Skip to main content
Log in

Red-emitting carbon dots phosphors: a promising red color convertor toward warm white light emitting diodes

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Various luminescent carbon materials are artificially synthesized and as admirable fluorescent materials because of the increased research of carbon nanodots (CDs). Herein, a novel solvent-dependent red CDs (rCDs) is introduced through solvothermal method. The as-prepared rCDs remain benzene structure and possess abundant surface function groups that endow them well solubility in various solvents. Furthermore, multicolor luminescence are observed when rCDs are dissolved in different solvents, and the emission wavelength of these materials can be well-tuned from 475 to 624 nm, which presents intensity solvent-dependent properties. Red luminescence carbon phosphors are successfully synthesized by mix rCDs with silica powder. Finally, warm white light emitting diodes (WLEDs) are constructed using rCDs powder with Ce3+: YAG single crystal and blue GaN chips. The results demonstrate that the rCDs can act as red component to modify the correlated color temperature (CCT) and the color rendering index (CRI) of WLEDs .

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. H. Ali, S.K. Bhunia, C. Dalal, N.R. Jana, Red fluorescent carbon nanoparticle-based cell imaging probe. ACS Appl. Mater. Interfaces 8, 9305 (2016)

    Article  CAS  Google Scholar 

  2. S. Zhu, J. Zhang, S. Tang, C. Qiao, L. Wang, H. Wang, X. Liu, B. Li, Y. Li, W. Yu, Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: from fluorescence mechanism to up-conversion bioimaging applications. Adv. Func. Mater. 22, 4732–4740 (2012)

    Article  CAS  Google Scholar 

  3. H.S. Jang, D.Y. Jeon, White light emission from blue and near ultraviolet light-emitting diodes precoated with a Sr3SiO5:Ce3+,Li + phosphor. Opt. Lett. 32, 3444–3446 (2007)

    Article  CAS  Google Scholar 

  4. M. Gong, X. Liang, Y. Wang, H. Xu, L. Zhang, W. Xiang, Novel synthesis and optical characterization of phosphor-converted WLED employing Ce:YAG-doped glass. J. Alloys Compd. 664, 125–132 (2016)

    Article  CAS  Google Scholar 

  5. K. Uheda, N. Hirosaki, Y. Yamamoto. T. Naito, H. Nakajima, Yamamoto, Luminescence properties of a red phosphor, CaAlSiN3:Eu2+, for white light-emitting diodes. Electrochem. Solid-State Lett. 9, H22–H25 (2006)

    Article  Google Scholar 

  6. C. Guo, D. Huang, Q. Su, Methods to improve the fluorescence intensity of CaS:Eu2+ red-emitting phosphor for white LED. Mater. Sci. Eng. B 130, 189–193 (2006)

    Article  CAS  Google Scholar 

  7. L. Wei, C. Lin, M. Fang, G.M. Brik, S. Hu, H. Jiao, R. Liu, A low-temperature co-precipitation approach to synthesize fluoride phosphors K2MF6:Mn4+ (M=Ge, Si) for white LED applications. J. Mater. Chem. C 3, 1655–1660 (2015)

    Article  CAS  Google Scholar 

  8. Y. Chen, H. Lian, Y. Wei, X. He, Y. Chen, B. Wang, Q. Zeng, J. Lin, Concentration induced multi-color emission in carbon dots: origination from triple fluorescent centers. Nanoscale 10, 6734–6743 (2018)

    Article  CAS  Google Scholar 

  9. Y. Fan, X. Guo, Y. Zhang, Y. Lv, J. Zhao, X. Liu, Efficient and stable red emissive carbon nanoparticles with a hollow sphere structure for white light-emitting diodes. ACS Appl. Mater. Interfaces 8, 31863 (2016)

    Article  CAS  Google Scholar 

  10. C.X. Li, C. Yu, C.F. Wang, S. Chen, Facile plasma-induced fabrication of fluorescent carbon dots toward high-performance white LEDs. J. Mater. Sci. 48, 6307–6311 (2013)

    Article  CAS  Google Scholar 

  11. S. Li, Z. Guo, Y. Zhang, W. Xue, Z. Liu, Blood compatibility evaluations of fluorescent carbon dots. ACS Appl. Mater. Interfaces 7, 19153–19162 (2015)

    Article  CAS  Google Scholar 

  12. D. Zhao, C. Chen, L. Lu, F. Yang, X. Yang, A dual-mode colorimetric and fluorometric “light on” sensor for thiocyanate based on fluorescent carbon dots and unmodified gold nanoparticles. Analyst 140, 8157–8164 (2015)

    Article  CAS  Google Scholar 

  13. M.L. Cayuela, M. Soriano, Valcárcel, Strong luminescence of carbon dots induced by acetone passivation: efficient sensor for a rapid analysis of two different pollutants. Anal. Chim. Acta 804, 246 (2013)

    Article  CAS  Google Scholar 

  14. H. Li, Z. Kang, Y. Liu, S.T. Lee, Carbon nanodots: synthesis, properties and applications. J. Mater. Chem. 22, 24230–24253 (2012)

    Article  CAS  Google Scholar 

  15. Y. Dong, J. Shao, C. Chen, H. Li, R. Wang, Y. Chi, X. Lin, G. Chen, Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon 50, 4738–4743 (2012)

    Article  CAS  Google Scholar 

  16. R. Gaddam, D. Vasudevan, R. Narayan, K.V. Raju, Controllable synthesis of biosourced blue-green fluorescent carbon dots from camphor for the detection of heavy metal ions in water. RSC Adv. 4, 57137–57143 (2014)

    Article  CAS  Google Scholar 

  17. N. Kimura, K. Sakuma, S. Hirafune, K. Asano, Extrahigh color rendering white light-emitting diode lamps using oxynitride and nitride phosphors excited by blue light-emitting diode. Appl. Phys. Lett. 90,051109–051103 (2007)

    Article  Google Scholar 

  18. Y. Liu, N. Xiao, N. Gong, H. Wang, X. Shi, W. Gu, L. Ye, One-step microwave-assisted polyol synthesis of green luminescent carbon dots as optical nanoprobes. Carbon 68, 258–264 (2014)

    Article  CAS  Google Scholar 

  19. S. Zhu, J. Zhang, C. Qiao, S. Tang, Y. Li, W. Yuan, B. Li, L. Tian, F. Liu, R. Hu, Strongly green-photoluminescent graphene quantum dots for bioimaging applications. Chem. Commun. 47, 6858–6860 (2011)

    Article  CAS  Google Scholar 

  20. S. Qu, D. Zhou, D. Li, W. Ji, P. Jing, D. Han, L. Liu, H. Zeng, D. Shen, Toward efficient orange emissive carbon nanodots through conjugated sp(2)—domain controlling and surface charges engineering. Adv. Mater. 28, 3516 (2016)

    Article  CAS  Google Scholar 

  21. L. Tang, R. Ji, X. Li, G. Bai, C.P. Liu, J. Hao, J. Lin, H. Jiang, K.S. Teng, Z. Yang, Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots. ACS Nano. 8, 6312–6320 (2014)

    Article  CAS  Google Scholar 

  22. K. Jiang, L. Zhang, J. Lu, C. Xu, C. Cai, H. Lin, Triple-mode emission of carbon dots: applications for advanced anti-counterfeiting. Angew. Chem. 55, 7231–7235 (2016)

    Article  CAS  Google Scholar 

  23. H. Li, X. He, Z. Kang, H. Huang, Y. Liu, J. Liu, S. Lian, C.H. Tsang, X. Yang, S.T. Lee, Water-soluble fluorescent carbon quantum dots and photocatalyst design. Angew. Chem. 49, 4430 (2010)

    Article  CAS  Google Scholar 

  24. J. Peng, W. Gao, B.K. Gupta, Z. Liu, R. Romeroaburto, L. Ge, L. Song, L.B. Alemany, X. Zhan, G. Gao, Graphene quantum dots derived from carbon fibers. Nano Lett. 12, 844 (2012)

    Article  CAS  Google Scholar 

  25. R. Loukanov, M. Sekiya, N. Yoshikawa, Y. Kobayashi, S. Moriyasu, Nakabayashi, Photosensitizer-conjugated ultrasmall carbon nanodots as multifunctional fluorescent probes for bioimaging. J. Phys. Chem. C 120, 15869–15874 (2016)

    Article  Google Scholar 

Download references

Acknowledgements

The authors acknowledge the financial support from National Natural Sciences Foundation of China (Grants No. 51472183). The authors declare that they have no conflict of interest.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Weidong Xiang or Xiaojuan Liang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 266 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yuan, R., Liu, J., Xiang, W. et al. Red-emitting carbon dots phosphors: a promising red color convertor toward warm white light emitting diodes. J Mater Sci: Mater Electron 29, 10453–10460 (2018). https://doi.org/10.1007/s10854-018-9103-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-9103-3

Navigation