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Novel orange-red emitting Sm3+-doped Bi4Sr3Te5O19 phosphors with high color purity for white light-emitting diodes

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Abstract

Novel Sm3+-doped tellurate Bi4Sr3Te5O19 phosphors have been prepared through the solid-state reaction for the first time. The powder phase purity, particle morphology, and luminescence properties are analyzed in detail. Under the 405 nm excitation, the Bi4Sr3Te5O19:Sm3+ phosphors show orange-red emission with four typical peaks. The optimal doping concentration of Bi4Sr3Te5O19:xSm3+ is found at x = 0.02 mol and the critical transfer distance (Rc) is 21.08 Å. The color purity of Bi4Sr3Te5O19:Sm3+ phosphors are as high as 99.9%. The commission international de l'Eclairage (CIE) color coordinates are in the orange-red region. Temperature-related photoluminescence spectra and the corresponding CIE color coordinates indicate the phosphors possess good thermal stability and stable color property. Besides, the internal quantum efficiency (IQE) of the Bi4Sr3Te5O19:0.02Sm3+ phosphor reached 17.23%. Thus, Bi4Sr3Te5O19:Sm3+ phosphors have great potential applications in abundant lighting and displays.

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Acknowledgements

The work was supported by Natural Science Foundation of Shaanxi Province (Grant Nos. 2018JM4028, 2019JM545), the Project of the Collaborative Innovation Centre of Shaanxi in China (QBXT-Z(P)-18-2).

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Authors and Affiliations

  1. School of Chemistry and Environmental Science, Shaanxi University of Technology, Hanzhong, 723001, People’s Republic of China

    Fengmin Song

  2. Collaborative Innovation Center for Bioresource Comprehensive Development in the Qinling-Bashan area, Hanzhong, 723001, People’s Republic of China

    Fengmin Song

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Correspondence to Fengmin Song.

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Song, F. Novel orange-red emitting Sm3+-doped Bi4Sr3Te5O19 phosphors with high color purity for white light-emitting diodes. J Mater Sci: Mater Electron 31, 12417–12426 (2020). https://doi.org/10.1007/s10854-020-03788-8

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  • DOI: https://doi.org/10.1007/s10854-020-03788-8

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