Abstract
The Co1−xNixFe2O4 (x = 0.2, 0.5, 0.8) spinel ferrites were synthesised by sol–gel auto combustion method. The Co1−xNixFe2O4/RGO composites were prepared by in situ chemical reduction method and XRD, FTIR, Raman spectroscopy, SEM, VSM and VNA were investigated for crystalline structure and electromagnetic properties. The crystallite size decreases with addition of RGO in ferrites. Magnetization saturation, coercivity and remnant magnetisation decreases with increase of Ni content in the composite with lowest remnant of 9.41 emu/g for 80% of Ni in Co1−xNixFe2O4/RGO showing ferromagnetic nature. The complex permittivity and complex permeability of the composites were measured at X-band frequency which shows significant change with addition of RGO. The maximum reflection loss of − 19.56 dB at 10.04 GHz with bandwidth (RL < 10 dB) 2.49 GHz was obtained for Co0.2Ni0.8Fe2O4/RGO composite with the thickness of 2 mm. The investigations present easy composite preparation of spinel ferrites with graphene oxide and comparison of electromagnetic studies imply the use of Co0.2Ni0.8Fe2O4/RGO composite as microwave absorber in shielding and communications.
Similar content being viewed by others
References
Y. Li, D. Li, J. Yang, H. Luo, F. Chen, X. Wang, R. Gong, Enhanced microwave absorption and surface wave attenuation properties of Co0.5Ni0.5Fe2O4 fibers/reduced graphene oxide composites. Materials 11(4), 508 (2018)
Y. Zhang, X. Wang, M. Cao, Confinedly implanted NiFe2 O 4-rGO: cluster tailoring and highly tunable electromagnetic properties for selective-frequency microwave absorption. Nano Res. 11(3), 1426–1436 (2018)
Y. Ding, Q.L. Liao, S. Liu, H.J. Guo, Y.H. Sun, G.J. Zhang, Y. Zhang, Reduced graphene oxide functionalized with cobalt ferrite nanocomposites for enhanced efficient and lightweight electromagnetic wave absorption. Sci. Rep. 6, 32381 (2016)
P. Liu, Z. Yao, J. Zhou, Z. Yang, L.B. Kong, Small magnetic Co-doped NiZn ferrite/graphene nanocomposites and their dual-region microwave absorption performance. J. Mater. Chem. C 4, 9738–9749 (2016)
J. Feng, F.Z. Pu, Z.X. Li, X.H. Li, X.Y. Hu, J.T. Bai, Interfacial interactions and synergistic effect of CoNi nanocrystals and nitrogen-doped graphene in a composite microwave absorber. Carbon 104, 214–225 (2016)
T. Wu, Y. Liu, X. Zeng, T.T. Cui, Y.T. Zhao, Y.N. Li, G.X. Tong, Facile hydrothermal synthesis of Fe3O4/C core-shell nanorings for efficient low-frequency microwave absorption. ACS Appl. Mater. Interface 8, 7370–7380 (2016)
M. Jafarian, S.S.S. Afghahi, Y. Atassi, M. Salehi, Insights on the design of a novel multicomponent microwave absorber based on SrFe10Al2O19 and Ni0.5Zn0.5Fe2O4/MWCNTs/polypyrrole. J. Magn. Magn. Mater. 471, 30–38 (2019)
A.L. Lopes-Moriyama, V. Madigou, C.P. deSouza, C. Leroux, Controlled synthesis of CoFe2O4 nanooctahedra. Powder Technol. 256, 482–489 (2014)
D. Moitra, S. Hazra, B.K. Ghosh, R.K. Jani, M.K. Patra, S.R. Vadera, N.N. Ghosh, A facile low temperature method for the synthesis of CoFe2O4 nanoparticles possessing excellent microwave absorption properties. RSC Adv. 5, 51130–51134 (2015)
H. Hosseini, H. Mahdavi, Nanocomposite based on epoxy and MWCNTs modified with NiFe2O4 nanoparticles as efficient microwave absorbing material. Appl. Organomet. Chem. 32, e4294 (2018)
M. Zong, Y. Huang, H. Wu, Y. Zhao, Q. Wang, X. Sun, One-pot hydrothermal synthesis of RGO/CoFe2O4 composite and its excellent microwave absorption properties. Mater. Lett. 114, 52–55 (2014)
X. Sun, J. He, G. Li, J. Tang, T. Wang, Y. Guo, H. Xue, Laminated magnetic graphene with enhanced electromagnetic wave absorption properties. J. Mater. Chem. C 1(4), 765–777 (2013)
P. Yin, Y. Deng, L. Zhang, W. Wu, J. Wang, X. Feng et al., One-step hydrothermal synthesis and enhanced microwave absorption properties of Ni0.5Co0.5Fe2O4/graphene composites in low frequency band. Ceram. Int. 44(17), 20896–20905 (2018)
M. Zong, Y. Huang, Y. Zhao, X. Sun, C. Qu, D. Luo, J. Zheng, Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO–Fe3O4 composites. RSC Adv. 3(45), 23638–23648 (2013)
M.A. Dar, H.A. Dar, D. Varshney, Influence of Sm doping on structural and dielectric properties of Y1-xSmxMnO3 (x = 0, 0.10, 0.20) manganites, in AIP Conference Proceedings, vol. 1728(1) (AIP Publishing, 2016), p. 020234
J. Ou, J. Wang, S. Liu, B. Mu, J. Ren, H. Wang, S. Yang, Tribology study of reduced graphene oxide sheets on silicon substrate synthesized via covalent assembly. Langmuir 26(20), 15830–15836 (2010)
R. Malekfar, M. Parishani, A. Cheraghi, Spectroscopy, Structural, and Optical Investigations of NiFe2O4 Ferrite. Int. J. Opt. Photonics 9(2), 73–78 (2015)
V.C. Tung, M.J. Allen, Y. Yang, R.B. Kaner, High-throughput solution processing of large-scale graphene. Nat. Nanotechnol. 4(1), 25 (2009)
L.V. Gasparov, D.B. Tanner, D.B. Romero, H. Berger, G. Margaritondo, Phys. Rev. B. 62, 7939 (2000)
Y. Lin, J. Wang, H. Yang, L. Wang, M. Cao, Increased capacitance of porous Co0.5Ni0.5Fe2O4 for supercapacitor application. Mater. Sci. Eng. B 228, 103–108 (2018)
K.V. Sankar, R.K. Selvan, Fabrication of flexible fiber supercapacitor using covalently grafted CoFe2O4/reduced graphene oxide/polyaniline and its electrochemical performances. Electrochimica Acta 213, 469–481 (2016)
Y. Liu, Z. Chen, Y. Zhang, R. Feng, X. Chen, C. Xiong, L. Dong, Broadband and lightweight microwave absorber constructed by in situ growth of hierarchical CoFe2O4/reduced graphene oxide porous nanocomposites. ACS Appl. Mater. Interfaces 10(16), 13860–13868 (2018)
C. Wang, X. Han, P. Xu, X. Zhang, Y. Du, S. Hu, X. Wang, The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material. Appl. Phys. Lett. 98, 072906 (2011)
J. Zou, R. Gao, C. Fu, W. Cai, G. Chen, X. Deng, Influence of Co ion doping on the microstructure, magnetic and dielectric properties of Ni1-xCoxFe2O4 ceramics. Process. Appl. Ceram. 12(4), 335–341 (2018)
K. Maaz, S. Karim, A. Mashiatullah, J. Liu, M.D. Hou, Structural analysis of nickel doped cobalt ferrite nanoparticles prepared by coprecipitation route. Physica B 404, 3947–3951 (2009)
W. Wang, C. Zang, Q. Jiao, Synthesis, structure and electromagnetic properties of Mn–Zn ferrite by sol–gel combustion technique. J. Magn. Magn. Mater. 349, 116–120 (2014)
X. Ren, G. Xu, Electromagnetic and microwave absorbing properties of NiCoZn-ferrites doped with La3+. J. Magn. Magn. Mater. 354, 44–48 (2014)
R. Che, L.M. Peng, X.F. Duan, Q. Chen, X.L. Liang, Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes. Adv. Mater. 16, 401–405 (2004)
X. Su, J. Wang, B. Zhang, W. Chen, Q. Wu, W. Dai, Y. Zou, Enhanced microwave absorption properties of epoxy composites containing graphite nanosheets@ Fe3O4 decorated comb-like MnO2 nanoparticles. Mater. Res. Express 5(5), 056305 (2018)
X. Su, J. Wang, X. Zhang, B. Zhang, Q. Wu, W. Dai et al., Synthesis of core–shell Fe3O4@ ppy/graphite nanosheets composites with enhanced microwave absorption performance. Mater. Lett. 239, 136–139 (2019)
B. Zhang, J. Wang, T. Wang, X. Su, S. Yang, W. Chen et al., High-performance microwave absorption epoxy composites filled with hollow nickel nanoparticles modified graphene via chemical etching method. Compos. Sci. Technol. 176, 54–63 (2019)
Acknowledgements
The authors are thankful to Director, National Institute of Technology, Kurukshetra, for providing the characterization facilities and Director, DMSRDE, Kanpur for providing VNA facility.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Das, A., Negi, P., Joshi, S.K. et al. Enhanced microwave absorption properties of Co and Ni co-doped iron (II,III)/reduced graphene oxide composites at X-band frequency. J Mater Sci: Mater Electron 30, 19325–19334 (2019). https://doi.org/10.1007/s10854-019-02293-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-02293-x