Abstract
In this present study, the photovoltaic, structural, elemental and optical properties of La-alloyed CdS quantum dots (QDs) synthesized at room temperature using the successive ionic layer adsorption and reaction (SILAR) technique were investigated for the first time. For La-alloyed CdS QDs with different La concentrations, incident photons to current efficiency (IPCE) was measured and the optimum La concentration giving the best solar cell efficiency was determined as 1%. Characterization procedures were then performed to determine the structural and optical properties of La-alloyed CdS QDs with 1% La. As a result, La-alloyed CdS QDs with 1% La have been proposed as promising materials for photovoltaic applications.
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K. Das, S.N. Sharma, M. Kumar, S.K. De, Morphology dependent luminescence of co-doped TiO2 nanostructures. J. Phys. Chem. C 113, 14783 (2009)
C. Wang, C. Bottcher, D.W. Bahnemann, J.K. Dohrmann, A comparative study of nanometer sized Fe (III) doped TiO2 photocatalyst: synhtesis, characterizaqtion and activity. J. Mater. Chem. 13, 2322 (2003)
H.R. Rajabi, M. Farsi, Effect of transition metal ion doping on the photocatalytic activity of ZnS quantum dots: synthesis, characterization ana application for dye decolarization. J Mol. Catal. A 339, 53 (2015)
T. Li, X. Zou, H. Zhou, Effect of doping on properties of CdS quantum dot-sensitized solar cells. Int. J. Photogener. 2014, 569763 (2014)
S. Horoz, Q. Dai, B.R. Yakami, J.M. Pikal, X. Zhang, J. Wang, W. Wang, J. Tang, Absorption induced by mn doping of ZnS for improved sensitized qunatum dot solar cells. Phys. Rev. Appl. 3, 024011 (2015)
A. Singh, A. Singh, J. Ciston, R. Bustillo, D. Nordlund, D.J. Milliron, Synergistic role of dopants on the morphology of alloyed copper nanocrystals. J. Am. Chem. Soc. 137, 646 (2015)
E. Gurbuz, R. Aydin, B. Şahin., A study of the influence of transition metal (Ni, Mn) co dopin on the morphological, structural ana optical properties of nanostructured CdO films. J Mater. Sci.: Mater. Sci. 28, 1 (2017)
W. Lee, W.C. Kwak, S.K. Min, J.C. Lee, W.S. Chae, Y.M. Sumg, S.H. Han, Spectral broadening in quantum dots-senstized photochemical solar cells based on CdSe and Mg-doped CdSe nanocrytals. Electrochem. Commun. 10, 1699 (2008)
J.W. Lee, D.Y. Son, T.K. Ahn, H.W. Shin, I.Y. Kim, S.J. Hwang, M.J. Ko, S. Sul, H. Han, N.G. Park, Quantum-dot-sensitized solar cell with unprecedentedly high photocurrent. Sci. Rep. 3, 1050 (2013)
Z. Huang, X. Zou, H. Zhou, A strategy to achieve superior photocurrent by Cu-doped quantum dot sensitized solar cells. Mater. Lett. 95, 139 (2013)
L. Li, X. Zou, H. Zhou, G. Teng, Cu-doped-CdS/In-doped CdS sensitized quantum dot solar cells. J Nanomater. 2014, 314386 (2014)
N. Yao, J. Huang, K. Fu, X. Deng, M. Ding, X. Xu, Rare-earth ion doped phospor for dye-sensitized solar cells applications. RSC Adv. 6, 17546 (2016)
W. Wang, X. Li, D. Chi, H. Zhang, X. Liu, Lanthanide-doped unconversion materials: emerging applications for photovoltaics ana photocatalysis. Nanotechnology 25, 482001 (2014)
J. Wu, G. Xie, J. Lin, Z. Lan, M. Huang, Y. Huang, Enhancing photoelectrical performance of dye-sensitized solar cells by doping with europium doped yttria rare-earth oxide. J. Power Source 195, 6937 (2010)
J. Wu, J. Wang, J. Lin, Y. Xiao, G. Yue, M. Huang, Z. Lan, Y. Huang, L. Fan, S. Yin, T. Sato, Dual functions of YF3: Eu3+ for improving photovoltaic performance of dye-sensitized solar cells. Sci. Rep. 3, 2058 (2013)
S. Horoz, O. Sahin, Synthesis, chracterization and photovoltaic properties of Cr-doped CdS QDs. J. Mater. Sci.: Mater. Sci. 28, 17784 (2017)
P. Srivastava, P. Kumar, K. Singh, Room temperature ferromagnetism in magic-sized Cr-doped diluted magnetic semiconductor quantum dots. J. Nanopart. Res. 13, 5077 (2011)
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Dr. Sabit Horoz declares that he has no conflict of interest.
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Ekinci, A., Sahin, O. & Horoz, S. Characterization of La-alloyed CdS QDs synthesized by the successive ionic layer adsorption and reaction (SILAR) technique. J Mater Sci: Mater Electron 29, 5233–5238 (2018). https://doi.org/10.1007/s10854-017-8488-8
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DOI: https://doi.org/10.1007/s10854-017-8488-8