Abstract
Various luminescent carbon materials are artificially synthesized and as admirable fluorescent materials because of the increased research of carbon nanodots (CDs). Herein, a novel solvent-dependent red CDs (rCDs) is introduced through solvothermal method. The as-prepared rCDs remain benzene structure and possess abundant surface function groups that endow them well solubility in various solvents. Furthermore, multicolor luminescence are observed when rCDs are dissolved in different solvents, and the emission wavelength of these materials can be well-tuned from 475 to 624 nm, which presents intensity solvent-dependent properties. Red luminescence carbon phosphors are successfully synthesized by mix rCDs with silica powder. Finally, warm white light emitting diodes (WLEDs) are constructed using rCDs powder with Ce3+: YAG single crystal and blue GaN chips. The results demonstrate that the rCDs can act as red component to modify the correlated color temperature (CCT) and the color rendering index (CRI) of WLEDs .
Similar content being viewed by others
References
H. Ali, S.K. Bhunia, C. Dalal, N.R. Jana, Red fluorescent carbon nanoparticle-based cell imaging probe. ACS Appl. Mater. Interfaces 8, 9305 (2016)
S. Zhu, J. Zhang, S. Tang, C. Qiao, L. Wang, H. Wang, X. Liu, B. Li, Y. Li, W. Yu, Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: from fluorescence mechanism to up-conversion bioimaging applications. Adv. Func. Mater. 22, 4732–4740 (2012)
H.S. Jang, D.Y. Jeon, White light emission from blue and near ultraviolet light-emitting diodes precoated with a Sr3SiO5:Ce3+,Li + phosphor. Opt. Lett. 32, 3444–3446 (2007)
M. Gong, X. Liang, Y. Wang, H. Xu, L. Zhang, W. Xiang, Novel synthesis and optical characterization of phosphor-converted WLED employing Ce:YAG-doped glass. J. Alloys Compd. 664, 125–132 (2016)
K. Uheda, N. Hirosaki, Y. Yamamoto. T. Naito, H. Nakajima, Yamamoto, Luminescence properties of a red phosphor, CaAlSiN3:Eu2+, for white light-emitting diodes. Electrochem. Solid-State Lett. 9, H22–H25 (2006)
C. Guo, D. Huang, Q. Su, Methods to improve the fluorescence intensity of CaS:Eu2+ red-emitting phosphor for white LED. Mater. Sci. Eng. B 130, 189–193 (2006)
L. Wei, C. Lin, M. Fang, G.M. Brik, S. Hu, H. Jiao, R. Liu, A low-temperature co-precipitation approach to synthesize fluoride phosphors K2MF6:Mn4+ (M=Ge, Si) for white LED applications. J. Mater. Chem. C 3, 1655–1660 (2015)
Y. Chen, H. Lian, Y. Wei, X. He, Y. Chen, B. Wang, Q. Zeng, J. Lin, Concentration induced multi-color emission in carbon dots: origination from triple fluorescent centers. Nanoscale 10, 6734–6743 (2018)
Y. Fan, X. Guo, Y. Zhang, Y. Lv, J. Zhao, X. Liu, Efficient and stable red emissive carbon nanoparticles with a hollow sphere structure for white light-emitting diodes. ACS Appl. Mater. Interfaces 8, 31863 (2016)
C.X. Li, C. Yu, C.F. Wang, S. Chen, Facile plasma-induced fabrication of fluorescent carbon dots toward high-performance white LEDs. J. Mater. Sci. 48, 6307–6311 (2013)
S. Li, Z. Guo, Y. Zhang, W. Xue, Z. Liu, Blood compatibility evaluations of fluorescent carbon dots. ACS Appl. Mater. Interfaces 7, 19153–19162 (2015)
D. Zhao, C. Chen, L. Lu, F. Yang, X. Yang, A dual-mode colorimetric and fluorometric “light on” sensor for thiocyanate based on fluorescent carbon dots and unmodified gold nanoparticles. Analyst 140, 8157–8164 (2015)
M.L. Cayuela, M. Soriano, Valcárcel, Strong luminescence of carbon dots induced by acetone passivation: efficient sensor for a rapid analysis of two different pollutants. Anal. Chim. Acta 804, 246 (2013)
H. Li, Z. Kang, Y. Liu, S.T. Lee, Carbon nanodots: synthesis, properties and applications. J. Mater. Chem. 22, 24230–24253 (2012)
Y. Dong, J. Shao, C. Chen, H. Li, R. Wang, Y. Chi, X. Lin, G. Chen, Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon 50, 4738–4743 (2012)
R. Gaddam, D. Vasudevan, R. Narayan, K.V. Raju, Controllable synthesis of biosourced blue-green fluorescent carbon dots from camphor for the detection of heavy metal ions in water. RSC Adv. 4, 57137–57143 (2014)
N. Kimura, K. Sakuma, S. Hirafune, K. Asano, Extrahigh color rendering white light-emitting diode lamps using oxynitride and nitride phosphors excited by blue light-emitting diode. Appl. Phys. Lett. 90,051109–051103 (2007)
Y. Liu, N. Xiao, N. Gong, H. Wang, X. Shi, W. Gu, L. Ye, One-step microwave-assisted polyol synthesis of green luminescent carbon dots as optical nanoprobes. Carbon 68, 258–264 (2014)
S. Zhu, J. Zhang, C. Qiao, S. Tang, Y. Li, W. Yuan, B. Li, L. Tian, F. Liu, R. Hu, Strongly green-photoluminescent graphene quantum dots for bioimaging applications. Chem. Commun. 47, 6858–6860 (2011)
S. Qu, D. Zhou, D. Li, W. Ji, P. Jing, D. Han, L. Liu, H. Zeng, D. Shen, Toward efficient orange emissive carbon nanodots through conjugated sp(2)—domain controlling and surface charges engineering. Adv. Mater. 28, 3516 (2016)
L. Tang, R. Ji, X. Li, G. Bai, C.P. Liu, J. Hao, J. Lin, H. Jiang, K.S. Teng, Z. Yang, Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots. ACS Nano. 8, 6312–6320 (2014)
K. Jiang, L. Zhang, J. Lu, C. Xu, C. Cai, H. Lin, Triple-mode emission of carbon dots: applications for advanced anti-counterfeiting. Angew. Chem. 55, 7231–7235 (2016)
H. Li, X. He, Z. Kang, H. Huang, Y. Liu, J. Liu, S. Lian, C.H. Tsang, X. Yang, S.T. Lee, Water-soluble fluorescent carbon quantum dots and photocatalyst design. Angew. Chem. 49, 4430 (2010)
J. Peng, W. Gao, B.K. Gupta, Z. Liu, R. Romeroaburto, L. Ge, L. Song, L.B. Alemany, X. Zhan, G. Gao, Graphene quantum dots derived from carbon fibers. Nano Lett. 12, 844 (2012)
R. Loukanov, M. Sekiya, N. Yoshikawa, Y. Kobayashi, S. Moriyasu, Nakabayashi, Photosensitizer-conjugated ultrasmall carbon nanodots as multifunctional fluorescent probes for bioimaging. J. Phys. Chem. C 120, 15869–15874 (2016)
Acknowledgements
The authors acknowledge the financial support from National Natural Sciences Foundation of China (Grants No. 51472183). The authors declare that they have no conflict of interest.
Author information
Authors and Affiliations
Corresponding authors
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Yuan, R., Liu, J., Xiang, W. et al. Red-emitting carbon dots phosphors: a promising red color convertor toward warm white light emitting diodes. J Mater Sci: Mater Electron 29, 10453–10460 (2018). https://doi.org/10.1007/s10854-018-9103-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-9103-3