Enhancing the structural, optical and magnetic properties of Cu₂O films deposited using a SILAR technique through Fe-doping

Abstract

Undoped and Ferrous (Fe)-doped Cu₂O thin films were deposited onto glass substrates using successive ionic layer adsorption and reaction method. The variation in the concentration of Fe has significant impact on the final film properties, Fe doping with 5 wt% exhibited major property improvements compared with undoped and Fe doped films. The structural, optical, morphological, magnetic properties and atomic force microscope of the films were systematically investigated. The X-ray diffraction analysis showed that all the films had good crystalline quality and the preferential orientation along (111) plane. Optical studies show that the transmittance and optical band-gap values are maximum (2.5 eV) for the Fe doping level of 5 wt%. The relative errors are calculated for crystallite size and optical energy band gap values. The photoluminescence study confirms the presence of various defects in the Cu₂O matrix. The Fourier transform infrared results confirmed the presence of expected compounds in the samples. The field emission-scanning electron microscope images indicate that there is a gradual decrease in the grain-size with increase in the Fe doping level and a flower-like structure is obtained in the maximum doping level of Fe. The high resolution transition electron microscope reveals single-crystal nature. Magnetic measurements showed that undoped Cu₂O films exhibit diamagnetic behavior and at the maximum (5 wt%) Fe doping level, the films behave as anti-ferromagnetic material. The atomic force microscope reveals that the smoothness of the film surface increases at the maximum doping of Fe concentration.