An ultraviolet-assisted electrospinning procedure of polyimide ultrafine fibrous membranes fabricated by ester-type negative photosensitive polyimide

Abstract

An ultraviolet-assisted electrospinning (UVAES) procedure was performed using in situ photopolymerization during the electrospinning process to enhance the solvent resistance of polyimide (PI) ultrafine fibrous membranes (UFMs). The resultant PI UFMs were fabricated via solution electrospinning using photosensitive poly(amic acid ester) (PSPAE) modified with unsaturated double bond side chains as the main fiber-forming agent, diethylene glycol diacrylate as the crosslinker, and titanocene as the photoinitiator. The precursor PSPAE UFMs were prepared via both of normal electrospinning and UVAES procedures and then were converted to PI using thermal imidization at 350 °C in a nitrogen imidization. The physical and chemical properties of the obtained PI UFMs were subsequently studied. The fibers exposed to ultraviolet irradiation possessed a smooth surface morphology and maintained their fibrous structure after thermal imidization at elevated temperature as high as 350 °C in nitrogen, whereas the crosslink-free PSPAE fibers lost their fibrous structure after heating. Furthermore, as well as providing enhanced thermal decomposition stability, the introduction of a crosslinked structure via ultraviolet irradiation also protected the molecular chains from organic solvents, resulting in excellent solvent resistance of the PI UFMs.

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References

  1. 1.

    L. Wang, X. Fu, J. He, X. Shi, H. Peng, Adv. Mater. 32, 5 (2020)

    Google Scholar 

  2. 2.

    W. Zeng, L. Shu, Q. Li, S. Chen, F. Wang, X.M. Tao, Adv. Mater. 26, 31 (2014)

    Google Scholar 

  3. 3.

    J. Zhao, G. Wu, Y. Hu, L. Yang, X.M. Tao, J. Mater. Chem. A 3, 48 (2015)

    Google Scholar 

  4. 4.

    J.S. Heo, J. Eom, Y.H. Kim, S.K. Park, Small 14, 3 (2017)

    Google Scholar 

  5. 5.

    J. Xue, J. Xie, W. Liu, Y. Xia, Acc. Chem. Res. 50, 1976 (2017)

    CAS  Google Scholar 

  6. 6.

    A. Greiner, J.H. Wendorff, Angew Chem. Int. Ed. Engl. 46, 5670 (2007)

    CAS  Google Scholar 

  7. 7.

    J. Xue, T. Wu, Y. Dai, Y. Xia, Chem. Rev. 119, 5298 (2019)

    CAS  Google Scholar 

  8. 8.

    V. Thavasi, G. Singh, S. Ramakrishna, Energy Environ. Sci. 1, 205 (2008)

    CAS  Google Scholar 

  9. 9.

    B. Sun, Y.Z. Long, H.D. Zhang, M.M. Li, J.L. Duvail, X.Y. Jiang, H.L. Yin, Prog. Polym. Sci. 39, 862 (2014)

    CAS  Google Scholar 

  10. 10.

    S.S. Ray, S.S. Chen, C.W. Li, N.C. Nguyen, H.T. Nguyen, RSC Adv. 6, 85495 (2016)

    CAS  Google Scholar 

  11. 11.

    X. Liao, M. Dulle, J.M. de Souza e Silva, R.B. Wehrspohn, S. Agarwal, S. Forster, H. Hou, P. Smith, A. Greiner, Science 366, 1376 (2019)

    CAS  Google Scholar 

  12. 12.

    Y.L. Kang, J. Zhang, G. Wu, M. Zhang, S.C. Chen, Y.Z. Wang, ACS Sustain. Chem. Eng. 6, 11783 (2018)

    CAS  Google Scholar 

  13. 13.

    J.X. Wu, J. Zhang, Y.L. Kang, G. Wu, S.C. Chen, Y.Z. Wang, ACS Sustain. Chem. Eng. 6, 1753 (2017)

    Google Scholar 

  14. 14.

    Y. Deng, W.Z. Yang, D. Shi, M. Wu, X.L. Xiong, Z.G. Chen, S.C. Wei, NPG Asia Mater. 11, 39 (2019)

    Google Scholar 

  15. 15.

    W. Fu, Y. Dai, J.P.H. Li, Z. Liu, Y. Yang, Y. Sun, Y. Huang, R. Ma, L. Zhang, Y. Sun, ACS Appl. Mater. Int. 9, 21258 (2017)

    CAS  Google Scholar 

  16. 16.

    Y. Liu, D. Lin, Z. Liang, J. Zhao, K. Yan, Y. Cui, Nat. Commun. 7, 10992 (2016)

    CAS  Google Scholar 

  17. 17.

    J. Lin, B. Ding, J. Yu, ACS Appl. Mater. Int. 2, 521 (2010)

    CAS  Google Scholar 

  18. 18.

    D. Papkov, Y. Zou, N. Andalib, A. Goponenko, S.Z.D. Cheng, Y.A. Dzenis, ACS Nano 7, 3324 (2013)

    CAS  Google Scholar 

  19. 19.

    L. Jiang, Y. Zhao, J. Zhai, Angew Chem. Int. Ed. Engl. 43, 4338 (2004)

    CAS  Google Scholar 

  20. 20.

    F. Zhang, B. Zuo, Z. Fan, Z. Xie, Q. Lu, X. Zhang, D.L. Kaplan, Biomacromology 13, 798 (2012)

    CAS  Google Scholar 

  21. 21.

    B. Khalid, X. Bai, H. Wei, Y. Huang, H. Wu, Y. Cui, Nano Lett. 17, 1140 (2017)

    CAS  Google Scholar 

  22. 22.

    R. Zhang, C. Liu, P.C. Hsu, C. Zhang, N. Liu, J. Zhang, H.R. Lee, Y. Lu, Y. Qiu, S. Chu, Y. Cui, Nano Lett. 16, 3642 (2016)

    CAS  Google Scholar 

  23. 23.

    P. Bi, X. Liu, Y. Yang, Z. Wang, R. Xiong, Adv. Mater. 4, 1900426 (2019)

    CAS  Google Scholar 

  24. 24.

    Y. Ding, H. Hou, Y. Zhao, Z. Zhu, H. Fong, Prog. Polym. Sci. 61, 67 (2016)

    CAS  Google Scholar 

  25. 25.

    Y. He, D. Han, J. Chen, Y. Ding, S. Jiang, C. Hu, S. Chen, H. Hou, RSC Adv. 4, 59936 (2014)

    CAS  Google Scholar 

  26. 26.

    C. Huang, S. Chen, D.H. Reneker, C. Lai, H. Hou, Adv. Mater. 18, 668 (2006)

    CAS  Google Scholar 

  27. 27.

    F. Lu, J. Wang, Z. Chang, J. Zeng, Mater. Des. 181, 108069 (2019)

    CAS  Google Scholar 

  28. 28.

    T.L. Zhai, Q. Du, S. Xu, Y. Wang, RSC Adv. 7, 22548 (2017)

    CAS  Google Scholar 

  29. 29.

    T. Arai, H. Kawakami, Polymer 53, 2217 (2012)

    CAS  Google Scholar 

  30. 30.

    A. Goponenko, H. Hou, Y. Dzenis, Polymer 52, 3776 (2011)

    CAS  Google Scholar 

  31. 31.

    W.J. Kim, J.Y. Chang, Mater. Lett. 65, 1388 (2011)

    CAS  Google Scholar 

  32. 32.

    D. Serbezeanu, A. Popa, T. Stelzig, I. Sava, R. Rossi, G. Fortunato, Text Res. J. 85, 17 (2015)

    Google Scholar 

  33. 33.

    J. Lasprilla, M. Álvarez, J.M. Lagaron, Mater. Today Commun. 14, 1 (2018)

    Google Scholar 

  34. 34.

    S. Lingaiah, K. Shivakumar, Eur. Polym. J. 49, 2101 (2013)

    CAS  Google Scholar 

  35. 35.

    H. Xie, K.K. Yang, Y.-Z. Wang, Prog. Polym. Sci. 95, 32 (2019)

    CAS  Google Scholar 

  36. 36.

    D.J. Liaw, K.L. Wang, Y.C. Huang, K.R. Lee, J.Y. Lai, C.S. Ha, Prog. Polym. Sci. 37, 907 (2012)

    CAS  Google Scholar 

  37. 37.

    J. Deng, L. Wang, L. Liu, W. Yang, Prog. Polym. Sci. 34, 156 (2009)

    CAS  Google Scholar 

  38. 38.

    J.P. Fouassier, X. Allonas, D. Burget, Prog. Org. Coat. 47, 16 (2003)

    CAS  Google Scholar 

  39. 39.

    B.E. Kelly, I. Bhattacharya, H. Heidari, M. Shusteff, C.M. Spadaccini, H.K. Taylor, Science 363, 1075 (2019)

    CAS  Google Scholar 

  40. 40.

    D.A. Rau, J. Herzberger, T.E. Long, C.B. Williams, ACS Appl. Mater. Int. 3, 34828 (2018)

    Google Scholar 

  41. 41.

    P. Gupta, S.R. Trenor, T.E. Long, G.L. Wilkes, Macromolecules 37, 9211 (2004)

    CAS  Google Scholar 

  42. 42.

    Q. Niu, L. Zeng, X. Mu, J. Nie, G. Ma, J. Ind. Eng. Chem. 34, 337 (2016)

    CAS  Google Scholar 

  43. 43.

    M.W. Thielke, E.P. Bruckner, D.L. Wong, P. Theato, Polymer 55, 5596 (2014)

    CAS  Google Scholar 

  44. 44.

    K. Shanmuganathan, S.M. Elliot, A.P. Lane, C.J. Ellison, ACS Appl. Mater. Int. 6, 14259 (2014)

    CAS  Google Scholar 

  45. 45.

    L. Qi, C.Y. Guo, M.G.H. Fu, Y. Zhang, L.M. Yin, L. Wu, J.G. Liu, X.M. Zhang, Polymers 11, 2055 (2019)

    CAS  Google Scholar 

  46. 46.

    F. Windrich, E.J. Kappert, M. Malanin, K.-J. Eichhorn, L. Häuβler, N.E. Benes, B. Voit, Eur. Polym. J. 84, 279 (2016)

    CAS  Google Scholar 

  47. 47.

    Y. Cao, Z. Gan, B. Jia, R.A. Evans, M. Gu, Opt. Express 19, 19486 (2011)

    CAS  Google Scholar 

  48. 48.

    S.M. Choi, S.H. Kwon, M.H. Yi, J. Appl. Polym. Sci. 100, 2252 (2006)

    CAS  Google Scholar 

  49. 49.

    Y. Watanabe, Y. Shibasaki, S. Ando, M. Ueda, Polym. J. 37, 270 (2005)

    CAS  Google Scholar 

  50. 50.

    Y. Liu, F. Fan, Y. Hong, J. Zang, G. Kang, X. Tan, Opt. Express 25, 20654 (2017)

    CAS  Google Scholar 

  51. 51.

    D. Sabol, M. Gleeson, S. Liu, J. Sheridan, J. Appl. Phys. 107, 053113 (2010)

    Google Scholar 

  52. 52.

    C.Y. Guo, Q.W. Wang, J.G. Liu, L. Qi, M.G. Huangfu, X. Wu, Y. Zhang, X.M. Zhang, Express Polym. Lett. 13, 724 (2019)

    CAS  Google Scholar 

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Acknowledgements

This work is supported by the Shandong Key Research and Development Program (No. 2019JZZY020235) and Fundamental Research Funds of China University of Geosciences, Beijing (No. 2652017345).

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Correspondence to Jin-gang Liu or Xiu-min Zhang.

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Qi, L., Guo, Cy., Zhang, Y. et al. An ultraviolet-assisted electrospinning procedure of polyimide ultrafine fibrous membranes fabricated by ester-type negative photosensitive polyimide. J Mater Sci: Mater Electron 31, 17647–17658 (2020). https://doi.org/10.1007/s10854-020-04319-1

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