Abstract
In this work, the polycrystalline SnSe bulk samples were prepared by the spark plasma sintering (SPS) using the SnSe powders, which were synthesized by the hydrothermal reaction (HR) or the melting reaction (MR), respectively. X-ray diffraction (XRD) patterns reveal strong orientation along the [l00] direction for both wafer samples, but there is obvious different micro-morphologies in the powder and the bulk fracture as shown in scanning electron microscopy (SEM) images. The zigzag type texturing characteristic appears in the entire interior of the bulk sample prepared by the process (HR + SPS), while random arrangement occurs in interior of another bulk sample prepared by the process (MR + SPS).The formation mechanism of the zigzag type texturing come mainly from control of initial powders morphology and pressing into pre-pressed blocks by layers. The special zigzag type texturing characteristic improve the thermoelectric properties of samples, and the highest ZT value (~ 0.67) at 773 K were found in the SnSe bulk sample prepared by the process (HR + SPS) in the direction parallel to the pressing axis. The thermoelectric compatibility factor of samples prepared by the process (HR + SPS) are less than 2 at 773 K. The fracture toughness in the plane that vertical or parallel to the pressing direction was calculated to be 4.0 MPam1/2 and 4.2 MPam1/2, respectively. The proper thermoelectric compatibility factor and fracture toughness make the SnSe system better application prospect.
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X. Li, S. Li, B. Yang, S.K. Feng, H. Zhong, Microstructure and thermoelectric properties of un-doped Mg2Si1 – xSnx single crystals prepared by high temperature gradient directional solidification. J. Mater. Sci. 29(8), 6245–6253 (2018)
H.Q. Liu, Z.J. Yu, Y.J. Gu, Y.B. Chen, Effect of micro-structure on electrical transport properties in Ca3Co4O9 ceramics. Rare Met. 30, 77–80 (2011)
S. Roychowdhury, M.K. Jana, J. Pan, S.N. Guin, D. Sanyal, U.V. Waghmare, K. Biswas, Soft phonon modes leading to ultralow thermal conductivity and high thermoelectric performance in AgCuTe. Angew. Chem. 57(15), 4043–4047 (2018)
H.Q. Liu, X.B. Zhao, T.J. Zhu, Y.J. Gu, Enhanced thermoelectric properties of Co1 – x–yNix+y Sb3 – xSnx materials. Int. J. Miner., Metall. Mater. 19, 240–244 (2012)
X.B. Zhao, X.H. Ji, Y.H. Zhang, T.J. Zhu, J.P. Tu, Bismuth telluride nanotubes and the effects on the thermoelectric properties of nanotube-containing nanocomposites. Appl. Phys. Lett. 86(6), 062111 (2005)
K. Biswas, J.Q. He, I.D. Blum, C.I. Wu, T.P. Hogan, D.N. Seidman, V.P. Dravid, M.G. Kanatzidis, High-performance bulk thermoelectrics with all-scale hierarchical architectures. Nature 489, 414–418 (2012)
I. Lefebvre, M.A. Szymanski, J. Olivier-Fourcade, J.C. Jumas, Electronic structure of tin monochalcogenides from SnO to SnTe. Phys. Rev. B 58(4), 1896–1906 (1998)
G.D. Li, U. Aydemir, M. Wood, W.A. Goddard, P.C. Zhai, Q.J. Zhang, G.J. Snyder, Ideal strength and deformation mechanism in high-efficiency thermoelectric SnSe. Chem. Mater. 29, 2382–2389 (2017)
L.D. Zhao, S. Lo, Y. Zhang, H. Sun, G.J. Tan, C. Uher, C. Wolverton, V.P. Dravid, M.G. Kanatzidis, Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals. Nature 508, 373–377 (2014)
L.D. Zhao, G. Tan, S. Hao et al., Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe. Science 351(6269), 141–144 (2016)
C. Chen, H. Wang, Y. Chen, T. Day, G.J. Snyder, Thermoelectric properties of p-type polycrystalline SnSe doped with Ag. J. Mater. Chem. A 2, 11171–11176 (2014)
Y.X. Chen, Z. Ge, M. Yin et al., Understanding of the extremely low thermal conductivity in high-performance polycrystalline SnSe through potassium doping. Adv. Func. Mater. 26, 6836–6845 (2016)
Y. Fu, J. Xu, G.Q. Liu, Enhanced thermoelectric performance in p-type polycrystalline SnSe benefiting from texture modulation. J. Mater. Chem. C 4, 1201–1207 (2016)
G.D. Tang, Q. Wen, T. Yang, Rock-salt-type nano-precipitates lead to high thermoelectric performance in undoped polycrystalline SnSe. RSC Adv. 7, 8258–8263 (2017)
Z.H. Ge, D. Song, X. Chong, F. Zheng, L. Jin, X. Qian, Boosting the thermoelectric performance of (Na,K)-codoped polycrystalline SnSe by synergistic tailoring of the band structure and atomic-scale defect phonon scattering.J. Am. Chem. Soc. 139 (28), 9714–9720 (2017)
Z.J. Xu, L.P. Hu, P.J. Ying, X.B. Zhao, T.J. Zhu, Enhanced thermoelectric and mechanical properties of zone melted p-type (Bi,Sb) 2 Te 3 thermoelectric materials by hot deformation. Acta Mater. 84, 385–392 (2015)
Z. Liu, W. Gao, X. Meng, X. Li, J. Mao, Y. Wang, J. Shuai, W. Cai, Z. Ren, J. Sui, Mechanical properties of nanostructured thermoelectric materials α-MgAgSb. Scr. Mater. 127, 72–75 (2017)
F. Chu, Q. Zhang, Z. Zhou, D. Hou, L. Wang, W. Jiang, Enhanced thermoelectric and mechanical properties of Na-doped polycrystalline SnSe thermoelectric materials via CNTs dispersion. J. Alloys Compd. 741, 756–764 (2018)
J. Fu, X. Su, H. Xie, Y. Yan, W. Liu, Y. You, X. Cheng, C. Uher, X.F. Tang, Understanding the combustion process for the synthesis of mechanically robust SnSe thermoelectrics. Nano Energy 44, 53–62 (2018)
G.J. Snyder, T. Ursell, Thermoelectric efficiency and compatibility. Phys. Rev. Lett. 91, 148301 (2003)
G.J. Snyder, Application of the compatibility factor to the design of segmented and cascaded thermoelectric generators. Appl. Phys. Lett. 84(13), 2436–2438 (2004)
Z.Y. Chu, H.Q. Liu, C.H. Yuan, Y.Q. Wang, W.J. Wang, H.Z. Cui, Y.J. Gu, Textured SnSe micro-sheets: One-pot facile synthesis and comprehensive understanding on the growth mechanism. J Mater Chem Phys. 199, 464–470 (2017)
Y. Li, F. Li, J. Dong, Z. Ge, F. Kang, J. He, H. Du, B. Li, J.F. Li, Enhanced mid-temperature thermoelectric performance of textured SnSe polycrystals made of solvothermally synthesized powders. J. Mater. Chem. C 4, 2047–2055 (2016)
G.J. Snyder, E.S. Toberer, Complex thermoelectric materials. Nat. Mater. 7, 105–114 (2008)
J. Zhou, X.B. Li, G. Chen et al., Semiclassical model for thermoelectric transport in nanocomposites. Phys. Rev. B, 82, 115308 (2010)
E.K. Chere, Q. Zhang, K. Dahal, F. Cao, J. Mao, Z.F. Ren, Studies on thermoelectric figure of merit of Na-doped p-type polycrystalline SnSe. J. Mater. Chem. A. 4, 1848–1854 (2016)
S. Sassi, C. Candolfi, J.B. Vaney, V. Ohorodniichuk, P. Masschelein, A. Dauscher, B. Lenoir, Assessment of the thermoelectric performance of polycrystalline p-type SnSe. Appl. Phys. Lett. 104(21), 1–4 (2014)
J. Ding, B. Xu, Y. Lin, C. Nan, W. Liu, Lattice vibration modes of the layered material BiCuSeO and first principles study of its thermoelectric properties. New J. Phys. 17, 083012 (2015)
A. Soni, Y.Q. Shen, M. Yin et al. Interface driven energy filtering of thermoelectric power in spark plasma sintered Bi2Te2.7Se0.3 nanoplatelet composites. Nano Lett. 12 (8), 4305–4310 (2012)
P.H. Ngan, D.V. Christensen, G.J. Snyder, L.T. Hung, S. Linderoth, N.V. Nong, N. Pryds, Towards high efficiency segmented thermoelectric unicouples. Phys. Status Solidi A 211(1), 9–17 (2014)
G. Anstis, P. Chantikul, B.R. Lawn, D. Marshall, A critical evaluation of indentation techniques for measuring fracture toughness: I, direct crack measurements. J. Am. Ceram. Soc. 64(9), 533–538 (1981)
X. He, H. Shen, W. Wang, Z. Wang, B. Zhang, X. Li, The mechanical and thermo-physical properties and electronic structures of SnS and SnSe in orthorhombic structure. J. Alloys Compd. 556, 86–93 (2013)
K. Tyagi, B. Gahtori, S.B. Thula, N.K. Singh, S. Bishnoi, S. Auluck, A.K. Srivastava, A. Dhar, Electrical transport and mechanical properties of thermoelectric tin selenide. RSC Adv. 6(14), 11562–11569 (2016)
F. Ren, B.D. Hall, J.E. Ni, E.D. Case, J. Sootsman, M.G. Kanatzidis, E. Lara-Curzio, R.M. Trejo, E.J. Timm, Mechanical characterization of PbTe-based thermoelectric materials. MRS Proc. 1044, (2007)
L.D. Zhao, B.P. Zhang, J.F. Li, M. Zhou, W.S. Liu, J. Liu, Thermoelectric and mechanical properties of nano-SiC-dispersed Bi2Te3 fabricated by mechanical alloying and spark plasma sintering. J. Alloys Compd. 455(1–2), 259–264 (2008)
P.F. Becher, Microstructural design of toughened ceramics. J. Am. Ceram. Soc. 74, 255–269 (1991)
Acknowledgements
The authors would like to thank the financial supports from Tai-shan scholarship of climbing plan, No.tspd20161006, Shandong Natural Science Foundation Project (Grant No. ZR2015EM013), and a Project of Shandong Province Higher Educational Science and Technology Program (Grant No. YA07), and Shandong University of Science and Technology Research Fund (No. SDKDYC180370).
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Ma, C., Liu, H., Chen, R. et al. Anisotropy thermoelectric and mechanical property of polycrystalline SnSe prepared under different processes. J Mater Sci: Mater Electron 30, 6403–6410 (2019). https://doi.org/10.1007/s10854-019-00943-8
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DOI: https://doi.org/10.1007/s10854-019-00943-8