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Synthesis and characterisations of non-covalently bound aniline–indium(III) porphyrins

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Abstract

The aniline–indium(III) porphyrin chromophoric systems in which aniline is bonded non-covalently with porphyrin macrocycles were obtained by the treatment of each of the indium(III) porphyrins, i.e. tetra-p-methoxyphenyl indium(III) porphyrin and tetra-p-chlorophenyl indium(III) porphyrin with neutral aniline in CHCl3/CH3OH mixtures. The prepared aniline–indium(III) porphyrin chromophoric systems were successfully characterised by using FT-IR spectroscopy, 1H NMR spectroscopy and ESI-mass spectrometry. The 1H NMR and UV–Visible absorption spectroscopic studies of aniline–indium(III) porphyrin systems were further recorded as a function of pure aniline concentration in proper solvents. The results of these spectroscopic studies indicate the existence of interchromophoric interactions between aniline and indium(III) porphyrins which increase with the increase in pure aniline concentrations. Powder X-ray diffraction (PXRD) measurement data reflects change in crystalline phases of parent complexes upon incorporation of aniline molecules. Thermogravimetric analysis (TGA) indicates that aniline-incorporated indium(III) porphyrins are less thermally stable than their parent complexes.

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Acknowledgements

This research was supported by Council of Scientific and Industrial Research (CSIR) India (Grant No. 09/100(0190)/2016-EMR-I). Authors acknowledge the post graduate department of Chemistry, University of Jammu for recording 1H NMR spectra, UV-Visible absorption spectra and thermal analyses of the samples.

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Authors and Affiliations

  1. Postgraduate Department of Chemistry, University of Jammu, Jammu, 180006, India

    Padma Dechan & Gauri Devi Bajju

  2. G. G. M Science College, Canal Road, Jammu, 180016, India

    Shrdha Anand

  3. Advanced Materials Research Centre, Indian Institute of Technology, Block-A2, Kamand Campus, Mandi, Himachal Pradesh, 175005, India

    Puneet Sood

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  1. Padma Dechan
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Dechan, P., Anand, S., Sood, P. et al. Synthesis and characterisations of non-covalently bound aniline–indium(III) porphyrins. J Mater Sci: Mater Electron 32, 1703–1715 (2021). https://doi.org/10.1007/s10854-020-04939-7

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