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Aligned polyaniline/porous biomass carbon composites with superior microwave absorption properties

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Abstract

Hierarchical structure composites of loofah derived biomass carbon (PBC) decorated by aligned polyaniline (PANI) were successfully fabricated by simple carbonization and in situ oxidative polymerization. The morphology and structural of composites was studied. The microwave absorbing performance of aligned PANI/PBC was investigated in the frequency range of 2–18 GHz. The results indicated that aligned PANI/PBC with special structure possessed more distinct dielectric response characteristics and enhanced microwave absorbing performance. The minimum reflection loss (RL) value of aligned PANI/PBC was up to − 44.8 dB at 10.02 GHz and the effective absorption frequency width (RL < − 10 dB) is in the 5.58–18 GHz range with the thickness range of 1–3 mm. The excellent microwave absorbing performance of aligned PANI/PBC was mainly correlate with the multiple relaxation polarization, good impedance matching and the synergistic effect between PANI nanorods and PBC.

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Acknowledgements

This work was supported by National Natural Science Foundation of China (No. 51503183); Key Program for International Science and Technology Cooperation Projects of Ministry of Science and Technology of China (No. 2016YFE0125900); Program for Innovative Research Team of Zhejiang Sci-Tech University (15010039-Y).

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Authors and Affiliations

  1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, 310018, Zhejiang, China

    Qixin Yang, Wentong Yang, Yiyuan Shi, Lujun Yu, Xiang Li, Laiming Yu, Yubing Dong, Yaofeng Zhu & Yaqin Fu

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  1. Qixin Yang
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  2. Wentong Yang
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  3. Yiyuan Shi
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  4. Lujun Yu
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Correspondence to Yaofeng Zhu.

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Yang, Q., Yang, W., Shi, Y. et al. Aligned polyaniline/porous biomass carbon composites with superior microwave absorption properties. J Mater Sci: Mater Electron 30, 1374–1382 (2019). https://doi.org/10.1007/s10854-018-0407-0

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