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A facile method to enhance electrochemical performance of high-nickel cathode material Li(Ni0.8Co0.1Mn0.1)O2 via Ti doping

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Abstract

The cycle stability of Li(Ni0.8Co0.1Mn0.1)O2 is enhanced obviously by titanium doping via a facile solid-state method. The property of crystal structure is evaluated by XRD, which illustrates the samples possessed a layered α-NaFeO2 structure with R-3m space group. According to the charge/discharge studies, the capacity retention of pristine sample is around 51% after 125 cycles at 5 C, and the sample with Ti dopant displays a good cyclic stability, after 125 cycles, the capacity retention increases to 75% under 5 C, suggesting it could be possibly applied in fast charge Lithium-ion battery area. The superb electrochemical performance might be attributed to the Ti4+ occupy the layer structure to broaden the Lithium-ion channel, which is benefit to lithium intercalation and deintercalation during cycling.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 1474057, 51774076 and 51704063) and the Fundamental Research Funds for the Central Universities (N162502003).

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Authors and Affiliations

  1. School of Metallurgy, Northeastern University, No. 3-11, Wenhua Road, Heping District, Shenyang, 110819, People’s Republic of China

    Jiawei Li, Ying Li & Peihua Ma

  2. Jiangsu Lithitech Co. Ltd, Changzhou, 213300, People’s Republic of China

    Yongnan Guo & Jiale Lv

  3. College of Chemistry, Chemical Engineering and Materials Science, Zaozhuang University, Zaozhuang, 277160, People’s Republic of China

    Wentao Yi

  4. College of Materials Science and Engineering, Hunan University, Changsha, 410082, People’s Republic of China

    Yongnan Guo

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  1. Jiawei Li
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  4. Jiale Lv
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  5. Wentao Yi
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Correspondence to Ying Li.

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Li, J., Li, Y., Guo, Y. et al. A facile method to enhance electrochemical performance of high-nickel cathode material Li(Ni0.8Co0.1Mn0.1)O2 via Ti doping. J Mater Sci: Mater Electron 29, 10702–10708 (2018). https://doi.org/10.1007/s10854-018-9093-1

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  • DOI: https://doi.org/10.1007/s10854-018-9093-1

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