Skip to main content
SpringerLink
Log in

Analysis of structure and magnetic behavior in M-type hexaferrite compounds Sr1−xYxFe10CoTiO19

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Herein, we report the synthesis, structure and magnetic properties of Y-substituted CoTi-SrM hexaferrite Sr1−xYxFe10CoTiO19 (0.00 ≤ x ≤ 0.20) through a series of systematical measurements. The single phase of polycrystalline SrM hexaferrites can be obtained within the concentration x ≤ 0.15, and the lattice constants (a and c) show a corresponding variety due to the difference of substituted ionic radius (Δr). Besides, FTIR spectra also give the characteristic features of Fe3+–O2+ intrinsic vibration at tetrahedral and octahedral sites, which further confirm the integrity of M-type hexagonal magnetic structure. The comprehensive magnetic measurements [M(T) and M(H)] indicate a considerable results of temperature and magnetic properties. Especially, Ms can be improved to 79.19 emu/g under the definite substitution, and the soft magnetic behavior can also be preserved because of the fairly low Hcj. On the basis of the analyses in our present work, this substituted hexaferrite exhibits a quite promising candidate for high-frequency multilayer inductors.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. B.K. Rai, S.R. Mishra, V.V. Nguyen, J.P. Liu, Synthesis and characterization of high coercivity rare-earth ion doped Sr0.9RE0.1Fe10Al2O19 (RE: Y, La, Ce, Pr, Nd, Sm, and Gd). J. Alloys Compd. 550, 198–203 (2013)

    Article  CAS  Google Scholar 

  2. A.M. Alsmadi, I. Bsoul, S.H. Mahmood, G. Alnawashi, K. Prokeš, K. Siemensmeyer, B. Klemke, H. Nakotte, Magnetic study of M-type doped barium hexaferrite nanocrystalline particles. J. Appl. Phys. 114, 243910 (2013)

    Article  Google Scholar 

  3. G.L. Tan, X.N. Chen, Structure and multiferroic properties of barium hexaferrite ceramics. J. Magn. Magn. Mater. 327, 87–90 (2013)

    Article  CAS  Google Scholar 

  4. Ü. Özgür, Y. Alivov, H. Morkoç, Microwave ferrites, part 1: fundamental properties. J. Mater. Sci: Mater. Electron. 20, 789–834 (2009)

    Google Scholar 

  5. F.N.T. Gonzalez, A.M.B. Miró, F.S.D. Jesús, C.A.C. Escobedo, S. Ammar, Mechanism and microstructural evolution of polyol mediated synthesis of nanostructured M-type SrFe12O19. J. Magn. Magn. Mater. 407, 188–194 (2016)

    Article  Google Scholar 

  6. D.A. Vinnik, D.A. Zherebtsov, L.S. Mashkovtseva, S. Nemrava, A.S. Semisalova, D.M. Galimov, S.A. Gudkova, I.V. Chumanov, L.I. Isaenko, R. Niewa, Growth, structural and magnetic characterization of Co- and Ni-substituted barium hexaferrite single crystals. J. Alloys Compd. 628, 480–484 (2015)

    Article  CAS  Google Scholar 

  7. P.A.M. Castellanos, J.A. Rivera, A.C. Fuentes, R.L. Serrano, Magnetic and microstructural properties of the Ti4+-doped Barium hexaferrite. J. Magn. Magn. Mater. 280, 214–220 (2004)

    Article  Google Scholar 

  8. L. Peng, L.Z. Li, R. Wang, Y. Hu, X.Q. Tu, X.X. Zhong, Effect of La–Co substitution on the crystal structure and magnetic properties of low temperature sintered Sr1-xLaxFe12-xCoxO19 (x=0–0.5) ferrites. J. Magn. Magn. Mater. 393, 399–403 (2015)

    Article  CAS  Google Scholar 

  9. K. Uji, T. Waki, Y. Tabata, H. Nakamura, Phase stability, single crystal growth, and anisotropic magnetic properties of Ca–La magnetoplumbite-type ferrite. J. Solid State. Chem. 245, 17–22 (2017)

    Article  CAS  Google Scholar 

  10. C.C. Liu, X.S. Liu, S.J. Feng, K.M.U. Rehman, M.L. Li, C. Zhang, H.H. Li, X.Y. Meng, Microstructure and magnetic properties of M-type strontium hexagonal ferrites with Y-Co substitution. J. Magn. Magn. Mater. 436, 126–129 (2017)

    Article  CAS  Google Scholar 

  11. S. Bierlich, T. Reimann, H. Bartsch, J. Töpfer, Co/Ti-substituted M-type hexagonal ferrites for high-frequency multilayer inductors. J. Magn. Magn. Mater. 384, 1–5 (2015)

    Article  CAS  Google Scholar 

  12. A. Baykal, H. Güngüneş, H. Sözeri, M. Amir, I. Auwal, S. Asiri, S.E. Shirsath, A.D. Korkmaz, Magnetic properties and Mössbauer spectroscopy of Cu–Mn substituted BaFe12O19 hexaferrites. Ceram. Int. 43, 15486–15492 (2017)

    Article  CAS  Google Scholar 

  13. D. Ravinder, P. Shalini, P. Mahesh, K.K. Rao, M. Vithal, B.S. Boyanov, Electrical conductivity of Ba–Co–Ti hexagonal ferrites. J. Alloys Compd. 364, 17–22 (2004)

    Article  CAS  Google Scholar 

  14. M. Jean, V. Nachbaur, J. Bran, J.M.L. Breton, Synthesis and characterization of SrFe12O19 powder obtained by hydrothermal process. J. Alloys Compd. 496, 306–312 (2010)

    Article  CAS  Google Scholar 

  15. Y.J. Yang, J.X. Shao, F.H. Wang, X.S. Liu, S.J. Feng, D.H. Huang, J.S. Yang, C.G. Jin, Magnetic and structural properties of Sr0.75La0.25FexCu0.20O19 (10.40≤x≤11.80) hexagonal ferrites prepared by the solid-state reaction. J. Magn. Magn. Mater. 406, 144–148 (2016)

    Article  CAS  Google Scholar 

  16. C.C. Liu, X.C. Kan, F. Hu, X.S. Liu, S.J. Feng, J.Y. Hu, W. Wang, K.M.U. Rehman, M. Shezad, C. Zhang, H.H. Li, S.Q. Zhou, Q.Y. Wu, Investigations of Ce-Zn co-substitution on crystal structure and ferrimagnetic properties of M-type strontium hexaferrites Sr1-xCexFe12-xZnxO19 compounds. J. Alloys Compd. 785, 452–459 (2019)

    Article  CAS  Google Scholar 

  17. Z.F. Zi, Q.C. Liu, J.M. Dai, Y.P. Sun, Effects of Ce–Co substitution on the magnetic properties of M-type barium hexaferrites. Solid State. Commun. 152, 894–897 (2012)

    Article  CAS  Google Scholar 

  18. C.C. Liu, X.C. Kan, F. Hu, X.S. Liu, S.J. Feng, J.Y. Hu, W. Wang, K.M.U. Rehman, M. Shezad, C. Zhang, H.H. Li, S.Q. Zhou, Q.Y. Wu, Characterizations of magnetic transition behavior and electromagnetic properties of Co–Ti co-substituted SrM-based hexaferrites SrCoxTixFe12-2xO19 compounds. J. Alloys Compd. 784, 1175–1186 (2019)

    Article  CAS  Google Scholar 

  19. R. Sai, M. Sato, S. Takeda, S. Yabukami, M. Yamaguchi, Co/Ti-substituted SrM-based composite sheets: High frequency permeability and electromagnetic noise suppression above 6 GHz. J. Magn. Magn. Mater. 459, 49–56 (2018)

    Article  CAS  Google Scholar 

  20. C.C. Liu, X.S. Liu, S.J. Feng, K.M.U. Rehman, M.L. Li, C. Zhang, H.H. Li, X.Y. Meng, Effect of Y-La-Co substitution on microstructure and magnetic properties of M-type strontium hexagonal ferrites prepared by ceramic method. J. Magn. Magn. Mater. 445, 1–5 (2018)

    Article  CAS  Google Scholar 

  21. J. Singh, C. Singh, D. Kaur, H. Zaki, I.A.A. Latif, S.B. Narang, R. Jotania, S.R. Mishra, R. Joshi, P. Dhruv, M. Ghimire, S.E. Shirsath', S.S. Meena, Elucidation of phase evolution, microstructural, Mössbauer and magnetic properties of Co2+–Al3+ doped M-type Ba–Sr hexaferrites synthesized by a ceramic method. J. Alloys Compd. 695, 1112–1121 (2017)

    Article  CAS  Google Scholar 

  22. W.F.F.W. Ali, M. Othman, M.F. Ain, N.S. Abdullah, Z.A. Ahmad, Studies on the formation of yttrium iron garnet (YIG) through stoichiometry modification prepared by conventional solid-state method. J. Eur. Ceram. Soc. 33, 1317–1324 (2013)

    Article  CAS  Google Scholar 

  23. V. Rathod, A.V. Anupama, R.V. Kumar, V.M. Jali, B. Sahoo, Correlated vibrations of the tetrahedral and octahedral complexes and splitting of the absorption bands in FTIR spectra of Li-Zn ferrites. Vib. Spectrosc. 92, 267–272 (2017)

    Article  CAS  Google Scholar 

  24. C.C. Chauhan, A.R. Kagdi, R.B. Jotania, A. Upadhyay, C.S. Sandhu, S.E. Shirsath, S.S. Meena, Structural, magnetic and dielectric properties of Co–Zr substituted M-type calcium hexagonal ferrite nanoparticles in the presence of α-Fe2O3 phase. Ceram. Int. 44, 17812–17823 (2018)

    Article  CAS  Google Scholar 

  25. A.M. Alsmadi, I. Bsoul, S.H. Mahmood, G. Alnawashi, F.M.A. Dweri, Y. Maswadeh, U. Welp, Magnetic study of M-type Ru–Ti doped strontium hexaferrite nanocrystalline particles. J. Alloys Compd. 648, 419–427 (2015)

    Article  CAS  Google Scholar 

  26. Y.J. Yang, F.H. Wang, J.X. Shao, D.H. Huang, H. He, A.V. Trukhanov, S.V. Trukhanov, Influence of Nd-NbZn co-substitution on structural, spectral and magnetic properties of M-type calcium-strontium hexaferrites Ca0.4Sr0.6-xNdxFe12.0-x(Nb0.5Zn0.5)xO19. J. Alloys Compd. 765, 616–623 (2018)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Research on Quality Engineering Project Foundation of Anhui Province (Nos. 2016sjjd074, 2018mooc385), Academic Technical Leader of Suzhou University (No. 2018xjxs01), School-Enterprise Cooperation Project of Suzhou University (No. 2019hx010), Dual-ability Teaching Team of Suzhou University (No. 2019XJSN04) and Excellent Young Talents Support Project of Anhui Provincial Department of Education (gxyq2019101).

Author information

Authors and Affiliations

  1. Anhui Key Laboratory of Spintronics and Nanomaterials Research, Suzhou University, Suzhou, 234000, Anhui, People’s Republic of China

    Bangfeng Zong & Xiaofei Niu

Authors
  1. Bangfeng Zong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiaofei Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xiaofei Niu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zong, B., Niu, X. Analysis of structure and magnetic behavior in M-type hexaferrite compounds Sr1−xYxFe10CoTiO19. J Mater Sci: Mater Electron 31, 5290–5297 (2020). https://doi.org/10.1007/s10854-020-03089-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-020-03089-0

Search

Navigation