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Structural and magnetic properties of Li and Na added Bi1.8Sr2.1 (Li,Na)xCa1.1Cu2.2Oy (Bi-2212) ceramics (x = 0, 0.05, 0.1 and 0.2)

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Abstract

The effect of Li and Na addition on superconducting properties of Bi-2212 ceramics has been investigated by the general chemical composition of Bi1.8Sr2(Li,Na)xCa1.1Cu2.1Oy superconductor with x = 0, 0.05, 0.1 and 0.2. XRD observations reveal that there are some impurity phases such as Bi2CaO4, Bi2O3 and Bi1.09Ca0.91O2.55 as well as Bi-2212 main phase according to different Li-Na contents. The magnetization measurements taken at both 10 and 25 K for all samples reveal the characteristic diamagnetic response of Bi-2212 phase. In addition, Jc values of samples are calculated from the M–H loops according to Bean model. Jc observations show that the current carrying capacity of Bi-2212 phase at high magnetic fields can be increased by optimal contents of Li and Na addition.

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Acknowledgements

All samples have been prepared in the MEİTAM Central Laboratory in Mersin University in Turkey. Both SEM and XRD measurements have been made in the MEİTAM Central Laboratory in Mersin University. Other measurements in this study have been made in the METU Central Laboratory in Middle East Technical University in Ankara in Turkey.

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Authors and Affiliations

  1. Department of Nanotechnology and Advanced Materials, Graduate School of Natural and Applied Science, Mersin University, Mersin, Turkey

    Berdan Özkurt

  2. Department of Energy Systems Engineering, Faculty of Tarsus Technology, Mersin University, Mersin, Turkey

    Berdan Özkurt

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  1. Berdan Özkurt
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Correspondence to Berdan Özkurt.

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Özkurt, B. Structural and magnetic properties of Li and Na added Bi1.8Sr2.1 (Li,Na)xCa1.1Cu2.2Oy (Bi-2212) ceramics (x = 0, 0.05, 0.1 and 0.2). J Mater Sci: Mater Electron 28, 8857–8863 (2017). https://doi.org/10.1007/s10854-017-6614-2

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