Abstract
BiFeO3 as a type of single-phase room temperature multiferroic materials has aroused intensive investigations in recent years. Construction of porous BiFeO3 thin films is helpful for integration of other materials with desirable functionalities. Here, epitaxial BiFe0.93Mn0.07O3 (001) thin films were prepared on SrRuO3-buffered LaAlO3 (001) single crystal substrates by an all-solution chemical solution deposition, which is beneficial for large area thin film fabrication with low cost. Through addition of F-127 copolymer into the precursor solution, pores can be effectively introduced in BiFe0.93Mn0.07O3 (001) thin films while the epitaxy can be maintained. The amount of pores is gradually increased with increasing of the F-127 addition. The leakage current density is not obviously changed and the conduction mechanism can be well fitted through Ohmic behavior. Electric field dependent polarization hysteresis loops can be effectively maintained and the room temperature magnetic moment is obviously improved with the introduction of pores in epitaxial BiFe0.93Mn0.07O3 (001) thin films. The results will provide a facile route to fabricate large area epitaxial porous BiFeO3 thin films as an effective template for integration of other materials to realize desirable functionalities.
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References
W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials. Nature 442, 759–765 (2006)
R. Ramesh, N.A. Spaldin, Multiferroics: progress and prospects in thin films. Nat. Mater. 6, 21–29 (2007)
K.M. Cai, M.Y. Yang, H.L. Ju, S.M. Wang, Y. Ji, B.H. Li, K.W. Edmonds, Y. Sheng, B. Zhang, N. Zhang, S. Liu, H.Z. Zheng, K.Y. Wang, Electric field control of deterministic current-induced magnetization switching in a hybrid ferromagnetic/ferroelectric structure. Nat. Mater. 16, 712–716 (2017)
J. Wang, J.B. Neaton, H. Zheng, V. Nagarajan, S.B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D.G. Schlom, U.V. Waghmare, N.A. Spaldin, K.M. Rabe, M. Wuttig, R. Ramesh, Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 299, 1719–1722 (2003)
G. Catalan, J.F. Scott, Physics and applications of bismuth ferrite. Adv. Mater. 21, 2463–2485 (2009)
J.G. Wu, Z. Fan, D.Q. Xiao, J.G. Zhu, J. Wang, Multiferroic bismuth ferrite-based materials for multifunctional applications: ceramic bulks, thin films and nanostructures. Prog. Mater Sci. 84, 335–402 (2016)
Z.X. Cheng, X.L. Wang, S.X. Dou, H. Kimura, K. Ozawa, Improved ferroelectric properties in multiferroic BiFeO3 thin films through La and Nb codoping. Phys. Rev. B 77, 092101 (2008)
J.F. Li, J.L. Wang, M. Wuttig, R. Ramesh, N. Wang, B. Ruette, A.P. Pyatakov, A.K. Zvezdin, D. Viehland, Dramatically enhanced polarization in (001), (101), and (111) BiFeO3 thin films due to epitaxial-induced transitions. Appl. Phys. Lett. 84, 5261–5263 (2004)
M.C. Ramirez, C.F. Sanchez-Valdes, J.J. Gervacio-Arciniega, R. Font, C. Ostos, D. Bueno-Baques, M. Curie, J.L. Sanchez-Llamazares, J.M. Siqueiros, J. Raymond-Herrera, Room temperature ferromagnetism and ferroelectricity in strained multiferroic BiFeO3 thin films on La0.7Sr0.3MnO3/SiO2/Si substrates. Acta Mater. 128, 451–464 (2017)
T.J.A. Mori, C.L. Mouls, F.F. Morgado, P. Schio, J.C. Cezar, Parasitic phases at the origin of magnetic moment in BiFeO3 thin films grown by low deposition rate RF sputtering. J. Appl. Phys. 122, 124102 (2017)
S.Y. Yang, F. Zavaliche, L. Mohaddes-Ardabili, V. Vaithyanathan, D.G. Scholm, Y.J. Lee, Y.H. Chu, M.P. Cruz, Q. Zhan, T. Zhao, R. Ramesh, Metalorganic chemical vapor deposition of lead-free ferroelectric BiFeO3 films for memory applications. Appl. Phys. Lett. 87, 102903 (2005)
J.F. Ihlefeld, N.J. Podraza, Z.K. Liu, R.C. Rai, X. Xu, T. Heeg, Y.B. Chen, J. Li, R.W. Collins, J.L. Musfeldt, X.Q. Pan, J. Schubert, R. Ramesh, D.G. Schlom, Optical band gap of BiFeO3 grown by molecular-beam epitaxy. Appl. Phys. Lett. 92, 142908 (2008)
X.W. Tang, X.B. Zhu, J.M. Dai, Y.P. Sun, Self-limited growth, dielectric, leakage and ferroelectric properties of nanocrystalline BiFeO3 thin films by chemical solution deposition. Acta Mater. 61, 1739–1747 (2013)
R.W. Schwartz, Chemical solution deposition of perovskite thin films. Chem. Mater. 9, 2325–2340 (1997)
F.F. Lange, Chemical solution routes to single-crystal thin films. Science 273, 903–909 (1996)
G.F. Zou, J. Zhao, H.M. Luo, T.M. McCleskey, A.K. Burrell, Q.X. Jia, Polymer-assisted-deposition: a chemical solution route for a wide range of materials. Chem. Soc. Rev. 42, 439–449 (2013)
M. Tomczyk, A. Mahajan, A. Tkach, P.M. Vilarinho, Interface-based reduced coercivity and leakage currents of BiFeO3 thin films: a comparative study. Mater. Des. 160, 1322–1334 (2018)
Q. Zhang, N. Valanoor, O. Standard, Epitaxial (001) BiFeO3 thin-films with excellent ferroelectric properties by chemical solution deposition-the role of gelation. J. Mater. Chem. C 3, 582–595 (2015)
Q. Zhang, D. Sando, V. Nagarajan, Chemical route derived bismuth ferrite thin films and nanomaterials. J. Mater. Chem. C 4, 4092–4124 (2016)
L.H. Jin, X.W. Tang, D.P. Song, R.H. Wei, J. Yang, J.M. Dai, W.H. Song, X.B. Zhu, Y.P. Sun, Annealing temperature effects on (111)-oriented BiFeO3 thin films deposited on Pt/Ti/SiO2/Si by chemical solution deposition. J. Mater. Chem. C 3, 10742–10747 (2015)
L.H. Jin, X.W. Tang, R.H. Wei, B.B. Yang, J. Yang, J.M. Dai, W.H. Song, X.B. Zhu, Y.P. Sun, BiFeO3(00 l)/LaNiO3/Si thin films with enhanced polarization: an all-solution approach. RSC Adv. 3, 78629–78635 (2016)
S.J. Yang, F.Q. Zhang, X.B. Xie, H.J. Sun, L.P. Zhang, S.H. Fan, Enhanced leakage and ferroelectric properties of Zn-doped BiFeO3 thin films grown by sol-gel method. J. Alloys Compd. 734, 243–249 (2018)
L. Yun, G.Q. Tan, M.Y. Guo, Z.J. Chai, L. Lv, M.T. Xue, X.X. Ren, J.C. Li, H.J. Ren, A. Xia, Multiferroic properties of La/Er/Mn/Co multi-doped BiFeO3 thin films. Ceram. Int. 45, 11765–11775 (2019)
L. Yao, X.H. Wu, S.H. Yang, Y.L. Zhang, Structural and optical properties of Ca doped BiFeO3 thin films prepared by a sol-gel method. Ceram. Int. 43, S470–S473 (2017)
B.B. Yang, L.H. Jin, R.H. Wei, X.W. Tang, L. Hu, P. Tong, J. Yang, W.H. Song, J.M. Dai, X.B. Zhu, Y.P. Sun, S.J. Zhang, X.L. Wang, Z.X. Cheng, Chemical solution route for high-quality multiferroic BiFeO3 thin films. Small (2020). https://doi.org/10.1002/smll.201903663)
A. Gruverman, Scaling effect on statistical behavior of switching parameters of ferroelectric capacitors. Appl. Phys. Lett. 75, 1452–1454 (1999)
Y.L. Zhang, J. Qi, Y.H. Wang, Y. Tian, J.K. Zhang, T.J. Hu, M.B. Wei, Y.Q. Liu, J.H. Yang, Tuning magnetic properties of BiFeO3 thin films by controlling Mn doping concentration. Ceram. Int. 44, 6054–6061 (2018)
Y.Z. Wang, R.R. Liu, J. Qian, X.S. Sun, Y.J. Han, C.H. Yang, Reduced leakage current, enhanced ferroelectric and dielectric properties in Mn-doped BiFeO3 thin film composited with TiO2 layers. Ceram. Int. 45, 12285–12289 (2019)
S. Yang, G.B. Ma, L. Xu, C.Y. Deng, X. Wang, Improved ferroelectric properties and band-gap tuning in BiFeO3 films via substitution of Mn. RSC Adv. 9, 29238–29245 (2019)
L.H. Jin, J.Z. Lu, D.P. Song, B.B. Yang, X.B. Zhu, Modified electrical properties of chemical solution deposited epitaxial BiFeO3 thin films by Mn substitution. Ceram. Int. 44, 11658–11664 (2018)
A. Castro, P. Ferreira, P.M. Vilarinho, Block copolymer-assisted nanopatterning of porous lead titanate thin films for advanced electronics. J. Phys. Chem. C 120, 10961–10967 (2016)
C. Reitz, P.M. Leufke, H. Hahn, T. Brezesinski, Ordered mesoporous thin film ferroelectrics of biaxially textured lead zirconate titanate (PZT) by chemical solution deposition. Chem. Mater. 26, 2195–2202 (2014)
T.E. Quickel, L.T. Schelhas, R.A. Farrell, N. Petkov, V.H. Le, S.H. Tolber, Mesoporous bismuth ferrite with amplified magnetoelectric coupling and electric field-induced ferrimagnetism. Nat. Commun. 6, 6562 (2014)
A. Castro, M.A. Martins, L.P. Ferreira, M. Godinho, P.M. Vilarinho, P. Ferreira, Multifunctional nanopatterned porous bismuth ferrite thin films. J. Mater. Chem. C 7, 7788–7797 (2019)
R.V. William, A. Marikani, D. Madhavan, Dielectric behavior and magnetical response for porous BFO thin films with various thicknesses over Pt/Ti/SiO2/Si substrate. Int. Ceram. 42, 6807–6716 (2016)
D.Y. Yang, X.W. Tang, R.H. Wei, Z.Z. Hui, W.H. Song, X.B. Zhu, Y.P. Sun, Epitaxial growth of SrRuO3 thin films with different orientation by chemical solution deposition. J. Alloys Compd. 682, 154–159 (2016)
D. Lee, M.G. Kim, S. Ryu, H.M. Jang, Epitaxially grown La-modified BiFeO3 magnetoferroelectric thin films. Appl. Phys. Lett. 86, 222903 (2005)
E.M. Choi, S. Patnaik, E. Weal, S.L. Sahonta, H. Wang, Z. Bi, J. Xiong, M.G. Blamire, Q.X. Jia, J.L. MacManus-Driscoll, Strong room temperature magnetism in highly resistive strained thin films of BiFe0.5Mn0.5O3. Appl. Phys. Lett. 98, 012509 (2011)
J.Z. Huang, Y. Wang, Y.H. Lin, M. Li, C.W. Nan, Effect of Mn doping on electric and magnetic properties of BiFeO3 thin films by chemical solution deposition. J. Appl. Phys. 106, 063911 (2009)
C.F. Chung, J.P. Lin, J.M. Wu, Influence of Mn and Nb dopants on electric properties of chemical-solution-deposited BiFeO3 films. Appl. Phys. Lett. 88, 242909 (2006)
J.G. Wu, J. Wang, D.Q. Xiao, J.G. Zhu, Leakage mechanism of cation-modified BiFeO3 thin film. AIP Adv. 1, 022138 (2011)
G.W. Pabst, L.W. Martin, Y.H. Chu, R. Ramesh, Leakage mechanisms in BiFeO3 thin films. Appl. Phys. Lett. 90, 072902 (2007)
Z.S. Liang, C.R. Ma, L.K. Shen, L. Lu, X.L. Lu, X.J. Lou, M. Liu, C.L. Jia, Flexible lead-free oxide film capacitors with ultrahigh energy storage performances in extremely wide operating temperature. Nano Energy 57, 519–527 (2019)
W. Liu, G. Tan, G. Dong, X. Yan, W. Ye, H. Ren, A. Xia, Structure transition and multiferroic properties of Mn-doped BiFeO3 thin films. J. Mater. Sci. Mater. Electron. 25, 723 (2014)
A.V. Dmitriev, E.V. Vladimirova, M.V. Kandaurov, D.G. Kellerman, A.Y. Chufarov, N.V. Tarakina, A.P. Tyutyunnik, Self-assembly of hollow bismuth ferrite spheres from nitrate solutions. J. Electron. Mater. 48, 4959–4969 (2019)
S. Huang, F. Hong, Z.C. Xia, F. Yang, X.X. Zhang, G.L. Xiao, Y.J. Song, D.Q. Jiang, H. Deng, Z.W. Ouyang, J.F. Wang, Z.M. Tian, J.B. Han, L.H. Yao, A. Forget, D. Colson, Z.X. Cheng, Multiferroic behavior from synergetic response of multiple ordering parameters in BiFeO3 single crystal under high magnetic field up to 50 T. J. Appl. Phys. 127, 044101 (2020)
Acknowledgements
This work was supported by Key Project of Support Plan for the Outstanding Youth of Anhui Provincial Colleges and Universities (gxyqZD2016144), and the Natural Science Foundation of Anhui Education Office (No. KJ2019A0779).
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Zhang, L., Yang, B., Deng, Y. et al. All chemical solution deposition of epitaxial porous BiFe0.93Mn0.07O3 thin films. J Mater Sci: Mater Electron 31, 17404–17411 (2020). https://doi.org/10.1007/s10854-020-04296-5
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DOI: https://doi.org/10.1007/s10854-020-04296-5