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Investigations on synthesis, growth and physicochemical properties of semi-organic nonlinear optical crystal: l-arginine sodium nitrate


Single crystals of l-arginine sodium nitrate semiorganic nonlinear optical crystal were grown by slow evaporation process at room temperature. The single crystal X-ray diffraction study confirms that the unit cell parameters of the grown l-arginine sodium nitrate crystal. Fourier transform infrared spectrum analysis was used to identify the functional groups of the grown crystal. The thermal stability of the l-arginine sodium nitrate was determined using thermogravimetric analysis and differential thermal analysis. The linear optical property of LARSN crystal has been studied using Ultraviolet–visible spectroscopy studies in the wavelength range 200–800 nm. The relative second harmonic efficiency of the l-arginine sodium nitrate compound is found to be 0.49 times that of Potassium Di-hydrogen phosphate. The mechanical property of the grown crystals was determined by Vicker’s micro hardness test and it proved the hard nature of the grown crystal. Dielectric study reveals that both dielectric constant and dielectric loss decreases with increase in frequency.

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  1. H. Nalwa, S. Miyata, Nonlinear Optics of Organic Molecules and Polymers (CRC Press, Tokyo, 1997)

    Book  Google Scholar 

  2. P.A. Franken, A. Hill, C.W. Peters, G. Weinrich, Generation of optical harmonics. Phys. Rev. Lett. 7, 118–119 (1961)

    Article  Google Scholar 

  3. A.A. Chernov, Modern Crystallography III-Crystal Growth, Solid State Series 36, (Springer, Berlin, 1984)

    Google Scholar 

  4. J.C. Brice, The Growth of Crystals from Liquids (Wiley, New York, 1972)

    Google Scholar 

  5. H.K. Henisch, Crystals in Gels and Liesegang rings (Cambridge Univ. Press, USA, 1988)

    Book  Google Scholar 

  6. R. Ittyachan, P. Sagayaraj, Growth and characterization of L-arginine diphosphate crystal. J. Cryst. Growth 243, 356–360 (2002)

    Article  Google Scholar 

  7. K. Ramya, C. Ramachandra Raja, Studies on the growth and characterization of L-Arginine Maleate Dihydrate crystal grown from liquid diffusion technique. J. Miner. Mater. Charact. Eng. 4, 143–153 (2016)

    Google Scholar 

  8. P. Jayaprakash, P. Sangeetha, M. Peer Mohamed, G. Vinitha, S. Muthu, M. Prakash, M. Lydia Caroline, Growth and characterization of DL-Mandelic acid (C6H5CH(OH)CO2H) single crystal for third-order nonlinear optical applications. J. Mol. Struct. 1148, 314–321 (2017)

    Article  Google Scholar 

  9. C. Rathika Thaya Kumari, P. Jayaprakash, M. Nageshwari, M. Peer Mohamed, P. Sangeetha, M. Lydia Caroline, Growth, optical, photoluminescence, dielectric, second and third order nonlinear optical studies of benzoyl valine acentric crystal, Taylor & Francis, Mol. Cryst. Liq. Cryst. 658 186–197 (2017)

    Article  Google Scholar 

  10. P. Jayaprakash, P. Sangeetha, C. Rathika Thaya Kumari, M. Lydia, Caroline, Investigation on the growth, spectral, lifetime, mechanical analysis and third-order nonlinear optical studies of L-methionine admixtured D-mandelic acid single crystal: a promising material for nonlinear optical applications. Physica B 518, 1–12 (2017)

    Article  Google Scholar 

  11. P. Sangeetha, P. Jayaprakash, M. Nageshwari, C. Rathika Thaya Kumari, S. Sudha, M. Prakash, G. Vinitha, M. Lydia Caroline, Growth and characterization of an efficient new NLO single crystal L-phenylalanine D-methionine for frequency conversion and optoelectronic applications. Physica B 525, 164–174 (2017)

    Article  Google Scholar 

  12. A.S. Hassanien, A.A. Akl, Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films. Superlattices Microstruct. 89, 153–169 (2016)

    Article  Google Scholar 

  13. P. Jayaprakash, P. Sangeetha, C. Rathika Thaya Kumari, I. Baskaran, M. Lydia, Caroline, Growth and characterization of L-asparagine monohydrate admixtured DL-mandelic acid nonlinear optical single crystal. J. Mater. Sci.: Mater. Electron. 28, 18787–18794 (2017)

    Google Scholar 

  14. P. Jayaprakash, M. Peer Mohamed, P. Krishnan, M. Nageshwari, G. Mani, M. Lydia Caroline, Growth, spectral, thermal, laser damage threshold, microhardness, dielectric, linear and nonlinear optical properties of an organic single crystal: L-phenylalanine DL-mandelic acid. Physica B 503, 25–31 (2016)

    Article  Google Scholar 

  15. A.S. Hassanien, Studies on dielectric properties, opto-electrical parameters and electronic polarizability of thermally evaporated amorphous Cd50S50-xSex thin films, J. Alloys Compd. 671, 566–578(2016).

    Article  Google Scholar 

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The Corresponding author sincerely thank to University Grant Commission (UGC), New Delhi, for funding research project (Ref No: F.NO:4-4/2015-16 (MRP/UGC-SERO).

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Correspondence to R. Ravisankar.

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Varalakshmi, S., Jayaprakash, P., Eswaran, P. et al. Investigations on synthesis, growth and physicochemical properties of semi-organic nonlinear optical crystal: l-arginine sodium nitrate. J Mater Sci: Mater Electron 30, 1885–1890 (2019).

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