Skip to main content
SpringerLink
Log in

In situ synthesis and preparation of TiO2/polyimide composite containing phenolphthalein functional group

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this paper, titanium dioxide (TiO2)/phenolphthalein-type polyimide (PPPI) composite was synthesized in situ polymerization, the diamino phenolphthalein type compound and dimethylacetamide as the matrix, and TiO2 as the filler. The mechanical property and thermal conductivity properties were used to characterize the properties of the obtained composite. A diamine monomer containing more benzene rings of phenolphthalein and an ether bond in its main chain were prepared, synthesized by a nucleophilic substitution reaction and a hydrazine hydrate reduction reaction. Polyimide composite had the same structure as that of a diamine monomer. And it was synthesized by solution imidization and heat imidization. The results showed that TiO2 improved the dispersibility, alignment and interfacial strength of the TiO2/PPPI composite. The mechanical property of polyimide composite was increased with the increasing TiO2 loading. And a suitable addition of TiO2 could enhance the mechanical properties of polyimide system. Compared to polyimide resin, the TiO2/PPPI composite had a higher thermal conductivity with the increasing of TiO2 content. All of these changes in properties were closely correlated with the TiO2/PPPI composite, which could form an interaction interface structure in the system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. T. Kuilla, S. Bhadra, D. Yao, N. Kim, S. Bose, Prog. Polym. Sci 35, 1350 (2010)

    Article  Google Scholar 

  2. G. Wu, Y. Cheng, Y. Ren, Y. Wang, J. Alloy. Compd 652, 346 (2015)

    Article  Google Scholar 

  3. W.Y. Zhou, L.N Dong, J. Polym. Res. 23, 45 (2016)

    Article  Google Scholar 

  4. G. Wu, H. Wu, K. Wang, A. Feng, RSC Adv. 6(63), 58069 (2016)

    Article  Google Scholar 

  5. X.Y. Huang, P.K. Jiang, Adv. Mater. 27(3), 546 (2015)

    Article  Google Scholar 

  6. H. Wu, G. Wu, Y. Ren, L. Yang, J. Mater. Chem. C 3, 7677 (2015)

    Article  Google Scholar 

  7. Y. Wang, G. Wu, K. Kou, C. Pan, J. Mater. Sci: Mater. El. 27, 8279 (2016).

  8. G.L. Wu, Y.H. Cheng, Q. Xie, Z.R. Jia, F. Xiang, Mater. Lett 144, 157 (2015)

    Article  Google Scholar 

  9. Y. Wang, K. Kou, W. Zhao, G. Wu, F. Han, RSC Adv. 5, 99313 (2015)

    Article  Google Scholar 

  10. C. Pan, K. Kou, G. Wu, Y. Zhang, J. Mater. Sci Mater. El. 27, 286 (2016)

    Article  Google Scholar 

  11. J. Gu, C. Liang, X. Zhao, B. Gan, H. Qiu, Y. Guo, X. Yang, Compos. Sci. Technol. 139, 83 (2017)

    Article  Google Scholar 

  12. G. Wang, X. Huang, P. Jiang, ACS Appl. Mater. Interf. 7, 18017 (2015)

    Article  Google Scholar 

  13. G. Wu, Y. Cheng, F. Xiang, Z. Jia, Mat. Sci. Semicon. Proc. 41, 6 (2016)

    Article  Google Scholar 

  14. J. Gu, X. Yang, C. Li, K. Kou, Ind. Eng. Chem. Res. 55(41), 10941 (2016)

    Article  Google Scholar 

  15. W. Zhou, Thermochim. Acta. 512(1–2), 183 (2011)

    Article  Google Scholar 

  16. C. Liu, H. Yan, Q. Lv, S. Li, S. Niu, Carbon 102, 145 (2016)

    Article  Google Scholar 

  17. J. Gu, C. Liang, J. Dang, W. Dong, Q. Zhang, RSC Adv. 6(42), 35809 (2016)

    Article  Google Scholar 

  18. G. Wu, Y. Wang, K. Wang, A. Feng, RSC Adv. 6, 102542 (2016)

    Article  Google Scholar 

  19. C. Pan, K. Kou, Q. Jia, Y. Zhang, G. Wu, T. Ji, Compos. Part B Eng 111, 83 (2017)

    Article  Google Scholar 

  20. Y. Zhou, H. Wang, L. Wang, K. Yu, Z. Lin, L. He, Mater. Sci. Eng. B 177(11), 892 (2012)

    Article  Google Scholar 

  21. C. Teng, C.M. Ma, C. Lu, S. Yang, S. Lee, M. Hsiao, Carbon 49(15), 5107(2011).

  22. S. Niu, H. Yan, S. Li, C. Tang, Z. Chen, X. Zhi, J. Mater. Chem. C 4, 6881 (2016)

    Article  Google Scholar 

  23. G. Wu, Y. Cheng, Q. Xie, C. Liu, J. Polym. Res. 21, 615 (2014)

    Article  Google Scholar 

  24. J. Gu, X. Yang, Z. Lv, N. Li, C. Liang, Int. J. Heat Mass Tran 92, 15 (2016)

    Article  Google Scholar 

  25. G. Wu, K. Kou, M. Chao, L. Zhuo, Thermochim. Acta. 537, 44 (2012)

    Article  Google Scholar 

  26. G. Wu, Y. Cheng, K. Wang, A. Feng, J. Mater. Sci Mater. El. 27(6), 5592 (2016)

    Article  Google Scholar 

  27. Y. Wang, K. Kou, G. Wu, A. Feng, L. Zhuo, RSC Adv. 5, 58821 (2015)

    Article  Google Scholar 

  28. G. Wu, K. Kou, L. Zhuo, Y. Wang, J. Zhang, Thermochim. Acta. 559, 86 (2013)

    Article  Google Scholar 

  29. Y. Wang, K. Kou, G. Wu, L. Zhuo, J. Li, Y. Zhang, Polymer 77, 354 (2015)

    Article  Google Scholar 

  30. G. Wu, K. Kou, N. Li, H. Shi, M. Chao, J. Appl. Polym. Sci 128, 1164 (2013)

    Article  Google Scholar 

  31. L. Bai, H. Yan, L. Yuan, J. Polym. Res. 23(8), 169 (2016)

    Article  Google Scholar 

  32. S. Wang, J. Zha, Y. Wu, L. Ren, Z. Dang, J. Wu, IEEE Trans. Dielectr. Electr. Insul. 22, 3350 (2015)

    Article  Google Scholar 

  33. S. Wang, J. Zha, W. Li, Z. Dang, Appl. Phys. Lett. 108, 092902 (2016)

    Article  Google Scholar 

  34. Y. Wu, J. Zha, W. Li, S. Wang, Z. Dang, Appl. Phys. Lett. 107, 112901 (2015)

    Article  Google Scholar 

  35. J. Zha, Y. Wu, S. Wang, D. Wu, Z. H Yan, Dang. IEEE Trans. Dielectr. Electr. Insul. 23, 2337 (2016)

    Article  Google Scholar 

  36. H. Hu, L. Liu, Z. Li, C. Zhao, Y. Huang, G. Chang, J. Yang, Polymer 66, 58 (2015)

    Article  Google Scholar 

  37. H. Arbess, F. Baccar, L. Theolier, S. Azzopardi, E. Woirgard, Microelectron. Reliab. 55, 2017 (2015)

    Article  Google Scholar 

  38. L. Kong, Y. Cheng, Y. Jin, Z. Ren, Y. Li, F. Xiao, J. Mater. Chem. C 3, 3364 (2015)

    Article  Google Scholar 

  39. L. Kong, T. Qi, Z. Ren, Y. Jin, Y. Li, Y. Cheng, F. Xiao, RSC Adv. 6, 68560 (2016)

    Article  Google Scholar 

  40. D.J. Liaw, K.L. Wang, Y.C. Huang, K.R. Lee, J.Y. Lai, C.S. Ha. Prog. Polym. Sci 37, 907 (2012)

    Article  Google Scholar 

  41. M.G. Dhara, S. Banerjee, Prog. Polym. Sci. 35(8), 1022 (2010)

    Article  Google Scholar 

  42. W. Chen, W. Yan, S. Wu, Z. Xu, K. Yeung, C. Yi, Macromol. Chem. Phys. 211, 1803 (2010)

    Article  Google Scholar 

  43. J. Gu, X. Meng, Y. Tang, Q. Zhang, J. Kong, Compos. Part A Appl. Sci. Manufact. 92, 27 (2017)

    Article  Google Scholar 

  44. M. Hasegawa, D. Hirano, M. Fujii, M. Haga, E. Takezawa, S. Yamaguchi, A. Ishikawa, T. Kagayama, J. Polym. Sci. Pol. Chem. 51, 575 (2013)

    Article  Google Scholar 

  45. Y. Chen, Q. Zhang, W. Sun, X. Lei, P. Yao, J. Membrane. Sci. 450, 138 (2014)

    Article  Google Scholar 

  46. S.D. Kim, S.Y. Kim, I.S. Chung, J. Polym. Sci. Pol. Chem. 51, 4413 (2013)

    Article  Google Scholar 

  47. M. Miki, T. Suzuki, Y. Yamada, J. Appl. Polym. Sci 130, 54 (2013)

    Article  Google Scholar 

  48. Y. Shoji, R. Ishige, T. Higashihara, J. Morikawa, T. Hashimoto, A. Takahara, J. Watanabe, M. Ueda, Macromolecules 46, 747 (2013)

    Article  Google Scholar 

  49. H. Sadeghipour, Z. Rafiee, D. Ashouri, High. Perform. Polym. 27(1), 31 (2015)

    Article  Google Scholar 

  50. M. Chao, K. Kou, G. Wu, J. Zhang, N. Li, D. Zhang, J. Macromol. Sci. Part. B 51(10), 2003 (2012)

    Article  Google Scholar 

  51. L.H. Zhuo, K.C. Kou, P. Yao, G. L. Wu, Y.Q. Wang, J. Therm. Analys. Calor. 119(3), 2039 (2015)

    Article  Google Scholar 

  52. L. Zhuo, K. Kou, Y. Wang, P. Yao, G. Wu, J. Mater. Sci. 49(14), 5141 (2014)

    Article  Google Scholar 

  53. S.D. Kim, S.Y. Kim, I.S. Chung, J. Polym. Sci. Part. A 51(20), 4413 (2013)

    Article  Google Scholar 

  54. Z. Hu, Y. Yin, H. Kita, K.I. Okamoto, Y. Suto, H. Wang, H. Kawasato, Polymer, 48(7), 1962 (2007)

    Article  Google Scholar 

  55. M. Hasegawa, D. Hirano, M. Fujii, J. Polym. Sci. Part. A 51(3), 575 (2013)

    Article  Google Scholar 

  56. D.H. Wang, J.K. Riley, S.P. Fillery, J. Polym. Sci. Part. A 51(23), 4998 (2013)

    Article  Google Scholar 

  57. Y. Shao, Y. Li, X. Zhao, Eur. Polym. J. 43(10), 4389 (2007)

    Article  Google Scholar 

  58. J. Shen, Y. Zhang, W. Chen, J. Polym. Sci. Part A 51(11), 2425 (2013)

    Article  Google Scholar 

  59. W. Li, X. Guo, J. Fang, J. Mater. Sci. 49(7), 2745 (2014)

    Article  Google Scholar 

  60. Y. Zhang, L. Yu, Q. Su, J. Mater. Sci. 47(4), 1958 (2012)

    Article  Google Scholar 

  61. C. Wang, X. Zhao, G. Li, Chin. J. Chem. 30, 1555 (2012)

    Article  Google Scholar 

  62. A. Ghosh, S.K. Sen, S. Banerjee, B. Voit, RSC Adv. 2(14), 5900 (2012)

    Article  Google Scholar 

  63. K. Zeng, Q. Guo, S. Gao, D. Wu, H. Fan, G. Yang, Macromol. Res. 20(1), 10 (2012)

    Article  Google Scholar 

  64. X. Huang, W. Huang, J. Liu, Polym. Int. 61(10), 1503 (2012)

    Article  Google Scholar 

  65. J. Wang, C. Liu, G. Su, X. Jian, High. Perform. Polym. 24(5), 356 (2012)

    Article  Google Scholar 

  66. J. B. Baek, H. Qin, P.T. Mather, L.S. Tan, Macromolecules. 35(13), 4951 (2002)

    Article  Google Scholar 

  67. H.W. Cao, Des. Monomers. Polym. 9(4), 369 (2006)

    Article  Google Scholar 

  68. Y. Po, G. Yi, J. Polym. Res. 18(6), 1725 (2011)

    Article  Google Scholar 

  69. B.F. Zhang, Polymer. 50(3), 817 (2009)

    Article  Google Scholar 

  70. X.H. Xiong, Chin. J. Mater. Res. 9, 715 (2014)

    Google Scholar 

  71. C.P. Yang, J.H. Lin, J. Polym. Sci. Part A 32, 369 (1994)

    Article  Google Scholar 

  72. C.P. Yang, J.H. Lin, J. Polym. Sci. Part A 32, 423 (1994)

    Article  Google Scholar 

  73. C.P. Yang, H.C. Chiang, Y.Y. Su, Polym. J. 36(12), 979 (2004)

    Article  Google Scholar 

  74. L. Weng, Q.S. Xia, L.W. Yan, L.Z. Liu, Z. Sun, Polym. Compos. 37, 125 (2016)

    Article  Google Scholar 

  75. H. Zhou, D.Y. Wei, Y. Fan, H. Chen, Y.S. Yang, J.J. Yu, L.G. Jin, Mater. Sci. Eng. B 203, 13 (2016)

    Article  Google Scholar 

  76. L.P. Liu, F.Z. Lv, P.G. Li, L. Ding, W.S. Tong, P.K. Chu, Y.H. Zhang, Compos. Part. A 84, 292 (2016)

    Article  Google Scholar 

  77. B. Sadhasivam, S. Muthusamy, Des. Monomers. Polym. 19(3), 236 (2016)

    Article  Google Scholar 

  78. L.C. He, P. Zhang, H.F. Chen, J. Sun, J.J. Wang, C.X. Qin, L.X. Dai, Polym. Int. 65, 84 (2016)

    Article  Google Scholar 

  79. G. Wu, Y. Cheng, Z. Wang, K. Wang, A. Feng, J. Mater. Sci: Mater. El. (2016). doi:10.1007/s10854-016-5560-8.

    Google Scholar 

  80. Y.J. Wang, X.J. Wu, C.G. Feng, Q.X. Zeng, Microelectron. Eng 154, 17 (2016)

    Article  Google Scholar 

  81. Y. Sun, J. Wang, S. Qi, G. Tian, D. Wu, Appl. Phys. Lett. 107, 012905 (2015)

    Article  Google Scholar 

  82. M. Chao, K. Kou, G. Wu, D. Zhang, J. Macrom. Sci. Part A Pure Appl. Chem. 49, 578 (2012)

    Article  Google Scholar 

  83. M. Sun, J. Chang, G. Tian, H. Niu, D. Wu, J. Mater. Sci. 51, 2830 (2016)

    Article  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Science Foundation of China (No. 51407134), China Postdoctoral Science Special Foundation (No. 2015T81028), China Postdoctoral Science Foundation (No. 2016M590619, No. 2016M592138), Natural Science Foundation of Shandong Province (No. ZR2016EEQ28), Natural Science Basic Research Plan in Shaanxi Province of China (No. 2015JM5215), Special Scientific Research Program of Shaanxi Provincial Department of Education (No. 16JK1043), Baoji Science and Technology Project (No. 16RKX1-29), Key Project of Baoji University of Arts and Sciences (No. ZK16072), Baoji Engineering Technology Research Center for Ultrafast Optics and New Materials (No. 2015CXNL-1-3). A Feng is supported by scholarship from the China Scholarship of Council (No. 201508615058). The authors also thank their colleagues in their laboratory for their support.

Author information

Authors and Affiliations

  1. Institute of Materials for Energy and Environment, State Key Laboratory Breeding Base of New Fiber Materials and Modern Textile, College of Materials Science and Engineering, Qingdao University, Qingdao, 266071, People’s Republic of China

    Guanglei Wu & Kuikui Wang

  2. Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Science, Northwestern Polytechnical University, Xi’an, 710129, People’s Republic of China

    Guanglei Wu, Junli Li, Yiqun Wang & Chen Pan

  3. Institute of Physics and Optoelectronics Technology, Baoji University of Arts and Sciences, Baoji, 721016, People’s Republic of China

    Ailing Feng

Authors
  1. Guanglei Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Junli Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kuikui Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yiqun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Chen Pan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ailing Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Guanglei Wu or Ailing Feng.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wu, G., Li, J., Wang, K. et al. In situ synthesis and preparation of TiO2/polyimide composite containing phenolphthalein functional group. J Mater Sci: Mater Electron 28, 6544–6551 (2017). https://doi.org/10.1007/s10854-017-6343-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-6343-6

Keywords

Search

Navigation