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Size dependence electrocatalytic activity of gold nanoparticles decorated reduced graphene oxide for hydrogen evolution reaction

  • Qingxiang Yang
  • Mengguo Dong
  • Haimei Song
  • liu Cao
  • Yan Zhang
  • Lijie Wang
  • Pengbo Zhang
  • Zhijun ChenEmail author
Article

Abstract

It is promising for AuNPs/RGO composites to be exploited for hydrogen evolution reaction (HER), due to the collaborative effects between the electrocatalytic Au nanoparticles (AuNPs) and conductive reduced graphene oxide (RGO). In this work, we used a simple way to decorate AuNPs onto the RGO surface by one pot in situ reduction both HAuCl4 and GO, for which the controlled average size of AuNPs (2.7, 11.5 and 45.7 nm) is adjusting with the mass ratio of HAuCl4 and GO. The obtained materials, AuNPs/RGO composites, show excellent electrocatalytic activity for the HER that critical dependence on the particle size of AuNPs. The results show that AuNPs/RGO with AuNPs size of 11.5 nm exhibits superior electrochemical activity: low onset potential of 0.029 V versus the reversible hydrogen electrode as well as a small Tafel slope of 86 mV per decade.

Keywords

Graphene Oxide Glassy Carbon Electrode HAuCl4 Reduce Graphene Oxide Hydrogen Evolution Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

This work was supported by grants from the Natural Science Foundation of China (Nos. 21271160, 21401170, 20976168).

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • Qingxiang Yang
    • 1
  • Mengguo Dong
    • 1
  • Haimei Song
    • 1
  • liu Cao
    • 2
  • Yan Zhang
    • 1
  • Lijie Wang
    • 1
  • Pengbo Zhang
    • 1
  • Zhijun Chen
    • 1
    Email author
  1. 1.School of Material and Chemical Engineering, Henan Provincial Key Laboratory of Surface and Interface ScienceZhengzhou University of Light IndustryZhengzhouPeople’s Republic of China
  2. 2.Jiyuan Institute of Environmental ScienceJiyuanPeople’s Republic of China

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