Abstract
Electromagnetic interference (EMI) shielding and thermal management are essential in the design and fabrication of electronic device. Lightweight graphite membranes (GMs) prepared by solid-state foaming technology using polyimide film, are used as raw materials in this work. We obtain four different samples with the thickness of 120 µm, 87 µm, 60 µm and 32 µm by rolling GMs. The EMI shielding effectiveness in 30–3000 MHz and in-plane thermal conductivity of GMs vary from 65.5 to 103.4 dB and 129.3 to 964.6 W m−1 K−1, respectively. The density and electrical conductivity vary from 0.27 to 1.72 g cm−3 and 2.7 × 103–1.5 × 104 S cm−1, respectively. Reflecting and absorbing both are noticeable performances of GMs. The dominant shielding mechanism is the absorption that attributed to the closed-cell pores inside. All the membranes still are thermally stable even the temperature is up to 1000 °C. Therefore, graphite membranes are indeed a novel material combining excellent EMI shielding performance and elevated thermal conductivity.
Similar content being viewed by others
References
K. Shang, The Design and Test of Electromagnetic Compatibility (EMC) (Publishing House of Electronics Industry, Beijing, 2013), p. 192
B. Shen, W.T. Zhai, W.G. Zheng, Ultrathin flexible graphene film: an excellent thermal conducting material with efficient EMI shielding. Adv. Funct. Mater. 24, 4542–4548 (2014)
B. Fugetsu, E. Sano, M. Sunada, Y. Sambongi, T. Shibuya, X.S. Wang, T. Hiraki, Electrical conductivity and electromagnetic interference shielding efficiency of carbon nanotube/cellulose composite paper. Carbon 46, 1256–1258 (2008)
H.M. Kim, K. Kim, C.Y. Lee, J. Joo, S.J. Cho, H.S. Yoon, D.A. Pejakovic, J.W. Yoon, A.J. Epstein, Electrical conductivity and electromagnetic interference shielding of multiwalled carbon nanotube composites containing Fe catalyst. Appl. Phys. Lett. 84, 589–591 (2004)
N. Li, Y. Huang, F. Du, X.B. He, X. Lin, H.J. Gao, Y.F. Ma, F.F. Li, Y.S. Chen, P.C. Eklund, Electromagnetic interference (EMI) shielding of single-walled carbon nanotube epoxy composites. Nano Lett. 6, 1141–1145 (2006)
M.H. Al-Saleh, U. Sundararaj, Electromagnetic interference shielding mechanisms of CNT/polymer composites. Carbon 47, 1738–1746 (2009)
J.J. Liang, Y. Huang, L. Zhang, Y. Wang, Y.F. Ma, T.Y. Guo, Y.S. Chen, Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites. Adv. Funct. Mater. 19, 2297–2302 (2009)
J.M. Thomassin, C. Pagnoulle, L.L. Bednarz, I. Huynen, R. Jerome, C. Detrembleur, Foams of polycaprolactone/MWNT nanocomposites for efficient EMI reduction. J. Mater. Chem. 18, 792–796 (2008)
S.Y. Yang, K. Lozano, A. Lomeli, H.D. Foltz, R. Jones, Electromagnetic interference shielding effectiveness of carbon nanofiber/LCP composites. Composites A 36, 691–697 (2005)
D.D.L. Chung, Electromagnetic interference shielding effectiveness of carbon materials. Carbon 39, 279–285 (2001)
Z.F. Liu, G. Bai, Y. Huang, Y.F. Ma, F. Du, F.F. Li, T.Y. Guo, Y.S. Chen, Reflection and absorption contributions to the electromagnetic interference shielding of single-walled carbon nanotube/polyurethane composites. Carbon 45, 821–827 (2007)
S. Geetha, K.K.S. Kumar, C.R.K. Rao, M. Vijayan, D.C. Trivedi, EMI shielding: methods and materials—a review. J. Appl. Polym. Sci. 112, 2073–2086 (2010)
Y. Li, B. Shen, X.L. Pei, Y.G. Zhang, D. Yi, W.T. Zhai, L.H. Zhang, X.C. Wei, W.G. Zheng, Ultrathin carbon foams for effective electromagnetic interference shielding. Carbon 100, 375–385 (2016)
Z.Y. Dou, G.H. Wu, X.L. Huang, D.L. Sun, L.T. Jiang, Electromagnetic shielding effectiveness of aluminum alloy–fly ash composites. Composites A 38, 186–191 (2007)
Z.R. Jia, D. Lan, K.J. Lin, M. Qin, K.C. Kou, G.L. Wu, H.J. Wu, Progress in low-frequency microwave absorbing materials. J. Mater. Sci.: Mater. Electron. 29, 17122–17136 (2018)
J.M. Thomassin, C. Jerome, T. Pardoen, C. Bailly, I. Huynen, C. Detrembleur, Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials. Mater. Sci. Eng. R 74, 211–232 (2013)
Z.R. Jia, Z.G. Gao, D. Lan, Y.H. Cheng, G.L. Wu, H.J. Wu, Effects of filler loading and surface modification on electrical and thermal properties of epoxy/montmorillonite composite. Chin. Phys. B 27, 117806–117813 (2018)
Z.R. Jia, K.J. Lin, G.L. Wu, H. Xing, H.J. Wu, Recent Progresses of high-temperature microwave-absorbing materials. Nano 13, 1830005–1830027 (2018)
H.J. Wu, S.H. Qu, K.J. Lin, Y.H. Qing, L.D. Wang, Y.C. Fan, Q.H. Fu, F.L. Zhang, Enhanced low-frequency microwave absorbing property of SCFs@TiO2 composite. Powder Technol. 333, 153–159 (2018)
M. Inagaki, N. Ohta, Y. Hishiyama, Aromatic polyimides as carbon precursors. Carbon 61, 1–21 (2013)
Z.C. Tao, H.B. Wang, P.F. Lian, J.P. Zhang, Z.J. Liu, Q.G. Guo, L. Liu, “Graphitic bubbles” derived from polyimide film. Carbon 116, 733–736 (2017)
M.H. Al-Saleh, G.A. Gelves, U. Sundararaj, Copper nanowire/polystyrene nanocomposites: lower percolation threshold and higher EMI shielding. Composites A 42, 92–97 (2011)
G.A. Gelves, M.H. Al-Saleh, U. Sundararaj, Highly electrically conductive and high performance EMI shielding nanowire/polymer nanocomposites by miscible mixing and precipitation. J. Mater. Chem. 21, 829–836 (2010)
F.Q. Zhang, Q.Z. Huang, B.Y. Huang, Q.M. Gong, T.F. Chen, Effects of graphitization dergee on the electrical conductivity of C/C composites. New Carbon Mater. 16, 45–48 (2001)
B. Shen, Y. Li, D. Yi, W.T. Zhai, X.C. Wei, W.G. Zheng, Microcellular graphene foam for improved broadband electromagnetic interference shielding. Carbon 102, 154–160 (2016)
N.C. Das, Y.Y. Liu, K.K. Yang, W.Q. Peng, S. Maiti, H. Wang, Single-walled carbon nanotube/poly(methyl methacrylate) composites for electromagnetic interference shielding. Polym. Eng. Sci. 49, 1627–1634 (2009)
H.N. Zhang, A.N. Li, J. Wang, Y. Zhang, Z. Zhao, H.F. Zhao, M. Cheng, C.W. Wang, J.Y. Wang, S.C. Zhang, J.Z. Wang, Graphene integrating carbon fiber and hierarchical porous carbon formed robust flexible “carbon-concrete” supercapacitor film. Carbon 126, 500–506 (2018)
X. Luo, D.D.L. Chung, Electromagnetic interference shielding reaching 130 dB using flexible graphite. Carbon 49, 773–778 (2011)
H. Malekpour, K.H. Chang, J.C. Chen, C.Y. Lu, D.L. Nika, K.S. Novoselov, A.A. Balandin, Thermal conductivity of graphene laminate. Nano Lett. 14, 5155–5161 (2014)
Y. Zhang, M. Edwards, M.K. Samani, N. Logothetis, L.L. Ye, Y.F. Fu, K. Jeppson, J. Liu, Characterization and simulation of liquid phase exfoliated graphene-based films for heat spreading applications. Carbon 106, 195–201 (2016)
Q.Z. Liang, X.X. Yao, W. Wang, Y. Liu, C.P. Wong, A three-dimensional vertically aligned functionalized multilayer graphene architecture: an approach for graphene-based thermal interfacial materials. ACS Nano 5, 2392–2401 (2011)
Acknowledgements
The authors would like to sincerely acknowledge the financial support of the Youth Innovation Promotion Association, Chinese Academy of Sciences (Grant No. 2017205).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Hao, B., Tao, Z., Liu, Z. et al. Lightweight graphite membranes with excellent electromagnetic interference shielding effectiveness and thermal conductivity. J Mater Sci: Mater Electron 30, 6734–6744 (2019). https://doi.org/10.1007/s10854-019-00985-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-00985-y