Abstract
In this study, we have synthesized Sr(PO3)2 glasses non-doped and doped with Ce (0.01, 0.05, 0.1, 1.0 and 3.0 mol%) prepared by the conventional melt-quenching method and investigated the optical properties [transmittance spectra, photoluminescence (PL) spectra, PL excitation spectra and PL decay times], scintillation properties with X-rays (scintillation spectra, scintillation decay times) and thermally-stimulated luminescence (TSL) properties (glow curves and dose response functions). The PL spectrum of the Ce-doped samples consist of an intense emission band due to the 5d–4f transitions of Ce3+ ion peaking at 350 nm. The decay time of the corresponding emission was 32–37 ns depending on the Ce concentration. The samples also showed scintillation with X-ray having a spectrum of an intense emission band peaking at 350 nm due to the Ce3+ ions, and decay time was 34–217 ns. The TSL glow peaks were observed at 190 and 450 °C for the Ce-doped glasses, and the dynamic range was confirmed at least over a three orders of magnitude 100–103 mGy.
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Acknowledgements
This work was supported by Grant-in-Aid for Scientific Research (A) (17H01375), Grant-in-Aid for Young Scientists (B) (17K14911) and Grant-in-Aid for Research Activity Start-up (16H06983, 17H06867) from the Ministry of Education, Culture, Sports, Science and Technology of the Japanese government (MEXT) as well as A-STEP from Japan Science and Technology Agency (JST). The Cooperative Research Project of Research Institute of Electronics, Shizuoka University, Mazda Foundation, Konica Minolta Science and Technology Foundation, NAIST Foundation and TEPCO Memorial Foundation are also acknowledged.
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Samizo, H., Kato, T., Kawano, N. et al. Photoluminescence, scintillation and TSL properties of Ce-doped Sr(PO3)2 glasses. J Mater Sci: Mater Electron 29, 1985–1991 (2018). https://doi.org/10.1007/s10854-017-8109-6
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DOI: https://doi.org/10.1007/s10854-017-8109-6