Abstract
Herein, we report the novel metal organic frameworks (MOFs)-based polypyrrole (TiO2/Cu-MOF/PPy) composite via facile hydrothermal technique. The prepared composites are characterized by X-ray diffractometer; microstructural characterization is done with field emission scanning electron microscopy (FESEM); and Fourier-transform infrared spectroscopy, X-ray photo-electron spectroscopy, UV–Vis absorbance spectra, and UV–Vis diffuse reflectance spectra analysis are obtained. The catalytic behavior is examined through the decomposition of methylene blue, rhodamine B, and methyl orange, as a standard dyes under visible light irradiation. Enhanced photocatalytic activities for the novel TiO2/Cu-MOF/PPy composite under visible light are attributed to the high charge separation, absorption, and carrier mobility of MOFs-based polypyrrole composite. Our result shows a great potential of MOFs-based polymer materials as catalyst under visible light radiation for the decomposition of industrial organic dyes.
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25 March 2023
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1007/s10854-023-10277-1
References
C. Xu et al., Nanostructured materials for photocatalysis. Chem. Soc. Rev. 48(14), 3868–3902 (2019)
T. Kanazawa, K. Maeda, Photochemical synthesis of nanoscale multicomponent metal species and their application to photocatalytic and electrochemical water splitting, in Nanostructured photocatalysts. ed. by R.B. Satishchandra, B. Ogale, N. Robertson (Elsevier, New York, 2020), pp. 19–38
X. Zhang et al., Metal–organic frameworks (MOFs) and MOF-derived materials for energy storage and conversion. Electrochem. Energy Rev. 2(1), 29–104 (2019)
B. Hampel et al., Application of TiO2–Cu composites in photocatalytic degradation different pollutants and hydrogen production. Catalysts 10(1), 85 (2020)
M. Valero-Romero et al., Photocatalytic properties of TiO2 and Fe-doped TiO2 prepared by metal organic framework-mediated synthesis. Chem. Eng. J. 360, 75–88 (2019)
L.E. Pérez-Jiménez et al., Enhancement of optoelectronic properties of TiO2 films containing Pt nanoparticles. Results Phys. 12, 1680–1685 (2019)
A. Omar et al., Chemical, optical and photovoltaic properties of TiO2/reduced graphene oxide photoanodes sensitized with Roselle and N719 dyes for dye-sensitized solar cell application. Pigm. Resin Technol. 49(4), 315–324 (2020)
M.K. Arfanis et al., Photocatalytic properties of copper: modified core-shell titania nanocomposites. J. Photochem. Photobiol. A 370, 145–155 (2019)
E. Akbarzadeh, H.Z. Soheili, M. Hosseinifard, M.R. Gholami, Preparation and characterization of novel Ag3VO4/Cu-MOF/rGO heterojunction for photocatalytic degradation of organic pollutants. Mater. Res. Bull. 121, 110621 (2020)
H. Karimi-Maleh et al., The determination of 2-phenylphenol in the presence of 4-chlorophenol using nano-Fe3O4/ionic liquid paste electrode as an electrochemical sensor. J. Colloid Interface Sci. 554, 603–610 (2019)
Z.-G. Sun et al., A promising visible-light photocatalyst: H2 plasma-activated amorphous-TiO2-supported Au nanoparticles. J. Catal. 375, 380–388 (2019)
R. Fatima et al., Photocatalytic degradation performance of various types of modified TiO2 against nitrophenols in aqueous systems. J. Clean. Prod. 231, 899–912 (2019)
B. Moazzenchi, M. Montazer, Click electroless plating of nickel nanoparticles on polyester fabric: electrical conductivity, magnetic and EMI shielding properties. Colloids Surf. A 571, 110–124 (2019)
Y. Wang et al., Conductive polymers for stretchable supercapacitors. Nano Res. 12, 1978–1987 (2019)
O.A.T. Dias et al., Flexible electrically conductive films based on nanofibrillated cellulose and polythiophene prepared via oxidative polymerization. Carbohyd. Polym. 220, 79–85 (2019)
A.-U.-H.A. Shah et al., Cost effective chemical oxidative synthesis of soluble and electroactive polyaniline salt and its application as anticorrosive agent for steel. Materials 12(9), 1527 (2019)
S. Chatterjee, C.-L. Hui, Review of stimuli-responsive polymers in drug delivery and textile application. Molecules 24(14), 2547 (2019)
L.Y. Molefe et al., Synthesis of porous polymer-based metal–organic frameworks monolithic hybrid composite for hydrogen storage application. J. Mater. Sci. 54(9), 7078–7086 (2019)
F.G. Zamani et al., Current trends in the development of conducting polymers-based biosensors. Trends Anal. Chem. 118, 264–276 (2019)
J.-Q. Liu et al., Recent developments in luminescent coordination polymers: designing strategies, sensing application and theoretical evidences. Coord. Chem. Rev. 406, 213145 (2020)
J. Li, J. Qiao, K. Lian, Hydroxide ion conducting polymer electrolytes and their applications in solid supercapacitors: a review. Energy Storage Mater. 24, 6–21 (2020)
M. Yuan, S.D. Minteer, Redox polymers in electrochemical systems: from methods of mediation to energy storage. Curr. Opin. Electrochem. 15, 1–6 (2019)
R. Luo et al., A simple strategy for high stretchable, flexible and conductive polymer films based on PEDOT: PSS-PDMS blends. Org. Electron. 76, 105451 (2020)
X. Fu et al., Flexible conducting polymer-based cellulose substrates for on-skin applications. Mater. Sci. Eng. C 108, 110392 (2020)
J. Chen et al., Polypyrrole-doped conductive supramolecular elastomer with stretchability, rapid self-healing, and adhesive property for flexible electronic sensors. ACS Appl. Mater. Interfaces 11(20), 18720–18729 (2019)
A.F. Cruz-Pacheco et al., Assessing the influence of the sourcing voltage on polyaniline composites for stress sensing applications. Polymers 12(5), 1164 (2020)
S. Morsi et al., Polypyrrole-coated latex particles as core/shell composites for antistatic coatings and energy storage applications. J. Coat. Technol. Res. 16(3), 745–759 (2019)
Folorunso, O., et al., Investigation of graphene loaded polypyrrole for lithium-ion battery. Materials Today: Proceedings, 2020.
W. Yang et al., Applications of metal–organic-framework-derived carbon materials. Adv. Mater. 31(6), 1804740 (2019)
J. Zhang et al., Hollow multi-shelled structure with metal–organic-framework-derived coatings for enhanced lithium storage. Angew. Chem. Int. Ed. 58(16), 5266–5271 (2019)
S. Wang et al., Enhanced thermoelectric properties of polyaniline/polypyrrole/carbon nanotube ternary composites by treatment with a secondary dopant using ferric chloride. J. Mater. Chem. C 8(2), 528–535 (2020)
S. Silvestri et al., Polypyrrole-TiO2 composite for removal of 4-chlorophenol and diclofenac. React. Funct. Polym. 146, 104401 (2020)
S. Silvestri et al., Synthesis of PPy-ZnO composite used as photocatalyst for the degradation of diclofenac under simulated solar irradiation. J. Photochem. Photobiol. A 375, 261–269 (2019)
T. Anirudhan, J. Christa, F. Shainy, Magnetic titanium dioxide embedded molecularly imprinted polymer nanocomposite for the degradation of diuron under visible light. React. Funct. Polym. 152, 104597 (2020)
M. Yu et al., Titanium dioxide and polypyrrole molecularly imprinted polymer nanocomposites based electrochemical sensor for highly selective detection of p-nonylphenol. Anal. Chim. Acta 1080, 84–94 (2019)
M. Maruthapandi et al., Carbon-dot initiated synthesis of polypyrrole and polypyrrole@ CuO micro/nanoparticles with enhanced antibacterial activity. ACS Appl. Polym. Mater. 1(5), 1181–1186 (2019)
K. Malook, M. Khan, M. Ali, Polypyrrole-CuO based composites, promotional effects of CuO contents on polypyrrole characteristics. J. Mater. Sci. 30(4), 3882–3888 (2019)
P. Wang et al., A novel electroactive PPy/HKUST-1 composite film-coated electrode for the selective recovery of lithium ions with low concentrations in aqueous solutions. Electrochim. Acta 306, 35–44 (2019)
Y. Zhou et al., Evaporation induced uniform polypyrrole coating on CuO arrays for free-standing high lithium storage anode. J. Solid State Electrochem. 23(6), 1829–1836 (2019)
C. Cui et al., Synthesis of electromagnetic functionalized Fe3O4 microspheres/polyaniline composites by two-step oxidative polymerization. J. Phys. Chem. B 116(31), 9523–9531 (2012)
A. Beniwal, Novel TPU/Fe2O3 and TPU/Fe2O3/PPy nanocomposites synthesized using electrospun nanofibers investigated for analyte sensing applications at room temperature. Sens. Actuators B 304, 127384 (2020)
K. Han et al., Tremella-like NiO microspheres embedded with fish-scale-like polypyrrole for high-performance asymmetric supercapacitor. RSC Adv. 9(38), 21608–21615 (2019)
L. Zhang et al., Preparation of stainless steel mesh-supported MnO2/polypyrrole nanocomposites as binder-free electrode for supercapacitor. NANO 15(03), 2050031 (2020)
V. Archana et al., Hierarchical CuO/NiO-carbon nanocomposite derived from metal organic framework on cello tape for the flexible and high performance nonenzymatic electrochemical glucose sensors. ACS Sustain. Chem. Eng. 7(7), 6707–6719 (2019)
A. Jamwal et al., Towards sustainable copper matrix composites: manufacturing routes with structural, mechanical, electrical and corrosion behaviour. J. Compos. Mater. 54(19), 2635–2649 (2020)
D. Ding, G. Ye, L. Chen, Superior corrosion resistance KAlSi2O6-containing materials for calcining Li-ion battery cathode materials. Corros. Sci. 157, 324–330 (2019)
N. Jadhav, S. Kasisomayajula, V. Gelling, Polypyrrole/metal oxides-based composites/nanocomposites for corrosion protection. Front. Mater. 7, 95 (2020)
S. Rostamnia, H. Alamgholiloo, X. Liu, Pd-grafted open metal site copper-benzene-1, 4-dicarboxylate metal organic frameworks (Cu-BDC MOF’s) as promising interfacial catalysts for sustainable Suzuki coupling. J. Colloid Interface Sci. 469, 310–317 (2016)
Y. Zhang et al., Theoretical study of D-A′–π–A/D–π–A′–π–A triphenylamine and quinoline derivatives as sensitizers for dye-sensitized solar cells. RSC Adv 10(29), 17255–17265 (2020)
K. Ullah et al., Enhanced visible light photocatalytic activity and hydrogen evolution through novel heterostructure AgI–FG–TiO2 nanocomposites. J. Mol. Catal. A 410, 242–252 (2015)
S.A.M. Rizvi et al., Synthesis and characterization of Cu-MOF derived Cu@ AC electrocatalyst for oxygen reduction reaction in PEMFC. Catal. Lett. 150, 1397–1407 (2020)
R. Rani et al., Enhanced hydrothermal stability of Cu MOF by post synthetic modification with amino acids. Vacuum 164, 449–457 (2019)
S.S. Nadar, V.K. Rathod, Immobilization of proline activated lipase within metal organic framework (MOF). Int. J. Biol. Macromol. 152, 1108–1112 (2020)
H. Yu et al., Effects of ion channel noise on neural circuits: an application to the respiratory pattern generator to investigate breathing variability. J. Neurophysiol. 117(1), 230–242 (2017)
C. Guo et al., FTIR-ATR study for adsorption of trypsin in aqueous environment on bare and TiO2 coated ZnSe surfaces. Chin. Chem. Lett. 31(1), 150–154 (2020)
N.D. Abazović et al., Photoluminescence of anatase and rutile TiO2 particles. J. Phys. Chem. B 110(50), 25366–25370 (2006)
S. Mugundan et al., Synthesis and characterization of undoped and cobalt-doped TiO2 nanoparticles via sol–gel technique. Appl. Nanosci. 5(4), 449–456 (2015)
J. Li et al., Kinetics and mechanisms of electrocatalytic hydrodechlorination of diclofenac on Pd-Ni/PPy-rGO/Ni electrodes. Appl. Catal. B 268, 118696 (2020)
X. Liang et al., A nano-structured and highly ordered polypyrrole-sulfur cathode for lithium–sulfur batteries. J. Power Sources 196(16), 6951–6955 (2011)
Z. Zhang et al., Encapsulation of CsPbBr 3 perovskite quantum dots into PPy conducting polymer: exceptional water stability and enhanced charge transport property. Appl. Surf. Sci. 526, 146735 (2020)
Y. Zhang et al., Facile synthesis of a Cu-based MOF confined in macroporous carbon hybrid material with enhanced electrocatalytic ability. Chem. Commun. 49(61), 6885–6887 (2013)
Y.-Y. Chen et al., Two chiral cadmium carboxylate framework isomers generated by spontaneous resolution: synthesis, structures and properties. J. Coord. Chem. 72(2), 251–261 (2019)
S. Wang et al., Synergistic effects between Cu metal–organic framework (Cu-MOF) and carbon nanomaterials for the catalyzation of the thermal decomposition of ammonium perchlorate (AP). J. Mater. Sci. 54(6), 4928–4941 (2019)
B. Wang et al., Incorporating Ni-MOF structure with polypyrrole: enhanced capacitive behavior as electrode material for supercapacitor. RSC Adv. 10(21), 12129–12134 (2020)
H. She et al., Enhanced performance of photocatalytic CO2 reduction via synergistic effect between chitosan and Cu:TiO2. Mater. Res. Bull. 124, 110758 (2020)
T. Larsson, B. Noläng, Y. Andersson, The electronic structure of the hydrogen solid solution in Ti3P. J. Alloy. Compd. 231(1–2), 153–158 (1995)
J. Zhao et al., Facile preparation of a self-assembled artemia cyst shell–TiO2–MoS2 porous composite structure with highly efficient catalytic reduction of nitro compounds for wastewater treatment. Nanotechnology 31(8), 085603 (2019)
P. Arul et al., Ultrasonic assisted synthesis of size-controlled Cu-metal–organic framework decorated graphene oxide composite: sustainable electrocatalyst for the trace-level determination of nitrite in environmental water samples. ACS Omega 5(24), 14242–14253 (2020)
P. Samanta et al., Advanced porous materials for sensing, capture and detoxification of organic pollutants toward water remediation. ACS Sustain. Chem. Eng. 7(8), 7456–7478 (2019)
L. Liu et al., The applications of metal−organic frameworks in electrochemical sensors. ChemElectroChem 5(1), 6–19 (2018)
I.I. Alkhatib et al., Metal-organic frameworks for photocatalytic CO2 reduction under visible radiation: a review of strategies and applications. Catal. Today 340, 209–224 (2020)
J. Tauc, R. Grigorovici, A. Vancu, Optical properties and electronic structure of amorphous germanium. Phys. Status Solidi 15(2), 627–637 (1966)
N. Alam et al., Fabrication and enhancement in photoconductive response of α-Fe2O3/graphene nanocomposites as anode material. J. Mater. Sci. 29(20), 17786–17794 (2018)
D. Han et al., Enhanced photocatalytic activity and photothermal effects of Cu-doped metal-organic frameworks for rapid treatment of bacteria-infected wounds. Appl. Catal. B 261, 118248 (2020)
E. Akbarzadeh et al., Preparation and characterization of novel Ag3VO4/Cu-MOF/rGO heterojunction for photocatalytic degradation of organic pollutants. Mater. Res. Bull. 121, 110621 (2020)
L.Á.A. Herrera, P.K.C. Reyes, A.M. Huerta Flores, L.T. Martínez, J.M.R. Villanueva, BDC-Zn MOF sensitization by MO/MB adsorption for photocatalytic hydrogen evolution under solar light. Mater. Sci. Semicond. Process. (2020). https://doi.org/10.1016/j.mssp.2020.104950
V. Kumara, K. Porkodib, F. Rochaa, Langmuir-Hinshelwood kinetics: a theoretical study. Catal. Commun. 9(1), 82–84 (2008)
K. Ullah et al., Synergistic effect of PtSe2 and graphene sheets supported by TiO2 as cocatalysts synthesized via microwave techniques for improved photocatalytic activity. Catal. Sci. Technol. 5(1), 184–198 (2015)
K.Z. Ullah, Z.-D. Meng, S. Ye, S. Sarkar, W.-C. Oh, Synthesis and characterization of novel PtSe2/graphene nanocomposites and its visible light driven catalytic properties. J. Mater. Sci. 49(12), 4139–4147 (2014)
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This work was supported by Doctoral Research Initiation Fund Project of Jilin Engineering Normal University (BSKJ201914).
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Liu, G., Wang, Y., Xue, Q. et al. RETRACTED ARTICLE: TiO2/Cu-MOF/PPy composite as a novel photocatalyst for decomposition of organic dyes. J Mater Sci: Mater Electron 32, 4097–4109 (2021). https://doi.org/10.1007/s10854-020-05151-3
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DOI: https://doi.org/10.1007/s10854-020-05151-3