Abstract
The strategy of achieving long cycle stability predominantly depends on the electrode materials in lithium ion batteries (LIBs). Herein, this strategy was achieved by the preparation of Mo4V6O25 nanorods using a simple low-temperature hydrothermal method. The prepared sample exhibited mesoporous nature, uniformly arranged nanorods and good thermal stability confirmed by BET, TEM and TG-DT analysis, respectively. This material was used as anode and exhibited initial discharge capacity of 1129 mAh g−1 at 100 mA g−1 for LIBs and delivered reasonable discharge capacities even at different current rates with excellent cycling stability. The Mo4V6O25 is considered as a promising anode material for LIBs with high electrochemical performance.
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D.J. Xue, S. Xin, Y. Yan, K.C. Jiang, Y.X. Yin, Y.G. Guo, L. Wan, J. Wan, J. Am. Chem. Soc. 134(25), 12–2515 (2012)
P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J.M. Tarascon, Nature 407, 496–499 (2000)
M.V. Reddy, G.V. Subba Rao, B.V. Chowdari, Chem. Rev. 113, 5364–5457 (2013)
Y. Huang, X.L. Huang, J.S. Lian, D. Xu, L.M. Wang, X.B. Zhang, J. Mater. Chem. 22, 2844–2847 (2012)
X.L. Huang, R.Z. Wang, D. Xu, Z.L. Wang, H.G. Wang, J.J. Xu, Z. Wu, Q.C. Liu, Y. Zhang, X.B. Zhang, Adv Funct. Mater. 23, 4345–4353 (2013)
H.G. Wang, D.L. Ma, X.L. Huang, Y. Huang, X.B. Zhang, Sci Rep. 2, 1–8 (2012)
P.P. Su, S.C. Liao, F. Rong, F.Q. Wang, J. Chen, C. Li, Q.H. Yang, J. Mater. Chem. A. 2, 17408–17414 (2014)
M.F. Hassan, Z.P. Guo, Z. Chen, H.K. Liu, J. Power Sources 195, 2372–2376 (2010)
X.L. Wu, L.Y. Jiang, F.F. Cao, Y.G. Guo, L.J. Wan, Adv. Mater. 21, 2710–2714 (2009)
R. Zhang, Y. Du, D. Li, D. Shen, J. Yang, Z. Guo, H.K. Liu, A.A. Elzatahry, D. Zhao, Adv. Mater. 26, 749–6755 (2014)
F. Zhou, S. Xin, H.W. Liang, L.T. Song, S.H. Yu, Angew. Chem. Int. Ed. 53, 11552–11556 (2014)
B. Liu, X. Zhao, Y. Xiao, M. Cao, J Mater Chem A. 2, 3338–3343 (2014)
X.L. Wang, W.Q. Han, H. Chen, J. Bai, T.A. Tyson, X.Q. Yu, X.J. Wang, X.Q. Yang, J. Am. Chem. Soc. 133, 20692–20695 (2011)
T. Jayalakshmi, K. Nagaraju, G. Nagaraju, J Ener Chem. 27, 183–189 (2018)
M. Uchiyama, S. Slane, E. Plichta, M. Salomon, J. Electrochem. Soc. 136, 36 (1989)
M.S. Michael, A. Fauzi, S.R.S. Prabaharan, J Inorg Mat. 2, 261–267 (2000)
B.L. Cushing, S.H. Kang, J.B. Goodenough, Instability of brannerite cathode materials upon lithium insertion. Inter J inor Mat. 3, 875–879 (2001)
J. Gopalakrishnan, N.S. Bhuvanesh, R. Vijayaraghavan, N.Y.A. Vasanthacharya, J. Mater. Chem. 7, 307–310 (1997)
Sakaebe H, Shikano M, Xia Y, Sakai T, Eriksson T, Gustafsson T, Thomas J, Como Italy. 225 (2000)
N. Amdouni, H. Zarrouk, F. Soulette, C.M. Julien, J. Mater. Chem. 13, 2374–2380 (2003)
R.S. Liu, C.Y. Wang, V.A. Drozd, S.F. Hu, H.S. Sheu, Electrochem. Solid State Lett. 8, A650 (2005)
Y. Liang, S. Yang, Z. Yi, M. Li, J. Sun, Y. Zhou, J. Mater. Sci. 40, 5553–5555 (2005)
M. Hu, J. Liang, X. Chen, J. Wei, Z. Zhou, RSC Adv. 00, 1–3 (2012)
L. Zhou, Y. Liang, L. Hu, X. Han, Z. Yi, Sun J Yang S. J Alloy Comp. 7, 389–393 (2008)
G. Qu, J. Wang, G. Liu, B. Tian, C. Su, Z. Che, J. Rueff, Z. Wang, Adv. Funct. Mater. 29, 1805227 (2018)
Y. Liang, S. Yang, Z. Yi, M. Li, J. Sun, Y. Zhou, J. Mater. Sci. 40, 553–5555 (2005)
R.S. Liu, C.Y. Wang, V.A. Drozd, S.F. Hu, H.A.S. Sheuc, Electrochem. Solid-State Lett. 8, A650–A653 (2005)
A. Satsuma, A. Hattori, K. Mizutani, A. Furuta, A. Miyamoto, T. Hattori, Y. Murakami, J. Phys. Chem. 93, 1484–1490 (1989)
K. Taramn, S. Teranishi, S. Yoshida, N. Tamura, Prod. Int. Cong. Catal. 3, 282 (1965)
K. Tarama, S. Yoshida, S. Ishida, H. Kakioka, Bull. Chem. Soc. Jpn. 4, 2840–2845 (1968)
Y. Yao, N. Xu, D. Guan, J. Li, Z. Zhuang, L. Zhou, C. Shi, X. Liu, L. Mai, ACS Appl. Mater. Inter. 45, 39425–39431 (2017)
O.M. Hussain, K. Srinivasa Rao, K.V. Madhuri, C.V. Ram Ana, B.S. Naidu, S. Pai, J. John, R. Pinto, Appl. Phys. A 75, 417–422 (2002)
P. Meduri, E. Clark, J.H. Kim, E. Dayalan, G.U. Sumanasekera, M.K. Sunkara, Nano Lett. 4, 784–1788 (2012)
Y. Du, G. Li, E.W. Peterson, J. Zhou, X. Zhang, R. Mu, Z. Dohnálek, M. Bowden, I. Lyubinetsky, S.A. Chambers, Nanoscale. 8, 3119–3124 (2016)
D. Porwal, A.C.M. Esther, I.N. Reddy, N. Sridhara, N.P. Yadav, D. Rangappa, P. Bera, C. Anandan, A.K. Sharma, A. Dey, RSC Adv. 5, 35737–35745 (2015)
H.K. Matralis, C. Papadopoulou, C. Kordulis, A. Aguilar Elguezabal, V. Cortes Corberan, Appl. Catal. A 126, 365–380 (1995)
N. Chena, C. Wanga, F. Hu, F. Bie, Y. Wei, G. Chen, F. Du, ACS Appl. Mater. Interfaces. 29, 16117–16123 (2015)
Acknowledgements
This work was financially supported by DST-SERB, Govt. of India, New Delhi (SB/FT/CS-083/2012), and thanks to Prf. N. Munichandraiah, Dept. of Inorganic and physical chemistry, IISC, Bangalore for providing the glove box facility.
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Jayalakshmi, T., Kishore, B. & Nagaraju, G. Mesoporous Mo4V6O25 as high electrochemical performance anode material for lithium ion battery. J Mater Sci: Mater Electron 32, 1593–1601 (2021). https://doi.org/10.1007/s10854-020-04928-w
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DOI: https://doi.org/10.1007/s10854-020-04928-w