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Crystal growth, optical, spectroscopic studies, PL behaviour and Hirshfield surface analysis of a third-order nonlinear optical Cesium Hydrogen Oxalate Dihydrate (CHOD) single crystal

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Abstract

Single crystal of oxalato-bridged, Cesium-extended frame work, Cesium Hydrogen Oxalate Dihydrate (CHOD), has been synthesized by slow evaporation solution growth technique. Diffraction studies were used to identify the geometry of the atoms present in the primitive cell of the crystal. The title compound has crystallized in triclinic category-bearing space group P-1. Spectroscopic investigation of the compound was done by FTIR and FT-Raman techniques. From UV–Vis studies, optical absorption edge was ascertained as 241 nm. It has excellent optical transmission window throughout the visible region. Energy dispersive X-ray analysis (EDAX) affirms the presence of Cesium in the compound. Fluorescence decay of the molecules present in the excited state for the crystal was studied. Hirshfield surface maps intermolecular contacts present in the crystal and the contributions made by the contacts were assessed by 2D Finger print plots. Z-Scan studies ascertain the magnitude of nonlinear refractive index and nonlinear refraction.

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Acknowledgements

Authors extend their thanks to SAIF IITM Chennai, St. Joseph's College, Trichy and VIT Chennai for accomplishing characterization techniques.

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Authors and Affiliations

  1. PG& Research Department of Physics, Arignar Anna Govt. Arts College, Cheyyar, 604 407, Tamil Nadu, India

    S. Sudha

  2. Department of Physics, Bharath Institute of Higher Education and Research, Agaram Road, Chennai, 600073, Tamil Nadu, India

    C. Rathika Thaya Kumari

  3. Department of Physics, Peri Institute of Technology, Chennai, Tamil Nadu, India

    M. Nageshwari

  4. Department of Physics, Govt. Thirumagal Mills College, Gudiyattam, 632602, Vellore, Tamil Nadu, India

    P. Ramesh

  5. Department of Physics, School of Advanced Sciences, VIT, Chennai, 600127, Tamil Nadu, India

    G. Vinitha

  6. Department of Physics, Dr. Ambedkar Govt. Arts College, Vyasarpadi, Chennai, 600039, Tamil Nadu, India

    M. Lydia Caroline

  7. Department of Chemistry, Bharath Institute of Higher Education and Research, Agaram Road, Chennai, 600073, Tamil Nadu, India

    G. Mathubala & A. Manikandan

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  1. S. Sudha
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Correspondence to M. Lydia Caroline.

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Sudha, S., Kumari, C.R.T., Nageshwari, M. et al. Crystal growth, optical, spectroscopic studies, PL behaviour and Hirshfield surface analysis of a third-order nonlinear optical Cesium Hydrogen Oxalate Dihydrate (CHOD) single crystal. J Mater Sci: Mater Electron 31, 15028–15037 (2020). https://doi.org/10.1007/s10854-020-04066-3

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