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Effects of Cr/Ti co-doping on the electrical and thermal properties of tantalum-based electrolyte materials for solid oxide fuel cells

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Abstract

New triclinic oxide material Ta1−x−yTixCryO2.5−δ (x = 0.077, y = 0–0.053) was synthesized via an oxalate co-precipitation method and tested as a novel electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Structural, electrical, and thermal properties of tantalum-based electrolyte co-doping with Cr3+/Ti4+ content were studied. X-ray powder diffraction showed that the crystal structure changed from orthorhombic to triclinic due to co-doped, and its high-temperature triclinic (pseudo-tetragonal) phase of tantalum pentoxide (H-Ta2O5) structure was stabilized to room temperature by doping. The crystalline phase facilitates the generation of more oxygen vacancies, which increases the electrical conductivity. The appearance of oxygen vacancies in the crystal with triclinic structure was confirmed with Raman spectroscopy and X-ray photoelectron spectroscopy. Scanning electron microscopy results exhibited the grain size decreases gradually with doping. Impedance curves showed high total ionic conductivity (1.48 × 10–1 S/cm at 700 °C) and low activation energy (Ea = 0.857 eV) for Ta0.9Ti0.067Cr0.033O2.5−δ. Thermal expansion coefficients (3.09 × 10–6 K−1) for co-doped samples were much lower in comparison to other electrolytes. Based on the results reported in this work, Ta1−x−yTixCryO2.5−δ can be an excellent oxygen conductor and recommended as solid electrolytes for IT-SOFC applications.

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Acknowledgements

The authors gratefully acknowledge the financial support of Hainan Provincial Natural Science Foundation of China (519MS022), the Key Scientific & Technological Project of Hainan Province (ZDKJ2017011), Special funds for guiding local scientific and technological development by China government (ZY2019HN0904), National Key Research and Development Program of China (2016YFC0700804), and Natural Science Foundation of China (51562008).

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  1. State Key Laboratory of Marine Resource Utilization in South China Sea (Hainan University) and Special Glass Key Lab of Hainan Province, Hainan University, Haikou, 570228, China

    Shuang Ding, Junwei Zhang, Shun Yang, Ziyang Song, Hong Jiang, Changjiu Li & Yongjun Chen

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  1. Shuang Ding
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  2. Junwei Zhang
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Correspondence to Changjiu Li.

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Ding, S., Zhang, J., Yang, S. et al. Effects of Cr/Ti co-doping on the electrical and thermal properties of tantalum-based electrolyte materials for solid oxide fuel cells. J Mater Sci: Mater Electron 31, 17307–17319 (2020). https://doi.org/10.1007/s10854-020-04286-7

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