Synthesis and dielectric properties of Cr-substituted CeO2 nanoparticles

  • B. M. Harish
  • B. S. Avinash
  • V. S. Chaturmukha
  • H. S. Jayanna
  • Ashok R. Lamani
  • S. Yallappa


Chromium doped ceria nanoparticles have been synthesized by using a novel solution combustion method with chromium nitrate hexahydrate as oxidizers and glycine as a fuel. The main objective of the present study is to find the effect of chromium on structural, optical, dielectric properties and ac- conductivity of cerium oxide nanoparticles (CeO2 NPs). The prepared samples were characterized by various physicochemical techniques such as UV–Vis absorption spectra, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDS) analysis. The powder XRD patterns confirm the cubic fluorite structure of CeO2 NPs. The UV–Vis absorption spectra showed that the doping causes the red shift of absorption peaks. The optical band gap of all samples has been measured by Tauc plot, which is found to be decreases with chromium concentration. The uniform shaped NPs with the range of ~ 20 nm is observed by FESEM images. EDS analysis confirms the expected elemental composition of Ce1−xCrxO2 NPs. The dielectric constant ɛ′, dielectric loss factor (tanδ) and AC conductivity of the samples were studied as function of frequency range from 20 Hz to 3 MHz and found to be decreases with increasing the chromium content.



The authors are thankful to Madhusudhana R, Assistant professor, Centre for Nanotechnology, the National Institute of Engineering, Mysure for providing XRD, EDS and FESEM data’s.


  1. 1.
    A. Zia, S. Ahmed, N.A. Shah, M. Anis-ur-Rehman, E.U. Khan, M. Basit, Phys. B 473, 42 (2015)CrossRefGoogle Scholar
  2. 2.
    O. Gurbuz, M. Okutan, Appl. Surf. Sci. 387, 1211 (2016)CrossRefGoogle Scholar
  3. 3.
    D. Mangalam, D.M. Prabaharana, K. Sadaiyandib, M. Mahendran, S. Sagadevan, Mater. Res. 19(2), 478 (2016)CrossRefGoogle Scholar
  4. 4.
    A.I. Ali, A.H. Ammar, A. Abdel, Moez, Superlattices Microstruct. 65, 285 (2014)CrossRefGoogle Scholar
  5. 5.
    M. Gilliot, A. Hadjadj, J. Martin, Thin Solid Films. 597, 65 (2015)CrossRefGoogle Scholar
  6. 6.
    S.A. Ansari, A. Nisar, B. Fatma, W. Khan, A.H. Naqvi, Mater. Sci. Eng. B 177, 428 (2012)CrossRefGoogle Scholar
  7. 7.
    N.I. Santha, M.T. Sebastian, N.M. Alford, K. Sarma, R.C. Pullar, S. Kamba, A. Pashkin, P. Samukhina, J. Petzelt, J. Am. Ceram. Soc. 87, 1233 (2004)CrossRefGoogle Scholar
  8. 8.
    D.H. Kim, S.K. Lim, C. An, Mater. Lett. 52, 240 (2002)CrossRefGoogle Scholar
  9. 9.
    R. Zamiri, H.A. Ahangar, A. Kaushal, A. Zakaria, G. Zamiri, D. Tobaldi, J.M.F. Ferreira, PLoS ONE. 10 (2015)Google Scholar
  10. 10.
    R. Rangel, G.J. Lopez Mercado, P. Bartolo-Perez, R. Garcia, Sci. Adv. Mater. 4, 573 (2012)CrossRefGoogle Scholar
  11. 11.
    N. Rahemi, M. Haghighi, A.A. Babaluo, M.F. Jafari, P.J. Estifaee, Nanosci. Nanotechnol. 13, 4896 (2013)CrossRefGoogle Scholar
  12. 12.
    G. Cheng, J. Xiong, F.J. Stadler, Powder Technol. 249, 89 (2013)CrossRefGoogle Scholar
  13. 13.
    Y. Zhu, X. Quan, F. Chen, X. Fan, Y. Feng, Sci. Adv. Mater. 4, 119 (2012)Google Scholar
  14. 14.
    S. Tsunekawa, R. Sivamohan, T. Ohsuna, A. Kasuya, H. Takahashi, K. Tohji, Mater. Sci. Forum. 439, 315 (1999)Google Scholar
  15. 15.
    K.S. Ranjith, P. Saravanan, S. Chen, C. Dong, C.L. Chen, S. Chen, K. Asokan, R. Thangavelu, R. Kumar, J. Phys. Chem. C 118, 27039 (2014)CrossRefGoogle Scholar
  16. 16.
    T.K. Gupta, J. Am. Ceram. Soc 73, 1817 (1990)CrossRefGoogle Scholar
  17. 17.
    S. Bernik, N. Daneu, A. Recnik, J. Eur. Ceram. Soc 24, 3703 (2004)CrossRefGoogle Scholar
  18. 18.
    D.P. Norton, Y.W. Heo, M.P. Ivill, K. Ip, S.J. Pearton, M.F. Chisholm, T. Steiner, Mater. Today 7, 34 (2004)CrossRefGoogle Scholar
  19. 19.
    T. Watari, R.C. Bradt, J. Ceram. Soc. Jpn. 101, 1085 (1993)CrossRefGoogle Scholar
  20. 20.
    S. Bernik, P. Zupancic, D. Kolar, J. Eur. Ceram. Soc. 19, 709 (1999)CrossRefGoogle Scholar
  21. 21.
    S. Phokha, D. Prabhakaran, A. Boothroyd, S. Pinitsoontorn, S. Maensiri, Microelectron. Eng. 126, 93 (2014)CrossRefGoogle Scholar
  22. 22.
    S.K. Alla, E.V.P. Komarala, R.K. Mandal, N.K. Prasad, Mater. Chem. Phys. 182, 280 (2016)CrossRefGoogle Scholar
  23. 23.
    N.S. Ferreira, L.G. Abracado, M.A. Macedo, Phys. B 407, 3218 (2012)CrossRefGoogle Scholar
  24. 24.
    S. Phokha, S. Pinitsoontorn, S. Maensiri, J. Appl. Phys. 112, 113904 (2012)CrossRefGoogle Scholar
  25. 25.
    S.-Y. Chen, C.-H. Tsai, M.-Z. Huang, D.-C. Yan, T.-W. Huang, A. Gloter, C.L. Chen, H.-J. Lin, C.-T. Chen, C.-L. Dong, J. Phys. Chem. C 116, 8707 (2012)CrossRefGoogle Scholar
  26. 26.
    R.D. Purohit, B.P. Sharma, K.T. Pillai, A.K. Tyagi, J. Mat. Res. Bull. 36, 2711 (2001)CrossRefGoogle Scholar
  27. 27.
    M. Hirano, M. Inagaki, J. Mater. Chem. 10, 473 (2000)CrossRefGoogle Scholar
  28. 28.
    S. Yang, L. Gao, J. Am. Chem. Soc. 128, 933 (2006)Google Scholar
  29. 29.
    H. Xiao, Z. Ai, L. Zhang, J. Phys. Chem. C 113, 16625 (2009)CrossRefGoogle Scholar
  30. 30.
    L. Yin, Y. Wang, G. Pang, Y. Koltypin, A. Gedanken, J. Colloid Interface Sci. 246, 78 (2002)CrossRefGoogle Scholar
  31. 31.
    S. Anushree, C. Kumar, Sharma, Mater. Chem. Phys. 155, 223 (2015)CrossRefGoogle Scholar
  32. 32.
    Y.Q. Song, H.W. Zhang, Q.Y. Wen, J. Appl. Phys. 102, 043912 (2007)CrossRefGoogle Scholar
  33. 33.
    A. Sundaresan, R. Bhargavi, N. Rangarajan, U. Siddesh, C.N.R. Rao, Phys. Rev. B 74, 161306 (2006)CrossRefGoogle Scholar
  34. 34.
    Q.-Y. Wen, H.-W. Zhang, Y.-Q. Song, Q.-H. Yang, H. Zhu, J.Q. Xiao, J. Phys. 19, 246205 (2007)Google Scholar
  35. 35.
    S.K. Alla, R.K. Mandal, N.K. Prasad, RSC Adv. 105, 102821 (2016)Google Scholar
  36. 36.
    Newtons 4th Ltd., Frequency response analyzer, guide to PSM1735—IAI compensation, guide to IAI Calibration (2008)Google Scholar
  37. 37.
    L.B. Kong, Z.W. Li, G.Q. Lin, Y.B. Gan, Acta Mater. 55, 6561 (2007)CrossRefGoogle Scholar
  38. 38.
    V.L. Mathe, K. Patankar, S.D. Lotke, P.B. Joshi, S.A. Patil, Bull. Mater. Sci. 25, 347 (2002)CrossRefGoogle Scholar
  39. 39.
    G. Rana, U.C. Johri, K. Asokan, Euro. Phys. Lett. 103, 17008 (2013)CrossRefGoogle Scholar
  40. 40.
    S. Sagadevan, Am. J. Nanosci. Nanotechnol. 1, 27 (2013)CrossRefGoogle Scholar
  41. 41.
    Y.S. Asar, T. Asar, S. Altındal, S. Özçelik, J. Alloy. Compd. 628, 442 (2015)CrossRefGoogle Scholar
  42. 42.
    H. Young, Y. Lin, H. Wang, F. Luo, Mater. Manuf. Process. 23, 489 (2008)CrossRefGoogle Scholar
  43. 43.
    O. Gürbüz, M. Okutan, Appl. Surf. Sci. 387, 1211 (2016)CrossRefGoogle Scholar
  44. 44.
    X. Li, Y. Huang, L. Xu, L. Liu, Y. Wang, X. Cao, C. Meng, Z. Wang, Mater. Res. Bull. 68, 87 (2015)CrossRefGoogle Scholar
  45. 45.
    M. Ashokkumar, S. Muthukumaran, J. Magn. Magn. Mater. 374, 61 (2015)CrossRefGoogle Scholar
  46. 46.
    M. Okutan, Y. Yerli, S.E. San, F. Yılmaz, O. Günaydın, M. Durak, Synth. Met. 157, 368 (2007)CrossRefGoogle Scholar
  47. 47.
    N. Jahan, A.K.M. Zakaria, F.-U.-Z. Chowdhury, S. Aktar, S.M. Yunus, D.K. Saha, M.N.I. Khan, in Proceedings of International Conference on Advances in Physics (2015)Google Scholar
  48. 48.
    R.V. Mangalaraja, P. Manohar, F.D. Gnanam, J. Mater. Sci. 39, 2037 (2004)CrossRefGoogle Scholar
  49. 49.
    A. Azam, A.S. Ahmed, M. Chaman, A.H. Naqvi, J. Appl. Phys. 108, 6 (2010)CrossRefGoogle Scholar
  50. 50.
    A. Tataroglu, S. Altındal, M.M. Bulbul, Microelectron. Eng. 81, 140 (2005)CrossRefGoogle Scholar
  51. 51.
    H. MahmoudiChenari, M.M. Golzan, H. Sedghi, A. Hassanzadeh, M. Talebian, Curr. Appl. Phys. 11, 1071 (2011)CrossRefGoogle Scholar
  52. 52.
    A.M.M. Farea, S. Kumar, K.M. Batoo, Y. Ali, Physica B 403, 684 (2008)CrossRefGoogle Scholar
  53. 53.
    K.M. Batoo, S. Kumar, C.G. Lee, Curr. Appl. Phys. 9, 107 (2009)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • B. M. Harish
    • 1
  • B. S. Avinash
    • 1
  • V. S. Chaturmukha
    • 1
  • H. S. Jayanna
    • 1
  • Ashok R. Lamani
    • 1
  • S. Yallappa
    • 2
  1. 1.Department of P.G. studies and Research in PhysicsKuvempu UniversityShimogaIndia
  2. 2.Department of ChemistryGokhale Centenary CollegeAnkola, Uttara KannadaIndia

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