Abstract
The composite multiferroic-ceramics of xPbFe12O19 + (1 − x) PbTiO3 being mixed in varying molar percentage has been successfully synthesized by the solid-state sintering method. The phase of PbFe12O19 (PFO) provides a ferromagnetic order while that of PbTiO3 (PTO) provides ferroelectric order, a combination of two orders gives multiferroic function. The presence of ferromagnetic PFO and ferroelectric phase PTO has been confirmed by X-ray diffraction analysis, indicating the formation of composite compounds with limited interface interaction. Microstructure observation shows the distribution of PFO and PTO grains concerning equable composition. The ferroelectric measurements have displayed hysteresis loops for x = 1, 0.6, and 0.4 compositions. Surprisingly the remnant polarization (Pr) and coercive field (Ec) increases with the concentration of PFO component (x value). With the increase of x value in the composite system, the augmentation of typical magnetic hysteresis loops with higher magnetization, and coercive force was observed. The xPFO + (1 − x) PTO composite ceramics shows coexistence of ferroelectricity and ferromagnetism. It demonstrates an important field of research for composite ceramics with multiferroic properties.
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References
D.I. Khomskii, Multiferroics: different ways to combine magnetism and ferroelectricity. J. Magn. Magn. Mater. 306, 1–8 (2006)
W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials. Nature 442, 759–765 (2006)
M. Fiebig, Th Lottermoser, D. Frohlich, A.V. Goltsev, R.V. Pisarev, Observation of coupled magnetic and electric domains. Nature 419, 818–820 (2002)
G. Tan, Y. Huang, H. Sheng, Magnetoelectric response in multiferroic SrFe12O19 ceramics. PLoS ONE 11, 0167084 (2016)
J.Y. Zhai, N. Can, L. Liu, Y.H. Lin, C.W. Nan, Dielectric behavior and magnetoelectric properties of lead zirconatetitanate/Co-ferrite particulate composites. J. Mater. Sci. Eng B 99, 329–331 (2003)
Y.J. Wang, S.W. Or, H.L.W. Chan, X.Y. Zhao, H.S. Luo, Enhanced magnetoelectric effect in longitudinal-transverse mode Terfenol-D/Pb(Mg1/3Nb2/3)O3–PbTiO3 laminate composites with optimal crystal cut. J. Appl. Phys. 103, 124511 (2008)
Y.M. Jia, S.W. Or, H.L.W. Chan, X.Y. Zhao, H.S. Luo, Converse magnetoelectric effect in laminated composites of PMN–PT single crystal and Terfenol-D alloy. J. Appl. Phys. Lett. 88, 242902 (2006)
J. Ryu, A.V. Carazo, K. Uchino, H.-E. Kim, Piezoelectric and magnetoelectric properties of lead zirconatetitanate/Ni-ferrite particulate composites. J. Electroceram. 7, 17–24 (2001)
H.F. Zhang, S.W. Or, H.L.W. Chan, Fine-grained multiferroic BaTiO3/(Ni0.5Zn0.5)Fe2O4 composite ceramics synthesized by novel powder-in-sol precursor hybrid processing route. Mater. Res. Bull. 44, 1339–1346 (2009)
H.F. Zhang, S.W. Or, H.L.W. Chan, Multiferroic properties of ceramic composites of Ni0.5Zn0.5Fe2O4-Pb(Zr0.53Ti0.47)O3 ceramic composites. J. Appl. Phys. 104, 104109 (2008)
L. Yuan, S.W. Or, Enhanced piezoelectric and pyroelectric effects in single-phase multiferroic Bi1-xNdxFeO3 (x = 0–0.15) ceramics. J. Appl. Phys. Lett. 88, 062905 (2006)
L. Mitoseriu, V. Buscaglia, M. Viviani, M.T. Buscaglia, I. Pallecchi, C. Harnagea, A. Testino, V. Trefiletti, P. Nanni, A.S. Siri, BaTiO3-(Ni0.5Zn0.5)Fe2O4 ceramic composites with ferroelectric and magnetic properties. J. Eur. Ceram. Soc. 27, 4379–4382 (2007)
A.R. Iordan, M. Airimioaiei, M.N. Palamaru, C. Galassi, A.V. Sandu, C.E. Ciomaga, F. Prihor, L. Mitoseriu, A. Ianculescu, In situ preparation of CoFe2O4-Pb(ZrTi)O3multiferroic composites by gel-combustion technique. J. Eur. Ceram. Soc. 29, 2807–2813 (2009)
P. Uniyal, K.L. Yadav, Synthesis and study of multiferroic properties of ZnFe2O4-BiFeO3 nanocomposites. J. AlloysCompounds 492, 406–410 (2010)
L. Silvestroni, H.J. Kleebe, H. Kungl, S. Lauterbach, M. Müller, M.J. Hoffmann, Lead ZirconateTitanate-Magnetoplumbite Composites: a first step toward multiferroic ceramics? J. Am. Ceram. Soc. 92, 2362–2367 (2009)
N. Yang, H.B. Yang, J.J. Jia, X.F. Pang, Formation and magnetic properties of nanosized PbFe12O19 particles synthesized by citrate precursor technique. J. Alloys Compounds 438, 263–267 (2007)
S. Díaz-Castañón, J.L. Sánchez LI, E. Estevez-Rams, F. Lecabue, B.E. Watts, Magneto-structural properties of PbFe12O19hexaferrite powders prepared by decomposition of hydroxide-carbonate and metal-organic precipitates. J. Magn. Magn. Mater. 185, 194–198 (1998)
S. Chauduhury, S.K. Rakshit, S.C. Parida, Z. Singh, K.D. Singh Mudher, V. Venugopal, Studies on structural and thermo-chemical behavior of MFe12O19(s) (M = Sr, Ba and Pb) prepared by citrate-nitrate gel combusiton method. J. Alloy Compds. 455, 25–30 (2008)
G.L. Tan, M. Wang, Multiferroic PbFe12O19 ceramics. J. Electroceramics 26, 170–174 (2011)
G.L. Tan, W. Li, Ferroelectricity and Ferromagnetism of M-Type Lead Hexaferrite. J. Am. Ceram. Soc. 98, 1812 (2015)
A. Srinivas, T. Karthik, R. Gopalan, V. Chandrasekaran, Improved magnetoelectricity by uniaxial magnetic field pressed and sintered composites in BaTiO3(x)-BaFe12O19 (1-x) system (x = 0.8,0.6). J. Mater. Sci. Eng. B 172, 289–293 (2010)
D.V. Karpinsky, R.C. Pullar, Y.K. Fetisov, K.E. Kamentsev, A.L. Kholkin, Local probing of magnetoelectric coupling in multiferroic composites of BaFe12O19-BaTiO3. J. Appl. Phys. 108, 042012 (2010)
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The authors acknowledge the financial support from the National Natural Science Foundation of China under contract No. 11774276.
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Mishra, D.D., Tewelde, D.M., Wang, M. et al. Multiferroic properties of PbFe12O19–PbTiO3 composite ceramics. J Mater Sci: Mater Electron 30, 10830–10834 (2019). https://doi.org/10.1007/s10854-019-01426-6
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DOI: https://doi.org/10.1007/s10854-019-01426-6