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Novel flexible coaxial nanoribbons arrays to help achieve tuned and enhanced simultaneous multicolor luminescence–electricity–magnetism trifunctionality

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Abstract

Flexible color-tunable coaxial nanoribbons array endowed with electricity and magnetism is obtained via coaxial electrospinning. Every single coaxial nanoribbon is composed of Fe3O4 nanoparticles (NPs)/polyaniline(PANI)/polymethylmethacrylate (PMMA) conductive-magnetic bifunctional core and [Eu(TTA)3(TPPO)2+Tb(TTA)3(TPPO)2]/PMMA [TTA = 2-Thenoyltrifluoroacetone radical, TPPO = tris(N,N-tetramethylene)phosphoric acid triamide] insulative-photoluminescent shell. In the coaxial nanoribbons array, the fluorescent color is adjustable in the range of green–yellow–red via modulating the mass ratios of RE(TTA)3(TPPO)2, (RE = Eu, Tb), PANI and Fe3O4 NPs, and changing excitation wavelength. The coaxial nanoribbons array possesses more excellent luminescent performance than the counterpart composite nanoribbons array. For the core of coaxial nanoribbons, the highest electrical conductivity reaches 3.152 × 10−2 S cm−1. Magnetism and electricity of the coaxial nanoribbons array can be tuned. Design philosophy and fabrication method provide a novel and facile strategy toward other nanomaterials with multifunctionality.

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Acknowledgements

This work was financially supported by National Natural Science Foundation of China (51573023, 50972020), Natural Science Foundation of Jilin Province of China (20170101101JC), the Open Project Program of Key Laboratory of Preparation and Application of Environmentally Friendly Materials (Jilin Normal University), Ministry of Education, China (No. 2017003), Industrial Technology Research and Development Project of Jilin Province Development and Reform Commission (2017C051), Science and Technology Research Planning Project of the Education Department of Jilin Province during the 13th Five-Year Plan Period (JJKH20170608KJ), Youth Foundation of Changchun University of Science and Technology (No. XQNJJ-2016-01).

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Authors and Affiliations

  1. Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, Changchun University of Science and Technology, Changchun, 130022, China

    Hong Shao, Qianli Ma, Wensheng Yu, Xinlu Wang, Xiangting Dong, Zhelin Liu, Jinxian Wang & Guixia Liu

  2. Key Laboratory of Preparation and Application of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, 130103, China

    Xiangting Dong & Limin Chang

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  1. Hong Shao
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  2. Qianli Ma
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  3. Wensheng Yu
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  4. Xinlu Wang
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  5. Xiangting Dong
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  9. Limin Chang
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Correspondence to Xiangting Dong.

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Shao, H., Ma, Q., Yu, W. et al. Novel flexible coaxial nanoribbons arrays to help achieve tuned and enhanced simultaneous multicolor luminescence–electricity–magnetism trifunctionality. J Mater Sci: Mater Electron 28, 16762–16775 (2017). https://doi.org/10.1007/s10854-017-7591-1

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