Xu, Y. Zhang, Z. Tang, Z. Shao, G. Zhou, M. Qin, M. Zeng, S. Wu, Z. Zhang, J. Gao, X. Lu, J. Liu, Nanoscale Res. Lett. 12, 11 (2017)
R. Khosla, E.G. Rolseth, P. Kumar, S.S. Vadakupudhupalayam, S.K. Sharma, J. Schulze, IEEE Trans. Device Mater. Reliab. 17, 80 (2017)
E. Schilirò, R. Lo Nigro, P. Fiorenza, F. Roccaforte, AIP Adv. 6, 075021 (2016)
K. Henkel, M. Kot, D. Schmeier, J. Vac. Sci. Technol. A Vacuum, Surf. Film 35, 01B125 (2017)
M.B. González, J.M. Rafí, O. Beldarrain, M. Zabala, F. Campabadal, J. Vac. Sci. Technol. B Nanotechnol. Microelectron. Mater. Process. Meas. Phenom 31, 01A101 (2013)
D. Joubert, Phys. Rev. B. Condens. Matter Mater. Phys. 59, 1758 (1999)
G. Kresse, J. Furthmüller, Comput. Mater. Sci. 6, 15 (1996)
J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77, 3865 (1996)
K. Iyakutti, E. Mathan Kumar, R. Thapa, R. Rajeswarapalanichamy, V.J. Surya, Y. Kawazoe, J. Mater. Sci. Mater. Electron. 27, 12669 (2016)
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Mahata, C., Ghosh, S., Chakraborty, S. et al. Charge trapping characteristics of sputter-AlOx/ALD Al2O3/Epitaxial-GaAs-based non-volatile memory. J Mater Sci: Mater Electron 32, 4157–4165 (2021). https://doi.org/10.1007/s10854-020-05157-x
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DOI: https://doi.org/10.1007/s10854-020-05157-x