Structural and dielectric properties of Pb(1−x)(Na0.5Sm0.5) x TiO3 ceramics

Abstract

A correlation between structure and vibrational properties related to a ferroelectric to paraelectric phase transition in perovskite Pb(1−x)(Na0.5Sm0.5) x TiO3 (0 ≤ x ≤ 0.5) (PNST-x) polycrystalline powders is discussed. Substitution leads to reduction of tetragonality which is associated with a shift of the phase transition to lower temperatures. The nature of the phase transition gets diffused with increasing substitution.

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Acknowledgements

One of the authors Arun Kumar Yadav is grateful to the university Grants Commission to award me fellowship (NFO-2015-17-OBC-UTT-28455).Principle investigator expresses sincere thanks to Indian Institute of Technology, Indore for funding the research and also using the Sophisticated Instrument Centre (SIC) for the research. The authors thank to Mr. Rituraj Sharma for providing the HR Raman facility in IISER Bhopal.

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Correspondence to Somaditya Sen.

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Yadav, A.K., Anita, Kumar, S. et al. Structural and dielectric properties of Pb(1−x)(Na0.5Sm0.5) x TiO3 ceramics. J Mater Sci: Mater Electron 28, 10730–10738 (2017). https://doi.org/10.1007/s10854-017-6849-y

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Keywords

  • Perovskite
  • Tolerance Factor
  • Diffuse Phase Transition
  • Paraelectric Phase Transition
  • Average Ionic Radius