Abstract
Clay mineral/CdS nanocomposites were successfully prepared via hydrothermal technique in the presence of different clay minerals for photocatalytic degradation of Congo red. The relevant structures and properties were systematically characterized and studied, including phase composition, crystal size, color, optical property and morphology of the obtained nanocomposites. The generated hexagonal CdS nanoparticles with a diameter of 30–60 nm were well anchored on the surface of clay minerals. Interestingly, the types of clay minerals affected the UV–Vis absorbance and band-gap energy of clay mineral/CdS nanocomposites, and the clay mineral/CdS nanocomposites derived from one-dimensional halloysite, sepiolite, and palygorskite exhibited higher photocatalytic activity for Congo red degradation than that of two-dimensional lamellar kaolin and montmorillonite. In addition, incorporating of clay minerals not only effectively decreased the size of CdS nanoparticles without the obvious aggregation, but also guard against electrochemical corrosion of CdS during photocatalytic degradation.
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References
Y. Shi, K. Zhou, B. Wang et al., Ternary graphene-CoFe2O4/CdS nanohybrids: preparation and application as recyclable photocatalysts. J. Mater. Chem. A 2, 535–544 (2014)
X. Li, W. Zhang, N. Liu et al., Superwetting copper meshes based on self-organized robust CuO nanorods: efficient water purification for in situ oil removal and visible light photodegradation. Nanoscale 10, 4561–4569 (2018)
L. Zhang, T. Wang, H. Wang et al., Graphene@poly(m-phenylenediamine) hydrogel fabricated by a facile post-synthesis assembly strategy. Chem. Commun. 49, 9974–9976 (2013)
X. Ma, P. Chen, M. Zhou et al., Tight ultrafiltration ceramic membrane for separation of dyes and mixed salts (both NaCl/Na2SO4) in textile wastewater treatment. Ind. Eng. Chem. Res. 56, 7070–7079 (2017)
K. Hedayati, S. Azarakhsh, J. Saffari et al., Magnetic and photo-catalyst CoFe2O4–CdS nanocomposites: simple preparation of Ni, Co, Zn or Ag-doped CdS nanoparticles. J. Mater. Sci. 28, 5472–5484 (2017)
K.P. Sonu, B.V.V.S.P. Kumar, S.J. George et al., Simple and facile approach to create charge reversible pores via hydrophobic anchoring of ionic amphiphiles. ACS Appl. Mater. Interfaces 9, 9136–9142 (2017)
F.L.Y. Lam, X. Hu, pH-insensitive bimetallic catalyst for the abatement of dye pollutants by photo-fenton oxidation. Ind. Eng. Chem. Res. 52, 6639–6646 (2013)
A. Christodoulakis, M. Machli, A.A. Lemonidou et al., Molecular structure and reactivity of vanadia-based catalysts for propane oxidative dehydrogenation studied by in situ Raman spectroscopy and catalytic activity measurements. J. Catal. 222, 293–306 (2004)
S. Rondiya, A. Rokade, P. Sharma et al., CZTS/CdS: interface properties and band alignment study towards photovoltaic applications. J. Mater. Sci. 29, 4201–4210 (2018)
J.X. Lv, Z.M. Zhang, J. Wang et al., In situ synthesis of CdS/Graphdiyne heterojunction for enhanced photocatalytic activity of hydrogen production. ACS Appl. Mater Interfaces 11, 2655–2661 (2018)
W. Xing, L. Ni, P. Huo, Z. Lu et al., Preparation high photocatalytic activity of CdS/halloysite nanotubes (HNTs) nanocomposites with hydrothermal method. Appl. Surf. Sci. 259, 698–704 (2012)
Q. Wang, J. Lian, Q. Ma et al., Preparation of carbon spheres supported CdS photocatalyst for enhancement its photocatalytic H2 evolution. Catal. Today 281, 662–668 (2017)
H. Gao, Z. Mo, R. Guo et al., Formation of snowflake-like CdS/reduced graphene oxide composite for efficient photocatalytic organic dye degradation. J. Mater. Sci. 29, 5944–5953 (2018)
H. Chen, S. Cao, J. Yao et al., Fabrication of Ag nanowires-CdS-Au photocatalyst and its excellent visible light photocatalytic activity: the role of synergetic electron transfer. J. Taiwan. Inst. Chem. E. 71, 189–196 (2017)
R. Peng, C.M. Wu, J. Baltrusaitis et al., Solar hydrogen generation over CdS incorporated in Ti-MCM-48 mesoporous materials under visible light illumination. Int. J. Hydrogen Energy 41, 4106–4119 (2016)
Z. Han, Q. Yang, J. Shi et al., Well-dispersed cadmium sulfide prepared in the presence of laponite by microwave irradiation. Solid State Sci. 10, 563–568 (2008)
F. Zhou, D. Chen, B. Cui et al., Synthesis and characterization of CdS/TiO2-montmorillonite nanocomposite with enhanced visible-light absorption. J. Spectrosc. (2014). https://doi.org/10.1155/2014/961230
H. Boukhatem, L. Djouadi, N. Abdelaziz et al., Synthesis, characterization and photocatalytic activity of CdS-montmorillonite nanocomposites. Appl. Clay Sci. 72, 44–48 (2013)
X. Li, L. Fu, J. Ouyang et al., Microwave-assisted synthesis and interfacial features of CdS/kaolinite nanocomposite. Colloid Surf. A 443, 72–79 (2014)
V. Štengl, D. Popelková, T.M. Grygar, Composite pigments based on surface coated kaolin and metakaolin. Appl. Clay Sci. 101, 149–158 (2014)
V.A. Vinokurov, A.V. Stavitskaya, E.V. Ivanov et al., Halloysite nanoclay based CdS formulations with high catalytic activity in hydrogen evolution reaction under visible light irradiation. ACS Sustain. Chem. Eng. 5, 11316–11323 (2017)
J. Zhang, R. He, X. Liu, Efficient visible light driven photocatalytic hydrogen production from water using attapulgite clay sensitized by CdS nanoparticles. Nanotechnology 24, 505401 (2013)
D. Chen, Y. Du, H. Zhu et al., Synthesis and characterization of a microfibrous TiO2-CdS/palygorskite nanostructured material with enhanced visible-light photocatalytic activity. Appl. Clay Sci. 87, 285–291 (2014)
J. Xiao, T. Peng, K. Dai et al., Hydrothermal synthesis, characterization and its photoactivity of CdS/rectorite nanocomposites. J. Solid State Chem. 180, 3188–3195 (2007)
Z. Han, H. Zhu, K.R. Ratinac et al., Nanocomposites of layered clays and cadmium sulfide: Similarities and differences in formation, structure and properties. Microporous Mesoporous Mater. 108, 168–182 (2008)
X. Wang, B. Mu, X. An et al., Insights into the relationship between the color and photocatalytic property of attapulgite/CdS nanocomposites. Appl. Surf. Sci. 439, 202–212 (2018)
D. Kandi, S. Martha, A. Thirumurugan et al., Modification of BiOI microplates with CdS QDs for enhancing stability, optical property, electronic behavior toward Rhodamine B decolorization, and photocatalytic hydrogen evolution. J. Phys. Chem. C 121, 4834–4849 (2017)
K. Nasau, The causes of color. Sci. Am. 243, 124–154 (1980)
S. Ma, Y. Deng, J. Xie et al., Noble-metal-free Ni3C cocatalysts decorated CdS nanosheets for high-efficiency visible-light-driven photocatalytic H2 evolution. Appl. Catal. B-Environ. 227, 218–228 (2018)
J. Zhao, K. Ge, L. Zhao et al., Enhanced photocatalytic properties of CdS -decorated BiPO4 heterogeneous semiconductor catalyst under UV-light irradiation. J. Alloy. Compd. 729, 189–197 (2017)
C. Singh, A. Goyal, R. Malik et al., Envisioning the attachment of CdS nanoparticles on the surface of MFe2O4 (M = Zn, Co and Ni) nanocubes: analysis of structural, optical, magnetic and photocatalytic properties. J. Alloy Compd. 695, 351–363 (2017)
D. Kashchiev, G.M. Van Rosmalen, Review: nucleation in solutions revisited. Cryst. Res. Technol. 38, 555–574 (2010)
U.A. Khan, J. Liu, J. Pan et al., Fabrication of floating CdS/EP photocatalyst by facile liquid phase deposition for highly efficient degradation of Rhodamine B (RhB) under visible light irradiation. Mater. Sci. Semicond. Proc. 83, 201–210 (2018)
R. Wang, J. Yan, M. Zu et al., Facile synthesis of interlocking g-C3N4/CdS photoanode for stable photoelectrochemical hydrogen production. Electrochim. Acta 279, 74–83 (2018)
J. Fu, B. Chang, Y. Tian et al., Novel C3N4-CdS composite photocatalysts with organic–inorganic heterojunctions: in situ synthesis, exceptional activity, high stability and photocatalytic mechanism. J. Mater. Chem. A 1, 3083–3090 (2013)
P. Chawla, S.P. Lochab, N. Singh, Photoluminescence, thermoluminescence and Raman studies of CdS nanocrystalline phosphor. J. Alloy Compd. 492, 662–666 (2010)
E. Rani, A. A.Ingale, A.K. Sinha, Interaction between CdS nanocrystals and PVP leading to co-operative growth of CdS-PVP nanocomposites: a Raman and AFM mapping study. J. Alloy Compd. 729, 597–602 (2017)
R. Arunadevi, B. Kavitha, M. Rajarajan et al., Investigation of the drastic improvement of photocatalytic degradation of Congo red by monoclinic Cd, Ba-CuO nanoparticles and its antimicrobial activities. Surf. Interfaces 10, 32–44 (2018)
V.A. Sakkas, M.A. Islam, C. Stalikas et al., Photocatalytic degradation using design of experiments: a review and example of the Congo red degradation. J. Hazard. Mater. 175, 33–44 (2010)
B. Mu, A. Wang, One-pot fabrication of multifunctional superparamagnetic attapulgite/Fe3O4/polyaniline nanocomposites served as adsorbent and catalyst support. J. Mater. Chem. A 3, 281–289 (2015)
B. Mu, J. Tang, L. Zhang et al., Preparation, characterization and application on dye adsorption of a well-defined two-dimensional superparamagnetic clay/polyaniline/Fe3O4 nanocomposite. Appl. Clay Sci. 132–133, 7–16 (2016)
F. Ferrarini, L.R. Bonetto, J.S. Crespo et al., Removal of Congo red dye from aqueous solutions using a halloysite-magnetite-based composite. Water Sci. Technol. 73, 2132–2142 (2016)
D. Jiang, Z. Liu, L. Fu et al., Efficient nanoclay-based composite photocatalyst: the role of nanoclay in photogenerated charge separation. J. Phys. Chem. C 122, 25900–25908 (2018)
H. Hu, M. Wang, C. Deng et al., Satellite-like CdS nanoparticles anchoring onto porous NiO nanoplates for enhanced visible-light photocatalytic properties. Mater. Lett. 224, 75–77 (2018)
Z. Yu, B. Yin, F. Qu et al., Synthesis of self-assembled CdS nanospheres and their photocatalytic activities by photodegradation of organic dye molecules. Chem. Eng. J. 258, 203–209 (2014)
I. Ullah, A. Haider, N. Khalid et al., Tuning the band gap of TiO2 by tungsten doping for efficient UV and visible photodegradation of Congo red dye. Spectrochim. Acta A 204, 150–157 (2018)
L. Zou, X. Wang, X. Xu et al., Reduced graphene oxide wrapped CdS composites with enhanced photocatalytic performance and high stability. Ceram. Int. 42, 372–378 (2016)
A. Khan, R. Zia, M. Rehman et al., CdS nanocapsules and nanospheres as efficient solar light-driven photocatalysts for degradation of Congo red dye. Inorg. Chem. Commun. 72, 33–41 (2016)
A. Mishra, A. Mehta, S. Basu, Clay supported TiO2 nanoparticles for photocatalytic degradation of environmental pollutants: A review. J Environ. Chem. Eng. 6, 6088–6107 (2018)
D. Kibanova, M. Trejo, H. Destaillats, J. Cervini-Silva, Synthesis of hectorite-TiO2 and kaolinite-TiO2 nanocomposites with photocatalytic activity for the degradation of model air pollutants. Appl. Clay Sci. 42, 563–568 (2009)
Acknowledgements
The authors are grateful for financial support of the Major Projects of the National Natural Science Foundation of Gansu, China (18JR4RA001), the Funds for Creative Research Groups of Gansu, China (17JR5RA306), the Youth Innovation Promotion Association of CAS (2017458), Major Science and Technology Projects of Lanzhou (2017-2-3) and the fifth “333 project” of Jiangsu Province, China (BRA2017259).
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Wang, X., Mu, B., Hui, A. et al. Comparative study on photocatalytic degradation of Congo red using different clay mineral/CdS nanocomposites. J Mater Sci: Mater Electron 30, 5383–5392 (2019). https://doi.org/10.1007/s10854-019-00831-1
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DOI: https://doi.org/10.1007/s10854-019-00831-1