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Hydrothermal synthesis of La0.7Sr0.3MnO3 and its application in visible light photocatalytic activity

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Abstract

La0.7Sr0.3MnO3 (LSMO) manganite has been synthesized by hydrothermal method. Nano-sized sample LSMO with rod-like morphologies was obtained. The structural, optical and photocatalytic properties were systematically investigated. The structural study confirmed that the as-synthesized sample is crystallized in rhombohedral structure with R-3c space group. In addition, the composition of the sample is similar to the stoichiometric ratios of LSMO. Band gap energy of 2 eV has been depicted by the optical study, which is an important factor for introducing this sample as a promising candidate in visible light photocatalytic activities. This process has been tested by the decolorization of Reactive Black 5 solution (10 ppm) for the sample (0.5 g/L) that confirms the considerable photocatalytic activity of the sample. Finally, this sample has been used for six different runs, based on which the reusability of this sample is confirmed.

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References

  1. E. Dagotto, T. Hotta, A. Moreno, Colossal magnetoresistant materials: the key role of phase separation. Phys. Rep. 344, 1–153 (2001)

    Article  CAS  Google Scholar 

  2. P. Schlottmann, Spin, charge, orbital and lattice degrees of freedom in quasi-cubic manganites: a brief review. Phys. B 404, 2699–2704 (2009)

    Article  CAS  Google Scholar 

  3. M. Ehsani, P. Kameli, F. Razavi, M. Ghazi, B. Aslibeiki, Influence of Sm-doping on the structural, magnetic, and electrical properties of La0.8−xSmxSr0.2MnO3 (0<x<0.45) manganites. J. Alloys Compd. 579, 406–414 (2013)

    Article  CAS  Google Scholar 

  4. M. Ehsani, P. Kameli, M. Ghazi, F. Razavi, M. Taheri, Tunable magnetic and magnetocaloric properties of La0.6Sr0.4MnO3 nanoparticles. J. Appl. Phys. 114, 223907 (2013)

    Article  CAS  Google Scholar 

  5. M. Ehsani, T. Raoufi, F. Razavi, Impact of Gd ion substitution on the magneto-caloric effect of La0.6-xGdxSr0.4MnO3 (x=0, 0.0125, 0.05, 0.10) manganites. J. Magn. Magn. Mater. 475, 484–492 (2019)

    Article  CAS  Google Scholar 

  6. Y.E. Samoshkina, I. Edelman, M. Rautskii, M. Molokeev, Correlation between magneto-optical and transport properties of Sr-doped manganite films. J. Alloys Compd. 782, 334–342 (2019)

    Article  CAS  Google Scholar 

  7. A. Das, S. De, S. Bandyopadhyay, S. Chatterjee, D. Das, Modified dielectric and magnetic properties of Fe and Co-substituted TbMnO3 nanoparticles. J. Alloys Compd. 778, 839–847 (2019)

    Article  CAS  Google Scholar 

  8. A.C.M. Loy, A.T. Quitain, M.K. Lam, S. Yusup, M. Sasaki, T. Kida, Development of high microwave-absorptive bifunctional graphene oxide-based catalyst for biodiesel production. Energy Convers. Manag. 180, 1013–1025 (2019)

    Article  CAS  Google Scholar 

  9. X. Lang, X. Sun, Z. Liu, H. Nan, C. Li, X. Hu, H. Tian, Ag nanoparticles decorated perovskite La0.85Sr0.15MnO3 as electrode materials for supercapacitors. Mater. Lett. 243, 34–37 (2019)

    Article  CAS  Google Scholar 

  10. F.R. Afje, M. Ehsani, Size-dependent photocatalytic activity of La0.8Sr0.2MnO3 nanoparticles prepared by hydrothermal synthesis. Mater. Res. Express. 5, 045012 (2018)

    Article  CAS  Google Scholar 

  11. R.D. Kumar, R. Thangappan, R. Jayavel, Enhanced visible light photocatalytic activity of LaMnO3 nanostructures for water purification. Res. Chem. Intermed. 44, 4323–4337 (2018)

    Article  CAS  Google Scholar 

  12. P.F. Smith, B.J. Deibert, S. Kaushik, G. Gardner, S. Hwang, H. Wang, J.F. Al-Sharab, E. Garfunkel, L. Fabris, J. Li, Coordination geometry and oxidation state requirements of corner-sharing MnO6 octahedra for water oxidation catalysis: an investigation of manganite (γ-MnOOH). ACS Catal. 6, 2089–2099 (2016)

    Article  CAS  Google Scholar 

  13. S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, Green synthesis and characterization of NaEuTi2O6 nanoparticles and its photocatalyst application. J. Mater. Sci.: Mater. Electron. 28, 4345–4350 (2017)

    CAS  Google Scholar 

  14. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, Precipitation synthesis, characterization, morphological control, and photocatalyst application of ZnWO4 nanoparticles. J. Electron. Mater. 7, 3612–3620 (2016)

    Article  CAS  Google Scholar 

  15. J. Das, E.R. Rene, J. Krishnan, Photocatalytic degradation of volatile pollutants. J. Environ. Chem. Toxicol. 2, 57–59 (2018)

    Google Scholar 

  16. P. Luca, M. Pasqualino, L. Stefano, Photoluminescence mechanisms in anatase and rutile TiO2. J. Phys. Chem. C 121, 9011–9021 (2017)

    Article  CAS  Google Scholar 

  17. D. Guerrero-Araque, P. Acevedo-Peña, D. Ramírez-Ortega, L. Lartundo-Rojas, R. Gómez, SnO2–TiO2 structures and the effect of CuO, CoO metal oxide on photocatalytic hydrogen production. J. Chem. Technol. Biotechnol. 92, 1531–1539 (2017)

    Article  CAS  Google Scholar 

  18. S.M. Wu, X.L. Liu, X.L. Lian, G. Tian, C. Janiak, Y.X. Zhang, Y. Lu, H.Z. Yu, J. Hu, H. Wei, Homojunction of oxygen and titanium vacancies and its interfacial n–p effect. Adv. Mater. 30, 1802173 (2018)

    Article  CAS  Google Scholar 

  19. B. Rusinque, Hydrogen Production by Photocatalytic Water Splitting Under Near-UV and Visible Light Using Doped Pt and Pd TiO 2. Electronic Thesis and Dissertation Repository, 5662 (2018)

  20. H. Palneedi, J.H. Park, D. Maurya, M. Peddigari, G.T. Hwang, V. Annapureddy, J.W. Kim, J.J. Choi, B.D. Hahn, S. Priya, Laser irradiation of metal oxide films and nanostructures: applications and advances. Adv. Mater. 30, 1705148–1705186 (2018)

    Article  CAS  Google Scholar 

  21. M. Ghiyasiyan-Arani, M. Masjedi-Arani, Size controllable synthesis of cobalt vanadate nanostructures with enhanced photocatalytic activity for the degradation of organic dyes. J. Mol. Catal. A 425, 31–42 (2016)

    Article  CAS  Google Scholar 

  22. X. Chen, Z. Wu, D. Liu, Z. Gao, Preparation of ZnO photocatalyst for the efficient and rapid photocatalytic degradation of azo dyes. Nanoscale Res. Lett. 12, 143–152 (2017)

    Article  CAS  Google Scholar 

  23. W.C. Huang, L.M. Lyu, Y.C. Yang, M.H. Huang, Synthesis of Cu2O nanocrystals from cubic to rhombic dodecahedral structures and their comparative photocatalytic activity. J. Am. Chem. Soc. 134, 1261–1267 (2011)

    Article  CAS  Google Scholar 

  24. T. Kanagaraj, S. Thiripuranthagan, Photocatalytic activities of novel SrTiO3–BiOBr heterojunction catalysts towards the degradation of reactive dyes. Appl. Catal. B 207, 218–232 (2017)

    Article  CAS  Google Scholar 

  25. A. Sobhani-Nasab, M. Maddahfar, S.M. Hosseinpour-Mashkani, Ce(MoO4)2 nanostructures: synthesis, characterization, and its photocatalyst application through the ultrasonic method. J. Mol. Liq. 216, 1–5 (2016)

    Article  CAS  Google Scholar 

  26. A. Arabi, M. Fazli, M.H. Ehsani, Tuning the morphology and photocatalytic activity of La0.7Ca0.3MnO3 nanorods via different mineralizer-assisted hydrothermal syntheses. Mater. Res. Bull. 90, 205–211 (2017)

    Article  CAS  Google Scholar 

  27. A. Arabi, M. Fazli, M.H. Ehsani, Synthesis and characterization of calcium-doped lanthanum manganite nanowires as a photocatalyst for degradation of methylene blue solution under visible light irradiation. Bull. Mater. Sci. 41, 77 (2018)

    Article  CAS  Google Scholar 

  28. M. Ehsani, T. Raoufi, A. Javadiyan, Critical behavior and size dependence of magnetic entropy changes on La0.6Sr0.4MnO3 manganite. J. Supercond. Nov. Magn. 31, 3723–3732 (2018)

    Article  CAS  Google Scholar 

  29. M. Zarifi, P. Kameli, M. Ehsani, H. Ahmadvand, H. Salamati, Effects of rare earth ions substitution on the magnetocaloric and critical behavior of La0.6A0.2Sr0.2MnO3 (A=Pr, Nd, Ce) manganite. J. Alloys Compd. 718, 443–452 (2017)

    Article  CAS  Google Scholar 

  30. T. Balakrishnan, N.S. Subramanian, A. Kathalingam, Studies on rheological, structural, optical, electrical and surface properties of LiMn2O4 thin films by varied spin rates. Mater. Sci. Poland 35, 626–631 (2017)

    Article  CAS  Google Scholar 

  31. S. Priyatharshni, M. Divagar, C. Viswanathan, D. Mangalaraj, N. Ponpandian, Electrochemical simultaneous detection of dopamine, ascorbic acid and uric acid using LaMnO3 nanostructures. J. Electrochem. Soc. 163, B460–B465 (2016)

    Article  CAS  Google Scholar 

  32. A. Rostamnejadi, P. Kameli, Particle size effect on magnetic properties of interacting La0.67Sr0.33MnO3 nanoparticles. arXiv preprint http://arxiv.org/abs/0907.2815. (2009)

  33. K. Li, R. Cheng, S. Wang, Y. Zhang, Infrared transmittance spectra of the granular perovskite. J. Phys.: Condens. Matter 10, 4315–4322 (1998)

    CAS  Google Scholar 

  34. S. Ravi, A. Karthikeyan, Effect of calcination temperature on La0.7Sr0.3MnO3 nanoparticles synthesized with modified sol-gel route. Phys. Procedia 54, 45–54 (2014)

    Article  CAS  Google Scholar 

  35. M. Rahimkhani, D.S. Khoshnoud, M. Ehsani, Origin of enhanced multiferroic properties in Bi0.85−xLa0.15HoxFeO3 nanopowders. J. Magn. Magn. Mater. 449, 538–544 (2018)

    Article  CAS  Google Scholar 

  36. N.D. Thorat, K.P. Shinde, S.H. Pawar, K.C. Barick, C.A. Betty, R.S. Ningthoujam, Polyvinyl alchohol: an efficient fuel for synthesis of superparamagnetic LSMO nanoparticles for biomedical application. RSC Adv. 41, 3060–3071 (2012)

    CAS  Google Scholar 

  37. H. Liu, J. Zhou, L. Zhang, Z. Hu, C. Kuo, J. Li, Y. Wang, L.H. Tjeng, T.-W. Pi, A. Tanaka, Insight into the role of metal-oxygen bond and O2p hole in high-voltage cathode LiNixMn2–xO4. J. Phys. Chem. C 121, 16079–16087 (2017)

    Article  CAS  Google Scholar 

  38. M. Cesaria, A. Caricato, G. Leggieri, M. Martino, G. Maruccio, Optical response of oxygen deficient La0 7Sr0 3MnO3 thin films deposited by pulsed laser deposition. Thin Solid Films 545, 592–600 (2013)

    Article  CAS  Google Scholar 

  39. S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, M. Mehrzad, Controlling the synthesis SrMoO4 nanostructures and investigation its photocatalyst application. J. Mater. Sci.: Mater. Electron. 27, 5758–5763 (2016)

    CAS  Google Scholar 

  40. L.C. Ferreira, M.S. Lucas, J.R. Fernandes, P.B. Tavares, Photocatalytic oxidation of Reactive Black 5 with UV-A LEDs. J. Environ. Chem. Eng. 4, 109–114 (2016)

    Article  CAS  Google Scholar 

  41. M.Y. Nassar, S. Abdallah, Facile controllable hydrothermal route for a porous CoMn2O4 nanostructure: synthesis, characterization, and textile dye removal from aqueous media. RSC Adv. 6, 84050–84067 (2016)

    Article  CAS  Google Scholar 

  42. Y. Ding, P. Zhou, H. Tang, Visible-light photocatalytic degradation of bisphenol A on NaBiO3 nanosheets in a wide pH range: a synergistic effect between photocatalytic oxidation and chemical oxidation. Chem. Eng. J. 291, 149–160 (2016)

    Article  CAS  Google Scholar 

  43. I. Kazeminezhad, A. Sadollahkhani, Influence of pH on the photocatalytic activity of ZnO nanoparticles. J. Mater. Sci.: Mater. Electron. 27, 4206–4215 (2016)

    CAS  Google Scholar 

  44. M. Mansournia, S. Rafizadeh, S.M. Hosseinpour-Mashkani, An ammonia vapor-based approach to ZnO nanostructures and their study as photocatalyst material. Ceram. Int. 42, 907–916 (2016)

    Article  CAS  Google Scholar 

  45. J. Cunningham, G. Al-Sayyed, S. Srijaranai, Adsorption of model pollutants onto TiO 2 particles in relation to phytoremediation of contaminated water, in Aquatic and surface photochemistry (CRC Press, Boca Raton, 2018), pp. 317–348

    Google Scholar 

  46. F.C.F. Low, T.Y. Wu, C.Y. Teh, J.C. Juan, N. Balasubramanian, Investigation into photocatalytic decolorisation of CI Reactive Black 5 using titanium dioxide nanopowder. Color. Technol. 128, 44–50 (2012)

    Article  CAS  Google Scholar 

  47. W.-D. Oh, L.-W. Lok, A. Veksha, A. Giannis, T.-T. Lim, Enhanced photocatalytic degradation of bisphenol A with Ag-decorated S-doped g-C3N4 under solar irradiation: performance and mechanistic studies. Chem. Eng. J. 333, 739–749 (2018)

    Article  CAS  Google Scholar 

  48. L. Aoudjit, P.M. Martins, F. Madjene, D. Petrovykh, S. Lancers-Mendez, Photocatalytic reusable membranes for the effective degradation of tartrazine with a solar photoreactor. J. Hazard. Mater. 344, 408–416 (2018)

    Article  CAS  Google Scholar 

  49. L. Yosefi, M. Haghighi, Fabrication of nanostructured flowerlike p-BiOI/p-NiO heterostructure and its efficient photocatalytic performance in water treatment under visible-light irradiation. Appl. Catal. B 220, 367–378 (2018)

    Article  CAS  Google Scholar 

  50. S. Wang, B. Yang, Y. Liu, Synthesis of a hierarchical SnS2 nanostructure for efficient adsorption of Rhodamine B dye. J. Colloid Interface Sci. 507, 225–233 (2017)

    Article  CAS  Google Scholar 

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Arabi, A., Ehsani, M.H. & Fazli, M. Hydrothermal synthesis of La0.7Sr0.3MnO3 and its application in visible light photocatalytic activity. J Mater Sci: Mater Electron 30, 19001–19008 (2019). https://doi.org/10.1007/s10854-019-02257-1

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