Abstract
This work reports a molecularly imprinting polymer based on environmentally friendly and non-toxic ZnO quantum dots for the selective detection sulfadimidine. The MIP@ZnO was prepared by sol–gel method, which usedZnO quantum dots, TEOS, APTES, ammonia as signal materials, cross-linker, function monomer, and initiator, respectively. Result proved that MIP@ZnO exhibited excellent selective fluorescence quenching in the presence of sulfadimidine, good linear relationship in the range of 0–40 μmol L−1 with a correlation coefficient (R2) of 0.98547 was obtained, and the imprinting factor was 2.83. Furthermore, MIP@ZnO has been successfully applied for detection SM2 in real samples with the spiked recoveries ranging from 95.6 to 99.8% with RSD below 2.38%.
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Acknowledgements
The work was funded by National Natural Science Foundation of China (Grant Nos. 21607013, 5102026), the Natural Science Basic Research Plan in Shaanxi Province of China (2020JM-221), the Fund Project of Shaanxi Key Laboratory of Land Consolidation (2018-JC01), the Fundamental Research Funds for the Central Universities, CHD (300102310203), and Colation and Entrepreneurship Project (201810710127, 201910710466).
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Zheng, J., Cheng, K., Wu, Y. et al. Environment-friendly ZnO-based molecularly imprinting polymers fluorescence sensor for direct detection of sulfadimidine. J Mater Sci: Mater Electron 31, 9550–9558 (2020). https://doi.org/10.1007/s10854-020-03497-2
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DOI: https://doi.org/10.1007/s10854-020-03497-2