Skip to main content
Log in

Flexible single walled nanotube based chemical sensor for 2,4-dinitrotoluene sensing

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this work, we have attempted to fabricate flexible single walled carbon nanotube based sensor for detection of 2,4-dinitrotoluene (DNT) an explosive chemical. For analyte sensing study, the flexible sensor is fabricated by vacuum filtration method. These fabricated gas sensors are characterised by SEM and Raman spectroscopy. The sensor response is investigated toward the explosive chemicals which have NO2 group in their molecular structure. The fabricated sensor is able to detect the traces of DNT at room temperature. The sensor gives 0.28–0.32% repeatable response to 0.22 ppm of DNT. The response of sensor increases with increase in the vapour concentration of the DNT vapours.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. https://www.nap.edu/read/10968/chapter/6#42. Accessed 28 Jul 2017

  2. F. Hincal, P. Erkekoglu, Toxic industrial chemicals (TICs)-chemical warfare without chemical weapons. FABAD J. Pharm. Sci. 31, 220–229 (2006)

    Google Scholar 

  3. X. Sun, Y. Wang, Y. Lei, Fluorescence based explosive detection: from mechanisms to sensory materials. Chem. Soc. Rev. 44, 8019–8061 (2015)

    Article  Google Scholar 

  4. M. Marshall, J.C. Oxley, Aspects of Explosives Detection (Elsevier, Amsterdam, 2011)

    Google Scholar 

  5. K.L. Gares, K.T. Hufziger, S.V. Bykov, S.A. Asher, Review of explosive detection methodologies and the emergence of standoff deep UV resonance Raman. J. Raman Spectrosc. 47, 124–141 (2016)

    Article  Google Scholar 

  6. M.J. Lefferts, M.R. Castell, Vapour sensing of explosive materials. Anal. Methods 7, 9005–9017 (2015)

    Article  Google Scholar 

  7. L.W. Burgess, Absorption-based sensors. Sens Actuators B 29, 10–15 (1995)

    Article  Google Scholar 

  8. X. Liu, S. Cheng, H. Liu, S. Hu, D. Zhang, H. Ning, A survey on gas sensing technology. Sensors 12, 9635–9665 (2012)

    Article  Google Scholar 

  9. D.J. Wales, J. Grand, V.P. Ting, R.D. Burke, K.J. Edler, C.R. Bowen, S. Mintova, A.D. Burrows, Gas sensing using porous materials for automotive applications. Chem. Soc. Rev. 44, 4290–4321 (2015)

    Article  Google Scholar 

  10. Y.-F. Sun, S.-B. Liu, F.-L. Meng, J.-Y. Liu, Z. Jin, L.-T. Kong, J.-H. Liu, Metal oxide nanostructures and their gas sensing properties: a review. Sensors 12, 2610–2631 (2012)

    Article  Google Scholar 

  11. D.A. Stuart, K.B. Biggs, R.P. Van Duyne, Surface-enhanced Raman spectroscopy of half-mustard agent. Analyst 131, 568–572 (2006)

    Article  Google Scholar 

  12. T.H. Kim, B.Y. Lee, J. Jaworski, K. Yokoyama, W.-J. Chung, E. Wang, S. Hong, A. Majumdar, S.-W. Lee, Selective and sensitive TNT sensors using biomimetic polydiacetylene-coated CNT-FETs. ACS Nano 5, 2824–2830 (2011)

    Article  Google Scholar 

  13. D.S. Moore, Instrumentation for trace detection of high explosives. Rev. Sci. Instrum. 75, 2499–2512 (2004)

    Article  Google Scholar 

  14. H.H. Choi, J. Lee, K.-Y. Dong, B.-K. Ju, W. Lee, Gas sensing performance of composite materials using conducting polymer/single-walled carbon nanotubes. Macromol. Res. 20, 143–146 (2012)

    Article  Google Scholar 

  15. M. Sagar, R. Mudhalwadkar, G. Sonar, Metal oxide semiconductor based thin film sensor for nitro aromatic explosive detection. in 2014 International Conference for Convergence of Technology (I2CT), IEEE, pp. 1–4

  16. O.K. Kannan, R. Bhalla, J.C. Kapoor, A.T. Nimal, U. Mittal, R.D.S. Yadava, Detection of landmine signature using SAW-based polymer-coated chemical sensor. Def. Sci. J. 54, 309 (2004)

    Article  Google Scholar 

  17. T. Caron, S. Clavaguera, M. Huron, P. Montméat, E. Pasquinet, J.-P. Lére-Porte, F. Serein-Spirau, F. Perraut, P. Prené, Detection of explosive vapors: development and performances of a fluorescence sensor. Chem. Eng. Trans. 23, 25–30 (2010)

    Google Scholar 

  18. A.D. Aguilar, E.S. Forzani, M. Leright, F. Tsow, A. Cagan, R.A. Iglesias, L.A. Nagahara, I. Amlani, R. Tsui, N.J. Tao, A hybrid nanosensor for TNT vapor detection. Nano Lett. 10, 380–384 (2009)

    Article  Google Scholar 

  19. P.C. Chen, S. Sukcharoenchoke, K. Ryu, L. Gomez de Arco, A. Badmaev, C. Wang, C. Zhou, 2, 4, 6-Trinitrotoluene (TNT) chemical sensing based on aligned single-walled carbon nanotubes and ZnO nanowires. Adv. Mater. 22, 1900–1904 (2010)

    Article  Google Scholar 

  20. J.A. Robinson, E.S. Snow, F.K. Perkins, Improved chemical detection using single-walled carbon nanotube network capacitors. Sens. Actuators A 135, 309–314 (2007)

    Article  Google Scholar 

  21. S. Hrapovic, E. Majid, Y. Liu, K. Male, J.H.T. Luong, Metallic nanoparticle-carbon nanotube composites for electrochemical determination of explosive nitroaromatic compounds. Anal. Chem. 78, 5504–5512 (2006)

    Article  Google Scholar 

  22. S.K. Sharma, N. Kaur, J. Singh, S. Sankar, S.S. Gaur, S. Lee, D.Y. Kim, N. Singh, H. Singh, Electrochemical sensitive determination of nanomolar guanine from ZnO nanorods coated on platinum electrode. Electroanalysis 27, 2537–2543 (2015)

    Article  Google Scholar 

  23. N. Kaur, J. Singh, P. Raj, N. Singh, H. Singh, S.K. Sharma, D.Y. Kim, N. Kaur, ZnO decorated with organic nanoparticles based sensor for the ratiometric selective determination of mercury ions. New J. Chem. 40, 1529–1534 (2016)

    Article  Google Scholar 

  24. S.K. Sharma, N. Kaur, J. Singh, A. Singh, P. Raj, S. Sankar, D.Y. Kim, N. Singh, N. Kaur, H. Singh, Salen decorated nanostructured ZnO chemosensor for the detection of mercuric ions (Hg2+). Sens. Actuators B 232, 712–721 (2016)

    Article  Google Scholar 

  25. Y. Wang, J.T.W. Yeow, A review of carbon nanotubes-based gas sensors. J. Sens. 2009, 24 (2009)

    Article  Google Scholar 

  26. D. Kumar, P. Chaturvedi, P. Saho, P. Jha, A. Chouksey, M. Lal, J. Rawat, R.P. Tandon, P.K. Chaudhury, Effect of single wall carbon nanotube networks on gas sensor response and detection limit. Sens Actuators B 240, 1134–1140 (2017)

    Article  Google Scholar 

  27. D. Kumar, P. Chaturvedi, A. Chouksey, P. Jha, J. Rawat, R.P. Tandon, P.K. Chaudhury, Highly sensitive NO2 detection and DMPP sensing at room temperature using flexible SWNT thick film sensor. Def. Sci. J. 66, 413–420 (2016)

    Article  Google Scholar 

  28. R. Tang, Y. Shi, Z. Hou, L. Wei, Carbon nanotube-based chemiresistive sensors. Sensors 17, 882 (2017)

    Article  Google Scholar 

  29. D. Kumar, I. Kumar, P. Chaturvedi, A. Chouksey, R.P. Tandon, P.K. Chaudhury, Study of simultaneous reversible and irreversible adsorption on single-walled carbon nanotube gas sensor. Mater. Chem. Phys. 177, 276–282 (2016)

    Article  Google Scholar 

  30. W.C. Trogler, M.J. Sailor, Detection of nitrobenzene, DNT, and TNT vapors by quenching of porous silicon photoluminescence. Chem.-A Eur. J. 6, 2205–2213 (2000)

    Article  Google Scholar 

  31. M.S. Dresselhaus, G. Dresselhaus, R. Saito, A. Jorio, Raman spectroscopy of carbon nanotubes. Phys. Rep. 409, 47–99 (2005)

    Article  Google Scholar 

  32. S. Costa, E. Borowiak-Palen, M. Kruszynska, A. Bachmatiuk, R.J. Kalenczuk, Characterization of carbon nanotubes by Raman spectroscopy. Mater. Sci. 26, 433–441 (2008)

    Google Scholar 

  33. K. Chikkadi, M. Muoth, W. Liu, V. Maiwald, C. Hierold, Enhanced signal-to-noise ratio in pristine, suspended carbon nanotube gas sensors. Sens. Actuators B 196, 682–690 (2014)

    Article  Google Scholar 

  34. S.J. Toal, W.C. Trogler, Polymer sensors for nitroaromatic explosives detection. J. Mater. Chem. 16, 2871–2883 (2006)

    Article  Google Scholar 

  35. T. Ohba, S. Yamamoto, T. Kodaira, K. Hata, Changing water affinity from hydrophobic to hydrophilic in hydrophobic channels. Langmuir 31, 1058–1063 (2015)

    Article  Google Scholar 

Download references

Acknowledgements

Authors gratefully acknowledge Dr. R. K. Sharma, Director, Solid State Physics Laboratory for the guidance and permission to publish the work and characterization group of Solid State Physics Laboratory for their kind help in sample characterization.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Deepak Kumar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kumar, D., Jha, P., Chouksey, A. et al. Flexible single walled nanotube based chemical sensor for 2,4-dinitrotoluene sensing. J Mater Sci: Mater Electron 29, 6200–6205 (2018). https://doi.org/10.1007/s10854-018-8595-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-8595-1

Navigation