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Effects of dyes in the growth, optical, mechanical and dielectric properties of KDP crystals

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Abstract

One among the prominent single crystal potassium dihydrogen phosphate (KDP) was grown by slow evaporation solution technique and also doped with three organic dyes like Alizarin, Congo red and Evans blue. The cell parameters of the pure and doped KDP crystals were found using powder x-ray diffraction. The optical behavior of the pure and doped KDP crystals was analyzed through the UV–Visible absorption spectrum. The functional group analysis of the grown crystals was done using FT-IR spectral study. The emission characteristics of the pure and doped KDP were found using photoluminescence study which results in multicolored emission spectra. The second harmonic generation of the pure and doped KDP crystals shows better frequency conversion property of the crystals. The laser damage threshold (LDT) study was done for all the grown crystals and the results were compared. The growth pattern of the pure and dye doped KDP crystals were examined using etching analysis. The mechanical stability of the grown crystals was determined using Vicker’s microhardness study. The dielectric property of pure and dye doped KDP crystals are carried out at room temperature for different frequencies.

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References

  1. I. Pritula, V. Gayvoronsky, Yu. Gromov, M. Kopylovsky, M. Kolybaeva, V. Puzikov, A. Kosinova, Funct. Mater. 15, 561 (2008)

    Google Scholar 

  2. S. Chennakrishnan, S.M. Ravi Kumar, D. Sivavishnu, M. Ganapathi, I.V. Potheher, M. Vimalan, J. Mater. Sci. Mater. Electron. 27, 10113 (2016)

    Article  Google Scholar 

  3. H.V. Alexandru, S. Antothe, J. Cryt. Growth 258, 149 (2003)

    Article  Google Scholar 

  4. V.I. Salo, A.P. Voronov, V.F. Tkachenko, G.N. Babenko, A.V. Makoveev, J. Cryst. Growth 337, 13 (2011)

    Article  Google Scholar 

  5. P. Kumaresan, S. Moorthybabu, P.M. Anbarasan, Mater. Res. Bull. 43, 1716 (2008)

    Article  Google Scholar 

  6. N. Balamurugan, P. Ramasamy, Cryst. Growth Des. 6, 1642 (2006)

    Article  Google Scholar 

  7. Bo Wang, C.S. Fang, S.L. Wang, X. Sun, Q.T. Gu, Y.P. Li, X.G. Xin, J.Q. Zhang, B. Liu, X.M. Miu, J. Cryst. Growth 297, 352 (2006)

    Article  Google Scholar 

  8. B. Kahr, S.H. Jang, J.A. Subramony, M.P. Kellev, L. Bastin, Adv. Mater. 8, 941 (1996)

    Article  Google Scholar 

  9. H.V. Alexandru, S. Antothe, J. Cryst. Growth 258, 149 (2003)

    Article  Google Scholar 

  10. H.V. Alexandru, J. Cryst. Growth 169, 347 (1996)

    Article  Google Scholar 

  11. V.I. Bredikhin, G.L. Galushkina, A.A. Kulagin, S.P. Kuznetsov, O.A. Malshakova, J. Cryst. Growth 259, 309 (2003)

    Article  Google Scholar 

  12. N.A. Booth, A.A. Cherniv, P.G. Vekilow, J. Cryst. Growth 237, 1812 (2002)

    Google Scholar 

  13. J. Anand, S.H. Jang, B. Kahr, Ferroelectrics 191, 293 (1997)

    Article  Google Scholar 

  14. J. A. Subramony, Dissertation, Purdue University, (1999)

  15. N. Zaitseva, L. Carman, I. Smolsky, R. Torres, M. Yan, J. Cryst. Growth 204, 512 (1999)

    Article  Google Scholar 

  16. S. Hirota, H. Miki, K. Fukui, K. Maeda, J. Cryst. Growth 235, 541 (2002)

    Article  Google Scholar 

  17. I. Pritula, V. Gayvoronsky, Y. Gromov, M. Kopylovsky, M. Kolybaeva, V. Puzikov, A. Kosinova, Y. Savvin, Y. Velikhov, A. Levchenko, Opt. Commun. 282, 1141 (2009)

    Article  Google Scholar 

  18. M.L. Dalal, M. Rahman, P.D. Tounsand, Nucl. Instr. Meth. B 32, 61 (1988)

    Article  Google Scholar 

  19. G. Fischfield, A. Affranchino, A. Di Loreto, C.C. Rocco, Cryst. Res. Technol. 39, 10920 (2004)

    Google Scholar 

  20. G.W. Lu, H.R. Xia, S.Q. Zhang, X. Sun, Z.S. Gao, J.Y. Wang, J. Cryst. Growth 233, 730 (2001)

    Article  Google Scholar 

  21. J.B. Benedict, P.M. Wallace, P.J. Reid, S.H. Jang, B. Kahr, Adv. Mater. 15, 1068 (2003)

    Article  Google Scholar 

  22. Y. Asakuma, M. Nishimura, Q. Li, H.M. Ang, M. Tade, K. Maeda, K. Fukui, J. Mol. Struct. Theochem. 7, 810 (2007)

    Google Scholar 

  23. B.L. Gupta, Rad. Phys. Chem. 67, 737 (2003)

    Article  Google Scholar 

  24. Yu. Velikhov, I. Pritula, I. Ganina, M. Kolybayeva, V. Puzikov, A.N. Levchenko, Cryst. Res. Technol. 42(1), 27 (2007)

    Article  Google Scholar 

  25. K. Senthil, S. Kalinathan, A. Kumar, P. Aravindan, RSC Adv. 4, 56112 (2014)

    Article  Google Scholar 

  26. G. Anandhababu, P. Ramasamy, J. Philp, Mater. Res. Bull. 46, 631 (2011)

    Article  Google Scholar 

  27. N. Boling, M. Crisp, G. Dube, Laser induced surface damage. Appl. Opt. 12, 650 (1973)

    Article  Google Scholar 

  28. S. Vediyappan, R. Arumugam, K. Pichan, R. Kasthuri, S.P. Muthu, R. Perumal, Appl. Phys. A 12, 123 (2017)

    Google Scholar 

  29. A. Senthil, P. Ramasamy, J. Cryst. Growth 401, 200 (2014)

    Article  Google Scholar 

  30. K. Sangwal, Etching of Crystals: Theory, Experiment and Application, 1st edn. (North Holland, Amsterdam, 1987)

    Google Scholar 

  31. C. Balarew, R. Duhlew, J. Solid State Chem. 1, 55 (1984)

    Google Scholar 

Download references

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Correspondence to R. Indirajith.

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Kanimozhi, D., Nandhini, S. & Indirajith, R. Effects of dyes in the growth, optical, mechanical and dielectric properties of KDP crystals. J Mater Sci: Mater Electron 30, 10244–10255 (2019). https://doi.org/10.1007/s10854-019-01361-6

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  • DOI: https://doi.org/10.1007/s10854-019-01361-6

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