Abstract
Gd2O3:Pr3+ phosphor was synthesized by combustion synthesis method using glycerine as a fuel. The structural properties as well as the optical properties were investigated. The structural characterization was done by using X-ray diffraction and electron mircroscopic techniques. Optical property such as photoluminescence was investigated under 275 nm excitation. Emission spectra has intense peak in red region around 638 nm. CIE coordinates also confirms that the prepared phosphor behaves as a red emitting phosphor.
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R.J. Han, L. Wang, K.Z. Chen, S.B. Yang, Photoluminescence properties of Y3Al5O12: Eu nanocrystallites prepared by co-precipitation method using a mixed precipitator of NH4HCO3 and NH3·H2O. Mater. Sci. Eng. B 166, 41 (2010)
M.R.N. Soares, C. Nico, D. Oliveira, M. Peres, L. Rino, A.J.S. Fernandes, T. Monteiro, F. Mosta, Red light from ZrO2: Eu3+ nanostructures. Mater. Sci. Eng. B 177, 712 (2012)
J.S. Liao, S.A. Zhang, H.Y. You, H.R. Wen, J.L. Chen, W.X. You, Energy transfer and luminescence properties of Eu3+-doped NaTb(WO4)2 phosphor prepared by a facile hydrothermal method. Opt. Mater. 33, 953 (2011)
L. Qin, Y.L. Huang, T. Tsuboi, H.J. Seo, The redemitting phosphors of Eu3+-activated MR2(MoO4)4 (M = Ba, Sr, Ca; R = La3+, Gd3+, Y3+) for light emitting diodes. Mater. Res. Bull. 47, 4498 (2012)
R.K. Tamrakar, D.P. Bisen, N. Brahme, Characterization and luminescence properties of Gd2O3 phosphor. Res. Chem. Intermed. 40(5), 1771–1779 (2014)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, N. Bramhe, Down-conversion luminescence property of Er3+ and Yb3+ co-doped Gd2O3 crystals prepared by combustion synthesis and solid state reaction method. Superlattices Microstruct. 81, 34–48 (2015)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, I.P. Sahu, Comparative study and role of Er3+ and Yb3+ concentrations on upconversion process of Gd2O3: Er3+/Yb3+ phosphors prepared by solid-state reaction and combustion method. J. Phys. Chem. C 119(36), 21072–21086 (2015)
K.M. Lin, Y.Y. Li, Luminescent properties and characterization of one dimensional Gd2O3: Eu3+ phosphor nano-wire for field emission application. Nanotechnology 17, 4048–4052 (2006)
C.S. Park, M.G. Kwak, S.S. Choi, Y.S. Song, S.J. Hong, J.I. Han et al., Influence of Eu3+ doping content on photoluminescence of Gd2O3: Eu3+ phosphors prepared by liquidphase reaction method. J. Lumin. 118, 199–204 (2006)
S.Y. Seo, S. Lee, H.D. Park, N. Shin, K.S. Sohn, Luminescence of pulsed laser deposited Gd2O3: Eu3+ thin film phosphors on quartz glass substrates. J. Appl. Phys. 92, 5248–5251 (2002)
K.H. Lee, Y.J. Bae, S.H. Byeon, Nanostructures and photoluminescence properties of Gd2O3:Eu red-phosphor prepared via hydrothermal route. Bull. Korean Chem. Soc. 29, 2161–2168 (2008)
X.Y. Chen, E. Ma, G.K. Liu, Energy levels and optical spectroscopy of Er3+ in Gd2O3 nanocrystals. J. Phys. Chem. C 111, 10404–10411 (2007)
H. Guo, Y.F. Li, D.Y. Wang, W.P. Zhang, M. Yin, L.R. Lou et al., Blue upconversion of cubic Gd2O3: Er produced by green laser. J. Alloy. Compd. 376, 23–27 (2004)
P. Boutinaud, R. Mahiou, E. Cavalli, M. Bettinelli, Red luminescence induced by intervalence charge transfer in Pr3+ doped compounds. J. Lumin. 122–123, 430 (2007)
X.Y. Yang, J. Liu, H. Yang, X.B. Yu, Y.Z. Guo, Y.Q. Zhou, J.Y. Liu, Synthesis and characterization of new red phosphors for white LED applications. J. Mater. Chem. 19, 3771 (2009)
S. Mahlik, M. Grinberg, A.A. Kaminskii, M. Bettinelli, P. Boutinaud, Luminescence of Ca(NbO3)2: Pr3+ at ambient and high hydrostatic pressure. J. Lumin. 129, 1219 (2009)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, Effect of annealing on down-conversion properties of monoclinic Gd2O3: Er3+ nanophosphors. Luminescence 30(6), 812–817 (2015)
D. Grier, G. McGarthy, Fargo. (ND, USA, ICCD, Grantin Aid, 1991)
A. Guinier, X-ray Diffraction. (Freeman, San Francisco, 1963)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, I.P. Sahu, M. Sahu, The effect of annealing and irradiation dose on the thermoluminescence glow peak of a monoclinic Gd2O3: Yb3+ phosphor. RSC Adv. 6(84), 80797–80807 (2016)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, I.P. Sahu, M. Sahu, The down conversion properties of a Gd2O3: Er3+ phosphor prepared via a combustion synthesis method. RSC Adv. 6(95), 92360–92370 (2016)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, I.P. Sahu, Upconversion and colour tunability of Gd2O3: Er 3+ phosphor prepared by combustion synthesis method. J. Alloy. Compd. 655, 423–432 (2016)
R.K. Tamrakar, D.P. Bisen, K. Upadhyay, I.P. Sahu, Comparative study and role of Er3+ and Yb3+ concentrations on upconversion process of Gd2O3: Er3+ Yb3+ phosphors prepared by solid-state reaction and combustion method. J. Phys. Chem. C 119(36), 21072–21086 (2015)
R.K. Tamrakar, K. Upadhyay, Thermoluminescence behaviour of Gd2O3: Er3+ phosphor prepared by combustion synthesis method. J. Mater. Sci. (2016). doi:10.1007/s10854-016-6050-8
H. Guo, X.D. Yang, T. Xiao, W.P. Zhang, L.R. Lou, J. Mugnier, Structure and optical properties of sol–gel derived Gd2O3 waveguide films. Appl. Surf. Sci. 230, 215–221 (2004)
J.A. Capobianco, F. Vetrone, J.C. Boyer, A. Speghini, M. Bettinelli, Enhancement of red emission (4F9/2→4I15/2) via upconversion in bulk and nanocrystalline cubic Y2O3: Er3+. J. Phys. Chem. B 106, 1181 (2002)
G. Blasse, J. Solid State Chem. 62, 207–211 (1986)
G. Blasse, Philips Res. Rep. 24, 131 (1969)
M.H. Jang, Y.K. Choi, K.B. Chung, H. Jeon, M.H. Cho, Luminescent mechanism of Eu3+doped epitaxial Gd2O3 films grown on a Si (111) substrate using an effusion cell. Curr. Appl. Phys. 11(2011) 1001–1005
S.Y. Zhang, Spectroscopy of rare earth ions-spectral property and spectral theory, 1st edn. (Science Press, Beijing, 2008) (Chinese)
S.E. Lin, K. Borgohain, W.C.J. Wei, Praseodymium-doped photo-luminescent strontium indate nanoparticles by ultrasonic spray pyrolysis. J. Am. Ceram. Soc. 89, 3266–3269 (2006)
C.X. Cardoso, Y. Messaddeq, L.A.O. Nunes, M.A. Aegerter, Optical properties of pure, Nd3 +–doped and Pr3 +–doped fluoroindate glasses. J. Non-Cryst. Solids 161, 277–281 (1993)
Y.K. Sharma, S.S.L. Surana, R.K. Singh, Optical absorption and fluorescence spectra of Pr(III) doped borosilicate glasses and their Judd–Ofelt analysis to study lasing characteristics. Indian J. Pure Appl. Phys. 46, 239–244 (2008)
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Tamrakar, R.K., Upadhyay, K. Optical properties of Gd2O3: Pr3+ phosphor synthesized by combustion method using glycerine as a fuel. J Mater Sci: Mater Electron 28, 6112–6118 (2017). https://doi.org/10.1007/s10854-016-6288-1
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DOI: https://doi.org/10.1007/s10854-016-6288-1