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Effect of K:Ba ratio on energy storage properties of strontium barium potassium niobate-glass ceramics

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Abstract

We prepared 15.16SrO–(16.84 − x)BaO–xK2O–32Nb2O5–28B2O3–8P2O5 glass ceramic composites with different K:Ba ratios through melt-casting followed by controlled crystallization. Although the dielectric constant of these samples decreased with an increase in x, a maximum theoretical energy density of 12.83 J/cm3 was obtained at x = 10.104. High breakdown strength (1844 kV/cm) and low dielectric loss (< 0.3%) might be the cause of high energy storage density at x = 10.104.

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References

  1. C. Aditya, P. Satyanarayan, V. Rahul et al., Anti-ferroelectric ceramics for high energy density capacitors. Materials 8, 8009–8031 (2015)

    Article  Google Scholar 

  2. Y. Xu, H. Guo, X. Liu et al., Effect of Ba content on the stress sensitivity of the antiferroelectric to ferroelectric phase transition in (Pb, La, Ba,)(Zr, Sn, Ti)O3 ceramics. J. Am. Ceram. Soc. 97, 206–212 (2014)

    Article  CAS  Google Scholar 

  3. J. Ding, Y. Liu, Y. Lu et al., Enhanced energy-storage properties of 0.89Bi0.5Na0.5TiO3-0.06BaTiO3-0.05K0.5Na0.5NbO3 lead-free anti-ferroelectric ceramics by two-step sintering method. Mater. Lett. 114, 107–110 (2014)

    Article  CAS  Google Scholar 

  4. S. Jiang, L. Zhang, G. Zhang et al., Effect of Zr:Sn ratio in the lead lanthanum zirconate stannate titanate anti-ferroelectric ceramics on energy storage properties. Ceram. Int. 39, 5571–5575 (2013)

    Article  CAS  Google Scholar 

  5. Y.F. Wang, Z.L. Lv, H. Xie et al., High energy-storage properties of [(Bi1/2Na1/2)0.94 Ba0.06]La(1−x)ZrxTiO3 lead-free anti-ferroelectric ceramics. Ceram. Int. 40, 4323–4326 (2014)

    Article  CAS  Google Scholar 

  6. V.S. Puli, D.K. Pradhan, A. Kumar et al., Structure and dielectric properties of BaO-B2O3-ZnO-[BaZr0.2Ti0.80O3]0.85-[Ba0.70Ca0.30TiO3]0.15 glass-ceramis for energy storage. J. Mater. Sci. 23, 2005–2009 (2012)

    CAS  Google Scholar 

  7. J. Song, G.H. Chen, C.L. Yuan et al., Effect of the Sr/Ba ratio on the microstructures and dielectric properties of SrO-BaO-Nb2O5-B2O3 glass-ceramics. Mater. Lett. 117, 7–9 (2014)

    Article  CAS  Google Scholar 

  8. T.Y. Liu, G.H. Chen, J. Song et al., Crystallization kinetics and dielectric characterization of CeO2-added BaO-SrO-Nb2O5-B2O3-SiO2 glass-ceramics. Ceram. Int. 39, 5553–5559 (2013)

    Article  CAS  Google Scholar 

  9. H.Y. Wang, J.H. Liu, J.W. Zhai et al., Effects of Sr substitution for Ba on dielectric and energy-storage density of SrO-BaO-K2O-Nb2O5-SiO2 glass-ceramics. J. Eur. Ceram. Soc. 37, 3917–3925 (2017)

    Article  CAS  Google Scholar 

  10. S.X. Xue, J.W. Wang, S.H. Liu et al., Effect of the Ba/Na ratio on the microstructure and dielectric properties of (BaO, Na2O)-Nb2O5-SiO2 glass-ceramics. Ceram. Int. 40, 7495–7499 (2014)

    Article  CAS  Google Scholar 

  11. S.X. Xue, J.W. Zhai, S. Xiao et al., Improved dielectric breakdown strength and suppressed energy loss in niobate glass-ceramics crystallized by microwave process. Mater. Lett. 190, 154–156 (2017)

    Article  CAS  Google Scholar 

  12. H.T. Wang, J.H. Liu, J.W. Zhai et al., Effect of K2O content on breakdown strength and energy-storage density in K2O-BaONb2O5-SiO2 glass-ceramics. Ceram. Int. 43, 4183–4187 (2017)

    Article  CAS  Google Scholar 

  13. H.T. Wang, J.H. Liu, J.W. Zhai et al., Effect of crystallization temperature on dielectric and energy-storage properties in SrO-Na2O-Nb2O5-SiO2 glass-ceramics. Ceram. Int. 43, 8898–8904 (2017)

    Article  CAS  Google Scholar 

  14. H.T. Wang, J.H. Liu, J.W. Zhai et al., Enhanced energy storage density and discharge efficiency in the strontium sodium niobate-based glass-ceramics. J. Alloys Compd. 687, 280–285 (2016)

    Article  CAS  Google Scholar 

  15. J. Chen, Y. Zhang, C. Deng et al., Effect of the Ba/Ti ratio on the microstructures and dielectric properties of barium titanate-based glass-ceramics. J. Am. Ceram. Soc. 92, 1350–1353 (2009)

    Article  CAS  Google Scholar 

  16. G.H. Chen, W.J. Zhang, Effects of heat treatment condition on properties of strontium barium niobate based glass-ceramic for energy storage capacitors. Adv. Mater. Res. 311–313, 2071–2074 (2011)

    Article  Google Scholar 

  17. J. Chen, Y. Zhang, C. Deng et al., Crystallization kinetics and dielectric properties of barium strontium titanate based glass–ceramics. Mater. Chem. Phys. 121, 109–113 (2010)

    Article  CAS  Google Scholar 

  18. G.H. Chen, J. Zheng, C.L. Yuan et al., Enhanced energy storage properties of P2O5 modified niobate-based B2O3 system glass ceramic composites. Mater. Lett. 176, 46–48 (2016)

    Article  CAS  Google Scholar 

  19. S. Xiu, S. Xiao, S. Xue et al., Crystallization kinetics behaviour and dielectric properties of strontium barium niobate-based glass–ceramics. J. Mater. Sci. 27, 5324–5330 (2016)

    CAS  Google Scholar 

  20. B. Li, D.Z. Wang, G.H. Chen et al., Effect of Yb2O3 content on dielectric and energy-storage properties of lead-free niobate glass-ceramics. J. Mater. Sci 29, 19238–19244 (2018)

    CAS  Google Scholar 

  21. X. Su, B. Riggs, M. Tomozawa et al., Preparation of BaTiO3/low melting glass core-shell nanoparticles for energy storage capacitor applications. J. Mater. Chem. A 2, 18087–18096 (2014)

    Article  CAS  Google Scholar 

  22. X.R. Wang, Y. Zhang, X.Z. Song et al., Glass additive in barium titanate ceramics and its influence on electrical breakdown strength in relation with energy storage properties. J. Eur. Ceram. Soc. 32, 559–567 (2012)

    Article  CAS  Google Scholar 

  23. Y. Yang, J. Song, G.H. Chen et al., Effect of crystallization temperature on the dielectric property and energy density of SrO-BaO-Nb2O6-B2O3 glass-ceramics. J. Non-Cryst. Solids 410, 96–99 (2015)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Financial supports of Guangxi Key Laboratory of Information Materials (Grants No. 171002-Z) are gratefully acknowledged by the authors.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Central South University, Changsha, 410083, China

    Bo Li, Dezhi Wang & Xiao Liu

  2. School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin, 541004, China

    Guohua Chen, Xiao Liu & Changlai Yuan

  3. Key Laboratory of Ministry of Education for Non-ferrous Materials Science and Engineering, Changsha, 410083, China

    Dezhi Wang

  4. Guilin Electrical Equipment Scientific Research Institute, Guilin, 541004, People’s Republic of China

    Bo Li

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  1. Bo Li
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  2. Dezhi Wang
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  3. Guohua Chen
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  4. Xiao Liu
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  5. Changlai Yuan
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Correspondence to Dezhi Wang or Guohua Chen.

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Li, B., Wang, D., Chen, G. et al. Effect of K:Ba ratio on energy storage properties of strontium barium potassium niobate-glass ceramics. J Mater Sci: Mater Electron 30, 19262–19269 (2019). https://doi.org/10.1007/s10854-019-02285-x

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  • DOI: https://doi.org/10.1007/s10854-019-02285-x

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