Abstract
Single-crystal \(\hbox {BaTiO}_3\) (BTO) films were prepared by pulsed laser deposition (PLD) on (100) \(\hbox {SrRuO}_3\)(SRO) buffered \(\hbox {SrTiO}_3\)(STO) substrates, which were treated by rapid thermal processing (RTP) in the temperature range of 600–750 \(^\circ {\hbox {C}}\). The XRD, Ferroelectric test system, Hall effect Test Station and current–voltage (I–V) characteristics were used to study microstructure and electrical properties. The results show that the RTP temperature can affect the microstructure of films, the contact of the interfaces and ferroelectric properties. The films exhibit small leakage current, resistance, barrier height, and better ferroelectric properties treated by RTP at \(650 \,^\circ {\hbox {C}}\).
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References
Y. Li, R. Yu, H. Zhou, Z. Cheng, X. Wang, L. Li, J. Zhu, Direct observation of thickness dependence of ferroelectricity in freestanding BaTiO3 thin film. J. Am. Ceram. Soc. 98(9), 2710–2712 (2015)
Q. Zhang, X. Xia, J. Wang, Y. Su, Effects of epitaxial strain, film thickness and electric-field frequency on the ferroelectric behavior of BaTiO3 nano films. Int. J. Solids Struct. 144, 32–45 (2018)
A. Chen, F. Khatkhatay, W. Zhang, C. Jacob, L. Jiao, H. Wang, Strong oxygen pressure dependence of ferroelectricity in BaTiO3/SrRuO3/SrTiO3 epitaxial heterostructures. J. Appl. Phys. 114(12), 124101 (2013)
Y.J. Shin, L. Wang, Y. Kim, Oxygen partial pressure during pulsed laser deposition: deterministic role on thermodynamic stability of atomic termination sequence at SrRuO3/BaTiO3 interface. ACS Appl. Mater. Interfaces 9(32), 27305–27312 (2017)
P.-C. Shen, W.-C. Ho, M.-Y. Tsai, Y.-M. Hsin, Post-annealing on the ohmic contact and gate recess simultaneously in AlGaN/GaN MIS-HEMT. In: Meeting Abstracts, no. 31, The Electrochemical Society, pp. 1345–1345 (2019)
K.-H. Chen, C.-C. Diao, C.-F. Yang, B.-X. Wang, Electrical characteristics of Bi4Ti3O12 ferroelectric thin films annealed under different temperature for applications in nonvolatile memory devices. Ferroelectrics 385(1), 646–53 (2009)
B. Pandey, T. Bhat, B. Roul, K. Nanda, S. Krupanidhi, BtO/GaN heterostructure based on Schottky junction for high-temperature selective ultra-violet photo detection. J. Phys. D 51(4), 045104 (2018)
C.-W. Nan, M. Bichurin, S. Dong, D. Viehland, G. Srinivasan, Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J. Appl. Phys. 103(3), 1 (2008)
C. Deng, Y. Zhang, J. Ma, Y. Lin, C.-W. Nan, Magnetic-electric properties of epitaxial multiferroic NiFe2O4–BaTiO3 heterostructure. J. Appl. Phys. 102(7), 074114 (2007)
C. Deng, Y. Zhang, J. Ma, Y. Lin, C.-W. Nan, Magnetoelectric effect in multiferroic heteroepitaxial BaTiO3–NiFe2O4 composite thin films. Acta Mater. 56(3), 405–412 (2008)
W. Lee, C.H. An, S. Yoo, W. Jeon, M.J. Chung, S.H. Kim, C.S. Hwang, Electrical properties of ZrO2/Al2O3/Zro2-based capacitors with TiN, Ru, and TiN/Ru top electrode materials. Phys. Status Solid. 12(10), 1800356 (2018)
E. Venkata Ramana, S. Yang, R. Jung, M. Jung, B. Lee, C. Jung, Ferroelectric and magnetic properties of Fe-doped BaTiO3 thin films grown by the pulsed laser deposition. J. Appl. Phys. 113(18), 187219 (2013)
J. Lyu, I. Fina, R. Solanas, J. Fontcuberta, F. S ánchez, Tailoring lattice strain and ferroelectric polarization of epitaxial BaTiO3 thin films on si (001). Sci. Rep. 8(1), 495 (2018)
B. Dudem, L.K. Bharat, H. Patnam, A.R. Mule, J.S. Yu, Enhancing the output performance of hybrid nanogenerators based on Al-doped BaTiO3 composite films: a self-powered utility system for portable electronics. J. Mater. Chem. A 6(33), 16101–16110 (2018)
M. Welke, P. Huth, K. Dabelow, M. Gorgoi, K. Schindler, A. Chassé, R. Denecke, Energy shifts in photoemission lines during the tetragonal-to cubic-phase transition in BaTiO3 single crystals and systems with CoFe2O4 and NiFe2O4 overlayers. J. Phys. Condens. Matter 30(20), 205401 (2018)
B. Wang, Y. Ma, B. Na, R. Lv, H. Liu, W. Li, H. Zhou, Enhanced dielectric thermal stability and permittivity of flexible composite films based on BaTiO3 nanoparticles highly filled PVDF/PAN blend nanofibrous membranes. Polym. Compos. 39(S3), E1841–E1848 (2018)
G. Panomsuwan, H. Manuspiya, A comparative study of dielectric and ferroelectric properties of sol–gel-derived BaTiO3 bulk ceramics with fine and coarse grains. Appl. Phys. A 124(10), 713 (2018)
A. Aidoud, T. Maroutian, S. Matzen, G. Agnus, B. Amrani, K. Driss-Khodja, P. Aubert, P. Lecoeur, Tuning the growth and strain relaxation of ferroelectric BaTiO3 thin films on SrRuO3 electrode: influence on electrical properties. Eur. Phys. J. Appl. Phys. 80(3), 30303 (2017)
M. Zhang, C. Deng, Fractal simulation of thin film nucleation growth process using a diffusion-limited aggregation model. Mod. Phys. Lett. B 32(33), 1850408 (2018)
M. Zhang, C. Deng, Orientation and electrode configuration dependence on ferroelectric, dielectric properties of BaTiO3 thin films, Ceram. Int. https://doi.org/10.1016/j.ceramint.2019.07.309
D. Fu, K. Suzuki, K. Kato, Frequency dependence of polarization hysteresis loop in CaBi4Ti4O14 ferroelectric thin films. Integr. Ferroelectr. 61(1), 19–23 (2004)
G.W. Pabst, L.W. Martin, Y.-H. Chu, R. Ramesh, Leakage mechanisms in \(\text{ BiFeO }_3\) thin films. Appl. Phys. Lett. 90(7), 072902 (2007)
H.L. Skriver, N. Rosengaard, Surface energy and work function of elemental metals. Phys. Rev. B 46(11), 7157 (1992)
W. Sun, Z. Zhou, J. Luo, K. Wang, J.-F. Li, Leakage current characteristics and sm/ti doping effect in BiFeO3 thin films on silicon wafers. J. Appl. Phys. 121(6), 064101 (2017)
A. James, A. Kumar, V .B. Prasad, S. Kamat, V. Singh, P. Ghoshal, A. Pandey, Tunability, ferroelectric and leakage studies on pulsed laser ablated (Pb0.92La0.08)(Zr0.60Ti0.40)O3 thin films. Mater. Chem. Phys. 211, 295–301 (2018)
X. Jing, W. Xu, C. Yang, Tuning electrical conductivity, charge transport, and ferroelectricity in epitaxial BaTiO3 films by Nb-doping. Appl. Phys. Lett. 110(18), 182903 (2017)
R. Pan, T. Zhang, J. Wang, Z. Ma, J. Wang, D. Wang, Rectifying behavior and transport mechanisms of currents in Pt/BaTiO3/Nb: SrTiO3 structure. J. Alloys Compd. 519, 140–143 (2012)
F. Liu, I. Fina, D. Gutiérrez, G. Radaelli, R. Bertacco, J. Fontcuberta, Selecting steady and transient photocurrent response in BaTiO3 films. Adv. Electron. Mater. 1(9), 1500171 (2015)
Y. Liu, J. Guo, E. Zhu, L. Liao, S.-J. Lee, M. Ding, I. Shakir, V. Gambin, Y. Huang, X. Duan, Approaching the Schottky–Mott limit in van der waals metal–semiconductor junctions. Nature 557(7707), 696 (2018)
E. Arveux, Surface and interface properties of BaTiO3 ferroelectric thin films studied by in-situ photoemission spectroscopy, Ph.D. thesis (2009)
J. Goniakowski, F. Finocchi, C. Noguera, Polarity of oxide surfaces and nanostructures. Rep. Progress Phys. 71(1), 016501 (2007)
Y. Sun, X. Shen, J. Wang, Zhao, Thermal annealing behaviour of Ni/Au on N-GaN Schottky contacts. J. Phys. D 35(20), 2648 (2002)
F. Chen, A. Klein, Polarization dependence of Schottky barrier heights at interfaces of ferroelectrics determined by photoelectron spectroscopy. Phys. Rev. B 86(9), 094105 (2012)
Z. Xi, J. Ruan, C. Li, C. Zheng, Z. Wen, J. Dai, A. Li, D. Wu, Giant tunnelling electroresistance in metal/ferroelectric/semiconductor tunnel junctions by engineering the Schottky barrier. Nat. Commun. 8, 15217 (2017)
V. Aubry, F. Meyer, Schottky diodes with high series resistance: limitations of forward i–v methods. J. Appl. Phys. 76(12), 7973–7984 (1994)
N. F. Mott, R. W. Gurney, Electronic Processes in Ionic Crystals (Oxford University Press, New York, 1940)
M. A. Lampert, P. Mark, Current injection in solids. Semicond. Semimet. 6, 1–96 (1970)
S.M. Sze, K.K. Ng, Physics of semiconductor devices (Wiley, New York, 2006)
P. Singh, P. Rout, M. Singh, R. Rakshit, A. Dogra, Thickness dependent charge transport in ferroelectric BaTiO3 heterojunctions. J. Appl. Phys. 118(11), 114103 (2015)
M. Mayimele, J.P.J. van Rensburg, F. Auret, M. Diale, Analysis of temperature-dependant current-voltage characteristics and extraction of series resistance in pd/zno Schottky barrier diodes. Physica B: Condensed Matter 480, 58–62 (2016)
D. Korucu, T. Mammadov, Temperature-dependent current-conduction mechanisms in au/n-inp Schottky barrier diodes (sbds). Journal of Optoelectronics and Advanced Materials 14(1), 41 (2012)
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Generous financial support from National Natural Science Foundation of China (Grant Nos. 51462003, 51762010) and the Science Research Plan Funds of Guizhou province of China (Qian Ke He Ren Cai [2015]4006) are gratefully acknowledged.
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Zhang, M., Deng, C. Enhanced ferroelectric properties of \(\hbox {BaTiO}_3\) films via rapid thermal processing. J Mater Sci: Mater Electron 31, 3130–3136 (2020). https://doi.org/10.1007/s10854-020-02859-0
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DOI: https://doi.org/10.1007/s10854-020-02859-0