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Tl2S–Ga2S3–GeS2 glasses for optically operated laser third harmonic generation

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Abstract

We have shown a possibility to apply Tl2S–Ga2S3–GeS2 glasses as an effective photoinduced third harmonic generation materials. As a photoinducing beam, the 200 mW green laser at 532 nm was used. The 15 ns pulsed Nd:YAG laser with power density tuned up to 800 MW/cm2 was used. Glass-formation region in the quasi-ternary system Tl2S–Ga2S3–GeS2 was investigated by quenching molten alloys from 1300 K. The minimum concentration of the glass-forming agent GeS2 is 30 mol%. Characteristic thermal parameters and optical absorption spectra of the glasses of the system were investigated. The variations of the bandgap energy were determined. It is crucial that the photoinducing beam was excited in the bulk of the materials and the output third harmonic generation signal was observed for the 355 nm beam formed near the surface.

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Acknowledgements

The authors are grateful to the Deanship of Scientific Research, King Saud University for funding through Vice Deanship of Scientific Research Chairs.

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Eastern European National University, 13 Voli Avenue, Lutsk, 43025, Ukraine

    O. V. Tsisar, L. V. Piskach, O. V. Parasyuk, L. P. Marushko & I. D. Olekseyuk

  2. Department of Experimental Physics, Eastern European National University, Lutsk, Ukraine

    O. V. Zamuruyeva

  3. Institute of Optoelectronics and Measuring Systems, Faculty of Electrical Engineering, Czestochowa University of Technology, Armii Krajowej 17, Czestochowa, Poland

    P. Czaja

  4. Department of Optoelectronics, Silesian University of Technology, ul.B.Krzywoustego 2, 44-100, Gliwice, Poland

    P. Karasiński

  5. Physics Department, Faculty of Science, Ain Shams University, Abbasia, Cairo, 11566, Egypt

    A. M. El-Naggar & A. A. Albassam

  6. Research Chair of Exploitation of Renewable Energy Applications in Saudi Arabia, Physics & Astronomy Department, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia

    A. M. El-Naggar

  7. Wireless and Photonic Networks Research Centre, Faculty of Engineering, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia

    G. Lakshminarayana

Authors
  1. O. V. Tsisar
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  2. L. V. Piskach
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  3. O. V. Parasyuk
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  4. L. P. Marushko
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  5. I. D. Olekseyuk
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  6. O. V. Zamuruyeva
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  7. P. Czaja
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  8. P. Karasiński
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  9. A. M. El-Naggar
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  10. A. A. Albassam
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  11. G. Lakshminarayana
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Corresponding author

Correspondence to G. Lakshminarayana.

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Tsisar, O.V., Piskach, L.V., Parasyuk, O.V. et al. Tl2S–Ga2S3–GeS2 glasses for optically operated laser third harmonic generation. J Mater Sci: Mater Electron 28, 19003–19009 (2017). https://doi.org/10.1007/s10854-017-7854-x

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  • DOI: https://doi.org/10.1007/s10854-017-7854-x

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